Electrical properties of tri-n-butyl tin acrylate-methylmethacrylate copolymers

The copolymerization of tri-n-butyl tin acrylate (TBTA) with methylmethacrylate (MMA) has been investigated in dioxane. The composition of these copolymers was determined quantitatively by ¹H nuclear magnetic resonance (NMR) spectroscopy. The tin contents were estimated by gravimetric as well as thermogravimetric techniques (TGA). The reactivity ratio of such copolymers was estimated by application of the Kelen-Tudos method. The dielectric properties of the copolymers have been studied over a frequency range of 100–50 kHz at different temperatures from 20 to 70°C. The electrical conductivity for such copolymers was also measured. The results are interpreted in terms of the tin content of the copolymers.     

Vibration and damping analysis of beams with composite coats

Numerical and experimental investigations of the dynamic behavior for coated laminate composite beams has been presented and discussed in the present work. A numerical technique is utilized to compute the eigen parameters of coated laminated composite beams. An attempt to study the variations in the natural frequencies and damping properties of laminated composite coated beams taking into account different lamina orientation of coat and various kinds of core isotropic material (steel and aluminium) is introduced. The variations of the eigen parameters vs. the code number of the coated layer with the use of various types of isotropic material are measured by utilizing (the frequency response displayed on) an (FFT) analyzer. The experimental and numerical work is carried out on four different fiber orientations, aligned longitudinally, transversely, making 45 ° with the fibers direction and randomly oriented. Comparison between experimental and numerical results shows a tight connection between them.     

Water and salt permeability of reinforcement polymer‐gel composite membrane

The charged mosaic polymer membrane (CMM) without reinforcement and the composite charged mosaic polymer membrane (CCMM) with reinforcement were investigated in terms of salt and water transport (permeability). The composite charged mosaic polymer membrane (CCMM) with reinforcement showed a unique transport behavior such as preferential material transport L_p and ω. Water permeability coefficient, L_p and salt permeability coefficient, ω were estimated by taking account of active layer thickness of composite polymer gel. The L_p and ω values of CCMM with reinforcement were larger than those of CMM without reinforcement. On the other hand, the reflection coefficient of CCMM, σ, showed negative value, which suggested preferential material transport to solvent transport. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Improvement of the engineering properties of asphalt pavements using a ‘soft’ compaction technique (AMIR-Compaction)

In most countries of the world asphalt pavement of road networks represents the biggest single investment in the transportation system. In Canada, asphalt pavement built over the past decade is worth more than 70 billion dollars (in 1984 dollars). In order to maintain the current road network at the present level of service and prevent it from further deterioration, over 6 billion dollars is needed anually.

Traditionally, asphalt overlays are widely used to rehabilitate existing deteriorated pavements. Unfortunately the new overlays have been observed to fail in a relatively short time. Thus the investment in overlays is lost.

Recent research based on the concept of relative rigidity has indicated that the rapid deterioration of new asphalt overlays is directly related to current construction equipment. It has been shown analytically and experimentally that steel rollers used in compacting the asphalt layer will result in surface cracks during construction. Traffic and environmental influences will accelerate the failure of the new layer.

This paper presents the results of a testing programme evaluating the engineering properties of asphalt slabs compacted by a new method using a compactor termed AMIR. The results showed that the AMIR compactor will prevent the formation of constitution cracks resulting in an increase of indirect tensile strength of 10% and an increase of direct tensile strength of up to 60% when compared to steel roller compacted asphalt slabs.     

An improved volleyball premier league algorithm based on sine cosine algorithm for global optimization problem

Volleyball premier league (VPL) simulating some phenomena of volleyball game has been presented recently. This powerful algorithm uses such racing and interplays between teams within a season. Furthermore, the algorithm imitates the coaching procedure within a game. Therefore, some volleyball metaphors, including substitution, coaching, and learning, are used to find a better solution prepared by the VPL algorithm. However, the learning phase has the largest effect on the performance of the VPL algorithm, in which this phase can lead to making the VPL stuck in optimal local solution. Therefore, this paper proposed a modified VPL using sine cosine algorithm (SCA). In which the SCA operators have been applied in the learning phase to obtain a more accurate solution. So, we have used SCA operators in VPL to grasp their advantages resulting in a more efficient approach for finding the optimal solution of the optimization problem and avoid the limitations of the traditional VPL algorithm. The propounded VPLSCA algorithm is tested on the 25 functions. The results captured by the VPLSCA have been compared with other metaheuristic algorithms such as cuckoo search, social-spider optimization algorithm, ant lion optimizer, grey wolf optimizer, salp swarm algorithm, whale optimization algorithm, moth flame optimization, artificial bee colony, SCA, and VPL. Furthermore, the three typical optimization problems in the field of designing engineering have been solved using the VPLSCA. According to the obtained results, the proposed algorithm shows very reasonable and promising results compared to others.

     

Visual tracking using convolutional features with sparse coding

Artificial Intelligence Review - Visual object tracking has become one of the most active research topics in computer vision, and it has been applied in several commercial...     

The Valve Metal Character of Zirconium as inferred from anode potential measurements in mineral acid solutions

A study on the value metal character of Zr in 0.1 M solutions of H₂SO₄, HNO₃, and H₃PO₄ has been performed using the anode potential as the primary variable in galvanostatic, potentiostatic, and capacity measurements. A method of surface pre-treatment, which suppresses both O₂ evolution and metal dissolution, has been described. Kinetic parameters of oxide growth have been calculated. The results indicate that:

• (i) the high field approximation is applicable following an exponential law, and
• (ii) the height and activation distance of the energy barrier for ion transport through the oxide phase (Verwey model) are the same three acids.

Measurements have been also made on the dielectric breakdown of oxide, and this occurs at potentials above 200 V. Direct capacity measurements give similar results as those based on reciprocal capacity calculated from galvanostatic experiments. It is concluded that the dominant anodic oxide species is ZrO₂ having a dielectric constant of 25. Open circuit potential measurements show that Zr is spontaneously oxidized in the three acids.     

Autocatalytic dissolution of Pb in HNO3

The reaction between Pb and HNO₃ has been investigated using the thermometric technique. Weight-loss measurements on the reaction were also obtained. As the HNO₃ concentration is increased from 5×10^–2 to 4mol l^–1, the corrosion rate increases. This is shown thermometrically by a substantial increase in the maximum temperature attained, T _m, as well as a decrease in the time, t, required for reaching T _m. Dissolution of Pb in HNO₃ is proposed to take place according to an autocatalytic mechanism. Passivation sets were detected in solutions 11 mol l^–1 HNO₃. A parallel indication between the thermometric technique and weight-loss measurements was obtained. The rate-determining step of the autocatalytic process involves HNO₂ in dissolution of Pb in HNO₃. This is supported by the results of addition of hydrazine to the solution. This additive raises the maximum measured temperature, without affecting the corresponding time necessary to reach it. The effect of addition of NaNO₂, NaNO₃, NaCl, Na₂SO₄, NaH₂PO₄ and NaClO₄ on the reaction number, RN, of Pb in 4 mol l^–1 HNO₃ was examined. Only NaNO₂ accelerates the dissolution reaction while the other salts show as inhibition effect. It was found that these additives inhibit dissolution due to the displacement of some cathodic depolarizing components, as NO₂, from the active sites on the metal surface. The effect of addition of HCl, H₂SO₄, HClO₄ and H₃PO₄ on the reaction number, RN, of Pb in 4 mol l^–1 HNO₃ was also investigated. The observed acceleration and retardation of the dissolution of Pb was found to be dependent on both the concentration and nature of anions of the extra acids added.     

Effect of SiO2 Addition on Chromium Transitions in Borate Glasses

Silicon - Melt-quenching technique was used to prepare borosilicate glasses of composition xSiO2- (75-x) B2O3–24.7Li2O-0.3Cr2O3 (x = 0, 10, 20, 30, 40 and 50 mol%). With...     

Corrosion inhibition of carbon steel in hydrochloric acid by cationic arylthiophenes as new eco-friendly inhibitors: Experimental and quantum chemical study

This study describes the adsorption behavior of three arylthiophene derivatives namely: 2-(4-amidino-3-fluorophenyl)-5-[4-methoxy phenyl] thiophene dihydrochloride salt (MA-1217), 2-(4-amidinophenyl)-5-[4-chlorophenyl] thiophene dihydrochloride salt (MA-1316) and 2-(4-amidino-3-fluorophenyl)-5-[4-chlorophenyl]thiophene dihydrochloride salt (MA-1312) at C-steel in 1.0 mol·L^-1 HCl interface using experimental and theoretical studies. Electrochemical and mass loss measurements showed that the inhibition efficiency (IE) of the arylthiophene derivatives increases with increasing concentrations and exhibited maximum efficiency 89% at 21×10^-6 mol·L^-1 (MA-1217) by mass loss method. The investigated arylthiophene derivatives obey the Langmuir adsorption isotherm. From polarization studies the arylthiophene derivatives act as mixed-type inhibitors. Surface analysis were carried out and discussed. The mode of orientation and adsorption of inhibitor molecules on C-steel surface was studied using molecular dynamics (MD) simulations. Quantum chemical parameters as well as the radial distribution function indices and binding energies confirm the experimental results.