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41.
Critical current densities of the superconducting Y-Ba-Cu-O (YBCO) films have been observed to decrease with the increase of power of microwave radiation. Presence of Josephson type of junctions in the microbridges has been established from the microwave irradiation and magnetic field studies. BCS energy gap parameter (2/kT c ) has been calculated from thedI/dV characteristics and found to be 3.7 at 13 K.  相似文献   
42.
43.
The kinetics of reduction of nickel chloride with hydrogen were investigated in the temperature range of 533 (260 °) to 788 K (515 °). Most experiments were done with porous NiCl2 granules having ?8+10 mesh (Tyler) size. The effects of temperature, sample size, granule size and hydrogen partial pressure on the reduction kinetics were investigated. In the temperature range 533 (260 °) to 651 K (378 °) the reduction is dominated by chemical kinetic factors. At higher temperatures diffusional effects appear to become quite significant. The temperature-dependence of the chemical kinetic rate constantK is given by $$\log K = 6.744 - \frac{{22,240}}{{2.303RT}};K\,\,is\,\,in\,\,\min ^{ - 1} $$ The activation energy for the reduction was found to be 22,240 cal /mol (or 93,050 J/mol) in the chemical kinetic regime.  相似文献   
44.
The chemistry of dicalcium silicate mineral   总被引:1,自引:0,他引:1  
Dicalcium silicate is of vital importance in several fields of silicate science. It exists in several polymorphic forms, of which one (the-form) is stable at room temperature without any stabilizer. The-form is commonly found in ordinary portland cement (OPC) in association with stabilizing ions. Stabilization of other forms,,L,H andm for structural and other studies have been reported. Theoretical structural analysis using topology has been reported to be of value in understanding the stabilization process of the polymorphs. The conversion of form is at times a problem in the cement industry, in addition to the formation of unwanted compounds, such as spurrite. The-form is low in hydraulic properties but in the presence of impurities such as excess CaO over the stoichiometric ratio, shows fairly high hydraulic properties. Of the other phases, the hydraulic properties of the a forms are quite encouraging but the choice of stabilizers etc. plays a dominant role. Correlation of hydraulicity with structural properties such as crystal defects, etc., has been reported but satisfactory explanation is yet to come. The hydration products of-C2S are quite similar to those of C3S but the kinetics are fairly slow. In the presence of active silica, and at elevated temperatures, even the-form hydrates at a faster rate. The influence of chemical accelerators on the hydration of C2S at room temperature is well studied and NaF is found to be one of the best accelerators. The formation of reactive-C2S by different preparative methods shows a quite interesting trend for potential manufacture of low-temperature inorganic cement or OPC with low C3S; even utilization of low-grade limestone could be possible. The role of C2S in the hydration of aluminous cements is being increasingly recognized and, in fact, a newer class of cements called alumina-belite cement, etc., are being developed in which C2S is purposely maintained as a major phase.  相似文献   
45.
The goal of this work is to improve availability of operational base-stations in a wireless mobile network through non-intrusive fault detection methods. Since revenue is generated only when actual customer calls are processed, we develop a scheme to minimize revenue loss by monitoring real-time mobile user call processing activity. The mobile user call load profile experienced by a base-station displays a highly non-stationary temporal behavior with time-of-day, day-of-the-week and time-of-year variations. In addition, the geographic location also impacts the traffic profile, making each base-station have its own unique traffic patterns. A hierarchical base-station fault monitoring and detection scheme has been implemented in an IS-95 CDMA Cellular network that can detect faults at - base station level, sector level, carrier level, and channel level. A statistical hypothesis test framework, based on a combination of parametric, semi-parametric and non-parametric test statistics are defined for determining faults. The fault or alarm thresholds are determined by learning expected deviations during a training phase. Additionally, fault thresholds have to adapt to spatial and temporal mobile traffic patterns that slowly changes with seasonal traffic drifts over time and increasing penetration of mobile user density. Feedback mechanisms are provided for threshold adaptation and self-management, which includes automatic recovery actions and software reconfiguration. We call this method, Operational Fault Detection (OFD). We describe the operation of a few select features from a large family of OFD features in Base Stations; summarize the algorithms, their performance and comment on future work.  相似文献   
46.
This paper presents an extended oblique machining theory applicable to the analysis of 3-D machining. Existing theories are evaluated to identify suitable formulations which are used with necessary modifications for predicting various quantities pertaining to cutting conditions of three dimensional machining. Actual chip flow angles extracted from measured forces, to account for the nose radius effect, are used, instead of available models, to predict important quantities such as shear plane angle, effective rake angle and shear flow angle. Experiments are conducted in the realms of conventional and high speed machining using AISI 4140 steel and aluminum 7075-T6 respectively with uncoated carbide inserts, and various process conditions pertaining to the cutting mechanics are calculated. The extended oblique machining theory is experimentally validated in predicting temperatures at the tool-chip interface and shear plane for conventional machining. Simulation results from the finite element modeling are used for verifying the shear stress and shear plane temperature predicted by the extended oblique machining theory.  相似文献   
47.
本文较详细地讨论了功率分流式封闭行星齿轮减速器的设计计算,文中阐述了该封闭传动的特点, 比计算,受力分析和效率计算,同时还研究报其封闭功率和功率分流等问题,因此,本文对于同类型的封闭行星减速器的设计工作具有较重要的指导意义。  相似文献   
48.
Unsaturated clays are subject to osmotic suction gradients in geoenvironmental engineering applications and it therefore becomes important to understand the effect of these chemical concentration gradients on soil-water characteristic curves (SWCCs). This paper brings out the influence of induced osmotic suction gradient on the wetting SWCCs of compacted clay specimens inundated with sodium chloride solutions/distilled water at vertical stress of 6.25 kPa in oedometer cells. The experimental results illustrate that variations in initial osmotic suction difference induce different magnitudes of osmotic induced consolidation and osmotic consolidation strains thereby impacting the wetting SWCCs and equilibrium water contents of identically compacted clay specimens. Osmotic suction induced by chemical concentration gradients between reservoir salt solution and soil-water can be treated as an equivalent net stress component, (pπ) that decreases the swelling strains of unsaturated specimens from reduction in microstructural and macrostructural swelling components. The direction of osmotic flow affects the matric SWCCs. Unsaturated specimens experiencing osmotic induced consolidation and osmotic consolidation develop lower equilibrium water content than specimens experiencing osmotic swelling during the wetting path. The findings of the study illustrate the need to incorporate the influence of osmotic suction in determination of the matric SWCCs.  相似文献   
49.
A system of two parallel single-server exponential queues is considered. These queues operate independently except that the service rate in each queue changes whenever the other queue is empty. By treating one of the queues as bounded, this model can be shown to have a matrix-geometric steady state vector which can be computed efficiently. Algorithms are also developed to compute the characteristics of the departure stream of customers from each queue. Some numerical results are presented, and based on these results an efficient approximation scheme for the system is developed which may possibly be extended to systems with more than two parallel queues.  相似文献   
50.
Molecular-dynamics computer-simulation of an ionic molecular solid LiKSO4 has been carried out at 300 and 1000 K using the atom-atom potentials obtained from lattice dynamical studies. We observe hopping of lithium ions to interstitial positions which is related to reorientations of sulphate tetrahedra.  相似文献   
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