Complexity reduction of signal detection by exploiting correlation characteristics of spreading sequences

In this paper, we propose an approach to reduce the multi‐user detection (MUD) complexity based on user grouping and signal replica classification by exploiting the correlation characteristics of spreading sequences in multipath fading channels. The spreading sequences are constructed from inter‐group complementary codes with a sparse and regular correlation matrix and inherit its attractive auto/cross‐correlation properties. Users are first partitioned into independent user groups according to whether or not there is interference among them, and then the replicas of user signals from the same user group are further classified into independent replica classes. The MUD is carried out within each low‐dimensional user group or replica class, respectively, reducing the MUD complexity substantially. This approach can be applied to most of the existing MUD algorithms for complexity reduction, and in this paper optimal MUD and multi‐stage MUD are exemplified. The analytical and simulated results demonstrate that this approach can reduce the MUD complexity significantly under any load conditions without performance loss. Copyright © 2009 John Wiley & Sons, Ltd.     

Delay constrained uplink scheduling policy for rtPS/ertPS service in IEEE 802.16e BWA systems

WiMAX is a promising broadband wireless networking technology and is expected to take the place of broadband access solutions such as DSL and cable. Owing to its superior support in mobility, it is expected to provide integrated voice and data service to realize broadband mobile computing. In order to reach better quality‐of‐service (QoS) requirements for real‐time applications, the IEEE 802.16e standard defines five different services among traffic categories with different multimedia requirements. However, the problem of choosing the right set of medium access control parameters and packet scheduling policy to provide strict QoS guaranteed in IEEE 802.16e Broadband Wireless Access (BWA) systems remains unsolved and left as an open issue. In this paper, we propose a novel polling‐based uplink packet scheduling policy for real‐time Polling Service and extended real‐time Polling Service (rtPS/ertPS) traffic to support real‐time applications, with strict delay requirements, such as variable bit rate (VBR) traffic in IEEE 802.16e BWA systems. The proposed transmit‐permission policy can derive sufficient conditions such that all the rtPS/ertPS sources satisfy their time constraints to provide deterministic QoS guarantees. In addition to theoretical analysis, simulations are conducted to evaluate the performance of the proposed scheme. As it turns out, our design provides a good quality performance in the IEEE 802.16e BWA systems. Copyright © 2008 John Wiley & Sons, Ltd.     

Temporal Anti‐aliasing of a Stereoscopic 3D Video

Frequency domain analysis is a fundamental procedure for understanding the characteristics of visual data. Several studies have been conducted with 2D videos, but analysis of stereoscopic 3D videos is rarely carried out. In this paper, we derive the Fourier transform of a simplified 3D video signal and analyze how a 3D video is influenced by disparity and motion in terms of temporal aliasing. It is already known that object motion affects temporal frequency characteristics of a time‐varying image sequence. In our analysis, we show that a 3D video is influenced not only by motion but also by disparity. Based on this conclusion, we present a temporal anti‐aliasing filter for a 3D video. Since the human process of depth perception mainly determines the quality of a reproduced 3D image, 2D image processing techniques are not directly applicable to 3D images. The analysis presented in this paper will be useful for reducing undesirable visual artifacts in 3D video as well as for assisting the development of relevant technologies.     

Performance of a mesoscale liquid fuel‐film combustion‐driven TPV power system

Combustion‐driven thermophotovoltaic (TPV) systems have obtained increasing attention in recent decades, but most studies have focused on developing narrowband photovoltaic cells and selective emitters. In terms of the heat source, conventional combustion configurations and light gaseous fuels are extensively utilized in macro‐ or meso‐scale TPV power systems to simplify thermal management and mechanical fabrication. As far as miniaturization is concerned, however, fuelling these systems with liquid hydrocarbons would provide inherent advantages of high energy density and low volatility. Liquid fuels also promise easy and safe fuel recharging for small‐scale power systems. In this paper, a central porous‐medium combustor was employed in a small scale TPV power system. The combustor incorporated an emitting chamber wall and a heat recuperator. The radiant efficiency and overall efficiency were compared using different liquid hydrocarbon fuels in the system. The electric output characteristics of the combustion driven TPV system have been investigated to demonstrate the feasibility of a GaSb cell‐based TPV power system and to provide design guidance for mesoscale liquid‐burning TPV systems. Copyright © 2008 John Wiley & Sons, Ltd.     

PbS and CdS Quantum Dot‐Sensitized Solid‐State Solar Cells: “Old Concepts,New Results”

Lead sulfide (PbS) and cadmium sulfide (CdS) quantum dots (QDs) are prepared over mesoporous TiO₂ films by a successive ionic layer adsorption and reaction (SILAR) process. These QDs are exploited as a sensitizer in solid‐state solar cells with 2,2′,7,7′‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD) as a hole conductor. High‐resolution transmission electron microscopy (TEM) images reveal that PbS QDs of around 3 nm in size are distributed homogeneously over the TiO₂ surface and are well separated from each other if prepared under common SILAR deposition conditions. The pore size of the TiO₂ films and the deposition medium are found to be very critical in determining the overall performance of the solid‐state QD cells. By incorporating promising inorganic QDs (PbS) and an organic hole conductor spiro‐OMeTAD into the solid‐state cells, it is possible to attain an efficiency of over 1% for PbS‐sensitized solid‐state cells after some optimizations. The optimized deposition cycle of the SILAR process for PbS QDs has also been confirmed by transient spectroscopic studies on the hole generation of spiro‐OMeTAD. In addition, it is established that the PbS QD layer plays a role in mediating the interfacial recombination between the spiro‐OMeTAD⁺ cation and the TiO₂ conduction band electron, and that the lifetime of these species can change by around 2 orders of magnitude by varying the number of SILAR cycles used. When a near infrared (NIR)‐absorbing zinc carboxyphthalocyanine dye (TT1) is added on top of the PbS‐sensitized electrode to obtain a panchromatic response, two signals from each component are observed, which results in an improved efficiency. In particular, when a CdS‐sensitized electrode is first prepared, and then co‐sensitized with a squarine dye (SQ1), the resulting color change is clearly an addition of each component and the overall efficiencies are also added in a more synergistic way than those in PbS/TT1‐modified cells because of favorable charge‐transfer energetics.     

Selective Determination of Dopamine on a Boron‐Doped Diamond Electrode Modified with Gold Nanoparticle/Polyelectrolyte‐coated Polystyrene Colloids

Negatively charged gold nanoparticles (AuNPs) and a polyelectrolyte (PE) have been assembled alternately on a polystyrene (PS) colloid by a layer‐by‐layer (LBL) self‐assembly technique to form three‐dimensional (Au/PAH)₄/(PSS/PAH)₄ multilayer‐coated PS spheres (Au/PE/PS multilayer spheres). The Au/PE/PS multilayer spheres have been used to modify a boron‐doped diamond (BDD) electrode. Cyclic voltammetry is utilized to investigate the properties of the modified electrode in a 1.0 M KCl solution that contains 5.0 × 10^?3 M K₃Fe(CN)₆, and the result shows a dramatically decreased redox activity compared with the bare BDD electrode. The electrochemical behaviors of dopamine (DA) and ascorbic acid (AA) on the bare and modified BDD electrode are studied. The cyclic voltammetric studies indicate that the negatively charged, three‐dimensional Au/PE/PS multilayer sphere‐modified electrodes show high electrocatalytic activity and promote the oxidation of DA, whereas they inhibit the electrochemical reaction of AA, and can effectively be used to determine DA in the presence of AA with good selectivity. The detection limit of DA is 0.8 × 10^?6 M in a linear range from 5 × 10^?6 to 100 × 10^?6 M in the presence of 1 × 10^?3 M AA.     

Temperature Responsive Solution Partition of Organic–Inorganic Hybrid Poly(N‐isopropylacrylamide)‐Coated Mesoporous Silica Nanospheres

A series of poly(N‐isopropylacrylamide)‐coated mesoporous silica nanoparticle materials (PNiPAm‐MSNs) has been synthesized by a surface‐initiated living radical polymerization with a reversible addition–fragmentation chain transfer (RAFT) reaction. The structure and the degree of polymerization of the PNiPAm‐MSNs has been characterized by a variety of techniques, including nitrogen sorption analysis, ²⁹Si and ¹³C solid‐state NMR spectroscopy, transmission electron microscopy (TEM), and powder X‐ray diffraction (XRD). The thermally induced changes of the surface properties of these polymer‐coated core–shell nanoparticles have been determined by examining their partition activities in a biphasic solution (water/toluene) at different temperatures.     

Efficient TiO2 Photocatalysts from Surface Hybridization of TiO2 Particles with Graphite‐like Carbon

Surface hybridization of TiO₂ with graphite‐like carbon layers of a few molecular layers thickness yields efficient photocatalysts. Photoelectrochemical measurements confirm an electronic interaction between TiO₂ and the graphite‐like carbon. A TiO₂ photocatalyst with a carbon shell of three molecular layers thickness (～1 nm) shows the highest photocatalytic activity which is about two times higher than that of Degussa P25 TiO₂ under UV light irradiation. The mechanism of the enhanced photocatalytic activity under UV irradiation is based on the high migration efficiency of photoinduced electrons at the graphite‐like carbon/TiO₂ interface, which is due to the electronic interaction between both materials. In addition, a high activity under visible light irradiation is observed after graphite‐like carbon hybridization. TiO₂'s response is extended into the visible range of the solar spectrum due to the electronic coupling of π states of the graphite‐like carbon and conduction band states of TiO₂.     

Organic Phenolic Configurationally Locked Polyene Single Crystals for Electro‐optic and Terahertz Wave Applications

We investigate a configurationally locked polyene (CLP) crystal 2‐(3‐(4‐hydroxystyryl)‐5,5‐dimethylcyclohex‐2‐enylidene)malononitrile (OH1) containing a phenolic electron donor, which also acts as a hydrogen bond donor. The OH1 crystals with orthorhombic space group Pna2₁ (point group mm2) exhibit large second‐order nonlinear optical figures of merit, high thermal stability and very favorable crystal growth characteristics. Higher solubility in methanol and a larger temperature difference between the melting temperature and the decomposition temperature of OH1 compared to analogous CLP crystals, are of advantage for solution and melt crystal growth, respectively. Acentric bulk OH1 crystals of large sizes with side lengths of up to 1 cm with excellent optical quality have been successfully grown from methanol solution. The microscopic and macroscopic nonlinearities of the OH1 crystals are investigated theoretically and experimentally. The OH1 crystals exhibit a large macroscopic nonlinearity with four times larger powder second harmonic generation efficiency than that of analogous CLP crystals containing dimethylamino electron donor. A very high potential of OH1 crystals for broadband THz wave emitters in the full frequency range of 0.1–3 THz by optical rectification of 160 fs pulses has been demonstrated.     

Instruction‐Level Power Estimator for Sensor Networks

In sensor networks, analyzing power consumption before actual deployment is crucial for maximizing service lifetime. This paper proposes an instruction‐level power estimator (IPEN) for sensor networks. IPEN is an accurate and fine grain power estimation tool, using an instruction‐level simulator. It is independent of the operating system, so many different kinds of sensor node software can be simulated for estimation. We have developed the power model of a Micaz‐compatible mote. The power consumption of the ATmega128L microcontroller is modeled with the base energy cost and the instruction overheads. The CC2420 communication component and other peripherals are modeled according to their operation states. The energy consumption estimation module profiles peripheral accesses and function calls while an application is running. IPEN has shown excellent power estimation accuracy, with less than 5% estimation error compared to real sensor network implementation. With IPEN's high precision instruction‐level energy prediction, users can accurately estimate a sensor network's energy consumption and achieve fine‐grained optimization of their software.