Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.     

Model of cold crystallization of uniaxially oriented poly(ethylene terephthalate) fibers

The differential scanning calorimeter heating curves of uniaxially oriented poly(ethylene terephthalate) (PET) fibers with three peaks were analyzed by using a newly proposed equation. The diffusion-controlled crystallization theory is suitable for describing cold crystallization of uniaxially oriented PET fibers. A crystallization model was proposed based on the kinetic parameters obtained. The model embraces the three sub-processes of crystallization corresponding to different growth geometries. The first sub-process corresponds to the nucleation of ordered molecular segments or the radial growth of preformed nucleus, resulting in the shorter bundle-like entities. The second sub-process corresponds to further growth of the bundle-like crystallites along chain direction, resulting in the longer bundle-like entities. The third sub-process corresponds to the three-dimensional growth of crystallites relating to the random segments, resulting in the spherical entities.     

Simultaneous spectrophotometric determination of copper(II), lead(II) and cadrnium(II)

The full spectrum technique in the fourier domain was studied for simultaneous determination of Cu(II), Pb(II) and Cd(II) with 4-(2-pyridylazo) resorcinol (PAR). A program called SPGRFSQ. was designed to perform the calculations. Seven error functions were calculated for deducing the number of factors. Data reduction was performed using principal component analysis (PCA) algorithm. Experimental results showed the method to be successful even where there was severe overlap of spectra.     

发电系统短期可靠性评估的等效机组法

本文提出了等效机组的概念,有效地解决了发电系统短期可靠性评估中的“状态爆炸”难题该方法不仅提高了短期可靠性评估的速度和精度,而且极大地压缩了计算存贮量,使发电系统短期可靠性评估更趋于实用化.通过对示例发电系统进行短期可靠性评估,其结果证明了该方法的正确性和有效性.     

TEM IMAGING TECHNIQUE

This imaging technique is used for approximate interpretation of TEM data including ungrounded loopsource and grounded line source soundings.Loop source data can be collected as central-loop soundings or asout-of-loop soundings with a short or long offset configuration.The imaging method is based on the same princi-ple as that employed by Fullager(1989),with apparent resistivities computed directly from time-derivative data,db/d,and then associated with depths according to image theory.     

安钢SAP预留系统的开发与应用

本文简述了安钢信息化建设概况,介绍了安钢信息化建设中开发SAP预留系统的设计流程,阐述了预留系统实现的功能.     

计算机及网络技术与现代继续临床医学教育

计算机网络技术是现代信息技术的核心内容,其运用于现代临床医学教育前景广阔,不但适用范围广,教学效率也相当的高。计算机多媒体是现代临床教学的重要手段,而网络技术的使用特使教学内容噩方式发生根本性变革。根据目前计算机技术已深入到医学诊断、治疗及科研领域且发展迅速的现状,提出在继续医学教育中开展计算机知识学习的问题,并针对不同年龄段卫生工作者的具体情况进行了探讨并提出了相应的对策,这对于提高卫生工作者的综合素质也有着重要的意义。     

Computational simulation of Belousov–Zhabotinskii oscillating chemical reaction

The suitability of computational simulation of the Belousov–Zhabotinskii oscillating chemical reaction by differential kinetic methodology for resolving nonlinear multi-component system is demonstrated in this work. According to the Field–KÖrÖs–Noyes mechanism and the Oregonator model, the change of the concentrations of HBrO₂, bromide ion and cerium ion are simulated. The results of computational simulation are consistent with experimental results very well. At the same time, the effect of variables and parameters, especially the rate constant on the oscillation curve, are investigated deeply. A simple method of estimating rate constants is obtained through simulation the concentrations of key components of the system, and then comparison the simulation results with the experimental ones. The reasonable rate constant is also proposed.     

Infrared target tracking based on proximal robust principal component analysis method

Applied Intelligence - Infrared target tracking plays an important role in both civil and military fields. The main challenges in designing a robust and high-precision tracker for infrared...