Selective Functionalization of Microstructured Surfaces by Laser‐Assisted Particle Transfer

Microcavity arrays represent millions of different reaction compartments to screen, for example, molecular interactions, exogenous factors for cells or enzymatic activity. A novel method is presented to selectively synthesize different compounds in arrays of microcavities with up to 1 000 000 cavities per cm². In this approach, polymer microparticles with embedded pre‐activated monomers are selectively transferred into microcavities with laser radiation. After particle patterning, heating of the particle matrix simultaneously leads to diffusion and coupling of the monomers inside each microcavity separately. This method exhibits flexibility, not only in the choice of compounds, but also in the choice of particle matrix material, which determines the chemical reaction environment. The laser‐assisted selective functionalization of microcavities can be easily combined with the intensively growing number of laser applications for patterning of molecules and cells, which is useful for the development of novel biological assays.     

Large Nonclassical Electrostriction in (Y,Nb)‐Stabilized δ‐Bi2O3

Classical electrostriction, describing a second‐order electromechanical response of insulating solids, scales with elastic compliance, S, and inversely with dielectric susceptibility, ε. This behavior, first noted 20 years ago by Robert Newnham, is shown to apply to a wide range of electrostrictors including polymers, glasses, crystalline linear dielectrics, and relaxor ferroelectrics. Electrostriction in fluorite ceramics of (Y, Nb)‐stabilized δ‐Bi₂O₃ is examined with 16%–23% vacant oxygen sites. Given the values of compliance and dielectric susceptibility, the electrostriction coefficients are orders of magnitude larger than those expected from Newnham's scaling law. In ambient temperature nanoindentation measurements, (Y, Nb)‐stabilized δ‐Bi₂O₃ displays primary creep. These findings, which are strikingly similar to those reported for Gd‐doped ceria, support the suggestion that ion conducting ceramics with the fluorite structure, a large concentration of anion vacancies and anelastic behavior, may constitute a previously unknown class of electrostrictors.     

Optimization of parameters of the linear TOF-SIMS spectrometer by DOE method

Time of flight SIMS spectrometers are widely used in many industrial and scientific applications. Mass spectra of secondary ions ejected from a bombarded surface supply valuable data on its composition and give insights into physical and chemical processes at the surface. The data quality depends on several parameters, which control the spectrometer functioning. This contribution presents our work on an application of a so-called Design of Experiments (DOE) procedure to optimize working parameters of a home-assembled linear TOF-SIMS spectrometer. The efficiency of optimization procedures was tested for mass spectra of positive ions sputtered from Al surface under keV Ar ion bombardment. In particular, we show that use of the method leads to a large increase both of the mass resolution and of the signal/noise ratio (S/N), i.e. improves two quantities, which play a crucial role in mass spectrometry measurements. In addition, it is shown that DOE' method allows to reduce significantly the number of test measurements, and therefore to shorten the adjusting procedure to a minimum.     

An observer‐metamerism sensitivity index for electronic displays

The effect of observer metamerism induced by electronic displays depends to a large extent on their primary spectra (red, green, and blue in the most common case). In particular, for narrow‐band primary spectra whose peak wavelength lies in the range of high variability of the observer's color‐matching function, some observers can experience very large differences between actual surface colors (e.g. in a light booth) and displayed colors if the monitor is optimized for the International Commission on Illumination (CIE) 1931 standard observer. However, because narrow‐band light‐emitting diodes lead to larger color gamuts, more and more monitors with very narrow band primaries are coming onto the market without manufacturers taking into account the associated problem of observer variations. Being able to measure these variations accurately and efficiently is therefore an important objective. In this paper, we propose a new approach to predict the extent of observer metamerism for a particular multiprimary display. Unlike existing dedicated models, ours does not depend on a reference illuminant and a set of reflectance spectra and is computationally more efficient.     

Community perception of the Klimkówka Reservoir in Poland

This article presents the results of a survey on how people perceive the Klimkówka storage reservoir located on the Ropa River in the Polish Carpathians. The analysis focused on establishing the role of various factors which impact the assessment of the reservoir by the local community. Community perception of the reservoir was analyzed in relation to several aspects linked to the reservoir itself, e.g. the risk of dam failure, feeling of safety, pros and cons, and how accustomed people were to the reservoir. A crucial issue was to identify how the real threat of a flood, experienced by people living below the dam, affected the way people perceived the reservoir. As a result of the analysis, a hierarchy of factors which determine people's assessment of large hydraulic structures was established. The results can be applied to determine specific measures aimed at limiting negative community perception of water infrastructure.     

Anomalous independence of multiple exciton generation on different group IV-VI quantum dot architectures

Multiple exciton generation (MEG) in PbSe quantum dots (QDs), PbSe(x)S(1-x) alloy QDs, PbSe/PbS core/shell QDs, and PbSe/PbSe(y)S(1-y) core/alloy-shell QDs was studied with time-resolved optical pump and probe spectroscopy. The optical absorption exhibits a red-shift upon the introduction of a shell around a PbSe core, which increases with the thickness of the shell. According to electronic structure calculations this can be attributed to charge delocalization into the shell. Remarkably, the measured quantum yield of MEG, the hot exciton cooling rate, and the Auger recombination rate of biexcitons are similar for pure PbSe QDs and core/shell QDs with the same core size and varying shell thickness. The higher density of states in the alloy and core/shell QDs provide a faster exciton cooling channel that likely competes with the fast MEG process due to a higher biexciton density of states. Calculations reveal only a minor asymmetric delocalization of holes and electrons over the entire core/shell volume, which may partially explain why the Auger recombination rate does not depend on the presence of a shell.     

无线局域网--展望未来

符合802．11b标准的无线局域网为市场上无线网络的发展搭建了稳定的平台。WiFi标准可保证不同厂商产品的互操作性，从而确保最终消费者投资的安全。随着与802．11b同在2．4GHz带宽上运行的更新的802．11g网络的推出，无线网络得到进一步发展。它们既能支持更高速率(最大54Mb/秒)，又具有向下兼容的特性。此外，消费者也可以选择在5GHz带宽的速率上运行802．11a     

Analysis of wet oxidation process after initial thermohydrolysis of excess sewage sludge

The authors propose a new technique to analyse a complex process of wet oxidation of excess sewage sludge by separating thermohydrolysis that results in the separation of sewage sludge into hydrolysates: solid and liquid products, from the basic process of oxidation of the two products. Wet oxidation kinetics was studied at different temperatures of both products based on the measurement of total organic carbon during the process with the use of a PARR high-pressure reactor. Decomposition of the liquid product leads to the formation of non-degradable and gaseous final products, while degradation of the solid product-via an intermediate liquid product-also leads to the formation of final and gaseous products. Solution of the kinetic equations that describe the dependence of relative organic carbon concentration on time is well illustrated by experimental results. On the basis of fitting theoretical curves to the experimental results, the kinetic parameters of the process were determined.