Living carbocationic polymerization

Mono- and bifunctionaltert-alcohols, i.e., cumyl alcohol (CumOH), 2,4,4-trimethyl-2-pentanol (TMPOH), 2,6-dihydroxy-2,4, 4, 6-tetramethylheptane (TMHDiOH), in conjunction with BCl₃ have been shown to be efficient initiating systems for the living polymerization of isobutylene (IB) in CH₃Cl or CH₂Cl₂ solvents in the –10° to –80°C range. The living nature of the polymerizations was demonstrated by linear M_n versus amount of polyisobutylene (PIB) formed (W_PIB) plots starting at the origin and corresponding horizontal number of PIB moles formed (N) versus W_PIB plots. Quenching with methanol producestert-chlorine terminated PIBs. Quantitative dehydrochlorination of the latter products yields exo-olefin (isopropylidene) end groups. These experiments demonstrate that living carbocationic polymerizations have in fact been conducted in these laboratories long ago (1) without having been recognized as such.     

A psychometric study of the McMaster Family Assessment Device in psychiatric, medical, and nonclinical samples.

Investigated the psychometric properties of the McMaster Family Assessment Device (FAD [N. Epstein et al; see PA, Vol 71:2891]), a multidimensional measure of family functioning, using data from psychiatric (n?=?1,138), nonclinical (n?=?627), and medical (n?=?298) samples. Internal scale reliabilities and factorial validity were assessed for each group, and results were compared across groups. In general, scale reliabilities were favorable and the hypothesized factor structure of the FAD was supported. Results also support the use of the 60-item version over the original 53-item version. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Assessment of edema using STIR+ via 3D cardiovascular magnetic resonance imaging in patients with suspected myocarditis

Objective

To evaluate three-dimensional T2-weighted fast spin echo triple inversion recovery sequences (STIR+) for the diagnosis of myocardial edema in patients with suspected early myocarditis after respiratory or gastrointestinal tract viral infection and at follow-up.

Materials and methods

We prospectively examined 28 patients with suspected myocarditis and 37 controls matched for gender and age. An ECG-triggered STIR+ was used to cover the entire left ventricle in short-axis images with 10-mm slice thickness and no interslice gap. The global signal intensity ratio (heart muscle in relation to skeletal muscle) was calculated (global STIR+ ratio) to evaluate edema. All patients had repeat examinations at follow-up (mean interval 4.9 months, 1–12 months).

Results

The mean global STIR+ ratio was 2.15 ± 0.4 in the initial examination of patients as compared to 1.78 ± 0.3 in controls (p < 0.0001) and 1.89 ± 0.3 in patients at follow-up (p = 0.0001 vs. first visit). Left ventricular ejection fraction did not differ between patients and controls at baseline and at follow-up.

Conclusion

We could identify a significantly higher global STIR+ ratio in patients with suspected myocarditis compared to controls, and a dynamic change during follow-up. The global STIR+ ratio may, therefore, be useful for the diagnosis of myocarditis and should be further explored.

     

The Vortex Path Model Analysis of the Field Angle Dependence of the Critical Current Density in Nanocomposite YBa2Cu3 O 7−x – BaZrO3 Films Obtained by Low Fluorine Chemical Solution Deposition

In the present paper, we analyze the role of in situ grown BaZrO₃ (BZO) inclusions in YBa₂Cu₃O_7?x (YBCO) thin films prepared by chemical solution deposition using a low fluorine coating solution, on the field angle dependence of the critical current density, J _c (??), data using the vortex path model. In order to form a coherent picture on the BZO doping influence on the pinning properties of the YBCO matrix, detailed structural analyses performed by X-ray diffraction techniques and microstructural evaluation by transmission electron microscopy are also presented. The evaluation of different contributions to the overall, J _c , permitted us to prove the effectiveness of the BZO inclusions acting as isotropic pinning centers, reflected in a uniform component of high relative value with respect to other components. For the studied 10 mol % BZO doping concentration, a threefold increase in the critical current density, J _c , of the YBCO host is measured, in self-field at 77 K, corresponding to a value of J _c =2.9MA/cm², whereas a factor 10 is measured at 1 T (J _c =0.35 MA/cm²).     

Switched-Capacitor Track-and-Hold Amplifiers With Low Sensitivity to Op-Amp Imperfections

This paper describes high-precision switched-capacitor (SC) track-and-hold amplifier (THA) stages. They use a novel continuous-time correlated double sampling (CDS) scheme to desensitize the operation to amplifier imperfections. Unlike earlier predictive-CDS amplifiers, the circuits do not need a sampled-and-held input signal for their operation. During the tracking period, an auxiliary continuous-time signal path is established, which predicts the output voltage during the holding period. This allows accurate operation even for low amplifier gains and large offsets over a wide input frequency range. Extensive simulations were performed to compare the performance of the proposed THAs with earlier circuits utilizing CDS. The results verify that their operation is far more robust than that of any previously described SC amplifiers     

In situ electrochemical impedance spectroscopy of Zr–1%Nb under VVER primary circuit conditions

Oxide layers were grown on tubular samples of Zr–1%Nb under conditions simulating those in VVER-type pressurised water reactors, viz. in near-neutral borate solutions in an autoclave at 290 °C. These samples were investigated using electrochemical impedance spectroscopy which was found to be suitable to follow in situ the corrosion process. A –CPE_oxR_ox– element was used to characterise the oxide layer on Zr–1%Nb. Both the CPE_ox coefficient, σ_ox, and the parallel resistance, R_ox, were found to be thickness dependent. The layer thickness, however, can only be calculated after a calibration procedure. The temperature dependence of the CPE_ox element was also found to be anomalous while the temperature dependence of R_ox indicates that the oxide layer has semiconductor properties. The relaxation time – defined as (R_oxσ_ox)^1/ – was found to be quasi-independent of oxidation time and temperature; thus it is characteristic to the oxide layer on Zr–1%Nb.     

Development and qualitative assessment of the GAME(Cycle) exercise system.

Increased physical activity is important for reducing the risk of cardiovascular disease. However, among people with disabilities, inactivity is prevalent. In order to encourage exercise among members of this group, an exercise system combining arm ergometry with video gaming, called the GAME(Cycle) was previously developed. User input was received through an arm crank ergometer on a swivel, with the angular velocity of the ergometer resistance wheel controlling one axis and rotation of ergometer about the swivel controlling the other. The purpose of this study was to detail the algorithms used in this device and present novel features included in a second generation of the GAME(Cycle). The features include a wheel on base, a steering return mechanism, and wireless fire buttons. A focus group of clinicians (n = 8), wheelchair users (n = 8), and clinician wheelchair users (n = 2) was conducted to evaluate the features of the GAME(Cycle). The focus group suggested improvements to the steering mechanism and to reduce vibration in the system. However, the focus group enjoyed the GAME(Cycle) and felt that it would encourage exercise among persons with disabilities.