N,N''-取代邻苯二胺的合成

通过2-取代苯并咪唑盐的还原开环反应制备了8个N,N′-不同取代的邻苯二胺,并经1HNMR、IR、MS及元素分析表征,其中5个未见文献报道.这是一条由邻苯二胺和羧酸经2.取代苯并咪唑制取该类化合物的简洁合成路线.     

一种环氧树脂阻尼灌封胶的热氧加速老化研究

研究了某种环氧树脂阻尼灌封胶在热氧老化的作用下分子结构、硬度、断面形貌以及动态力学性能随时间的变化．傅立叶红外光谱图表明，所制备的样品环氧基团反应比较完全，热氧老化后试样表面由仲胺和环氧基团形成的酯键发生了部分断裂和氧化；邵氏硬度的增加、瓦向高温区移动则表明在老化过程中复杂的固化反应仍然继续进行；最大损耗因子（tanδmax）波动较小表明试样老化后分子结构几乎保持不变；SEM图片显示试样的冲击断裂由老化前的韧性转变为老化后的脆性断裂．     

均匀设计法分析制备过程对钴钼硫化物催化剂机械强度的影响

建立了CoMoP/Al2O3加氢精制催化剂机械强度及其可靠性在制备过程中的数学模型,采用均匀设计考察了浸渍、干燥、煅烧、硫化4个制备过程中,浸渍时间、干燥温度、干燥时间、煅烧温度、煅烧时间、硫化温度和硫化升温速率7个实验因子对催化剂强度均值、Weibull模量的影响,同时考察了这些因素对颗粒密度的影响。方差分析表明所有模型都是充足的。实验结果表明,硫化过程是影响催化剂强度均值的主要过程。在实验范围内提高硫化温度、降低硫化时的升温速率有利于提高催化剂的强度。影响催化剂Weibull模量的因素主要为各个制备过程的交互效应。要提高催化剂强度的可靠性就必须全面考虑催化剂制备的各个过程,特别是各个制备过程的交互效应。     

VC++实现的串口通讯数据处理

说明了在异步串行通信(RS-232)的工作方式下,对所接收的数据进行接收、处理,丢弃乱码,并进行保存的可靠方法,并给出了相关的VC 语言程序.     

Aging response of the young’s modulus and mechanical properties of Ti-29Nb-13Ta-4.6Zr for biomedical applications

Alloys for implant devices require improved strength but a reduced Young’s modulus, in order to become mechanically more compatible with adjacent bone tissues. In this study, a new metastable β-type titanium alloy, Ti-29Nb-13Ta-4.6Zr (wt pct), was subjected to aging treatment to produce different microstructures, and the resulting mechanical properties, including the Young’s modulus, were measured. The Young’s modulus of this alloy is found to be sensitive to microstructures generated by various heat treatments. For microstructures varying from (α + β) to (α + β + ω) and (β + ω), the Young’s modulus increases with an accompanying increase in tensile strength and hardness, but decreases in ductility. The (β + ω) microstructure has a low strength, high modulus, and poor ductility and cannot be used for biomedical applications. For an (α + β) microstructure, the volume fraction of the phases is shown to be the main factor that determines the mechanical properties.     

A distributed adverse drug reaction detection system using intelligent agents with a fuzzy recognition‐primed decision model

Discovering unknown adverse drug reactions (ADRs) in postmarketing surveillance as early as possible is highly desirable. Nevertheless, current postmarketing surveillance methods largely rely on spontaneous reports that suffer from serious underreporting, latency, and inconsistent reporting. Thus these methods are not ideal for rapidly identifying rare ADRs. The multiagent systems paradigm is an emerging and effective approach to tackling distributed problems, especially when data sources and knowledge are geographically located in different places and coordination and collaboration are necessary for decision making. In this article, we propose an active, multiagent framework for early detection of ADRs by utilizing electronic patient data distributed across many different sources and locations. In this framework, intelligent agents assist a team of experts based on the well‐known human decision‐making model called Recognition‐Primed Decision (RPD). We generalize the RPD model to a fuzzy RPD model and utilize fuzzy logic technology to not only represent, interpret, and compute imprecise and subjective cues that are commonly encountered in the ADR problem but also to retrieve prior experiences by evaluating the extent of matching between the current situation and a past experience. We describe our preliminary multiagent system design and illustrate its potential benefits for assisting expert teams in early detection of previously unknown ADRs. © 2007 Wiley Periodicals, Inc. Int J Int Syst 22: 827–845, 2007.     

Fast algorithms for determining the linear complexity of sequences over GF(p/sup m/) with period 2/sup t/n

We prove a result which reduces the computation of the linear complexity of a sequence over GF(p^m) (p is an odd prime) with period 2n (n is a positive integer such that there exists an element bisinGF(p^m), bⁿ=-1) to the computation of the linear complexities of two sequences with period n. By combining with some known algorithms such as the Berlekamp-Massey algorithm and the Games-Chan algorithm we can determine the linear complexity of any sequence over GF(p^m) with period 2^tn (such that 2 ^t|p^m-1 and gcd(n,p^m-1)=1) more efficiently     

一种发出红色荧光的六核配合物[Cu6（pymt）6]

合成了一价铜和2-巯基嘧啶盐的配合物[Cu6（pymt）6]并进行结构分析，该配合物能发出强的红色荧光。其中，一价铜离子的配位环境为变形平面三角形，陪体pymt采用μ3-S2N桥联方式参与配位。