Rheological properties and foam processibility of precured EPDM

EPDM foam was prepared by dynamically vulcanizing EPDM compound in a HAAKE rheometer firstly, then mixing the partially precured EPDM compound with a blowing agent and a sulfur vulcanizing system on a two roll mill. The compound was extruded through a cold feed extruder, and the extrudate was foamed in a circulating hot air oven. EPDM compound was vulcanized partly in the HAAKE rheometer, the final torque increases with increasing sulfur content. Rheological measurement shows the dynamic storage modulus, the loss modulus, and the complex viscosity of precured EPDM compound increase with increasing sulfur content. Then the partially precured EPDM compound was compounded with a blowing agent and a sulfur vulcanizing systems, Rheometric measurement shows that the rate of vulcanization of partially precured EPDM compound is not affected by the precure. The blowing results show that the foam processibility could be improved and the expansion ratio increases in the same processing condition for optimum partially precured EPDM compound, which indicates the optimum crosslink density for EPDM could enhance the efficiency of blowing agent AC. SEM shows that the foam articles have a closed‐cell structure with few open cells, and the large cells inlay among the small cells. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3387–3394, 2006     

催化裂化装置分馏塔的技术改造

为解决抚顺石化石油一厂催化裂化装置产品分离效果不好、生产低凝柴油困难等问题,对分馏塔进行了技术改造.改造后,产品分离系统操作弹性增大,操作稳定性增强,产品质量得到改善,产品分布更趋合理.     

3-碘代-2-炔丙基丁基氨基甲酸酯的合成

介绍了一种水相合成杀菌剂3-碘代-2-炔丙基丁基氨基甲酸酯的方法:以2-炔丙基-丁基氨基甲酸酯、碘为主要原料,水为溶剂,次氯酸钠为氧化剂进行反应,试验了温度、原料配比、时间等反应条件,得出了最佳工艺条件,所得产物含量≥98.5%,收率为90%～92%(以碘计)。     

共挤保护膜研究概况

介绍了共挤保护膜的特点及国外发展现状以及共挤保护膜所用基材种类及特点，压敏胶主要成分及作用。     

框架结构护岸新技术在城市河道中的应用

好溪堰河是贯穿浙江省丽水市主城区的一条千年古河道,在河道整治过程中,受制于河道周边的密集建筑物,传统的河道护岸技术均难以同时满足水利、市政、交通及景观的多元化要求。在分析其他创新河道护岸技术特点及存在问题的基础上,提出了适用于城市河道的桩柱式、框柱式两种框架结构护岸新技术,这两种护岸在维护河道周边建筑物稳定的同时,均具有不加深河床就可拓宽河道过流断面、不减少河岸用地、保持岸路畅通、改善水质及生态效果、提高亲水性等优点,在丽水好溪堰河水系整治工程中应用较为成功。     

FLOW REGIME TRANSITIONS IN GAS-LIQUID JET-PUMP REACTOR

It is found that the reactor has four types of flow regimes:a,b,c,and d,of which b is desirable inoperation.Therefore it is essential to find the criteria for flow regime transitions.On the basis of momen-tum,energy and mass balance principles,theoretical criteria are obtained and agree well with the experi-mental results,which can be expressed ascri1     

State space approximation for general fractional order dynamic systems

Approximations for general fractional order dynamic systems are of much theoretical and practical interest. In this paper, a new approximate method for fractional order integrator is proposed. The poles of the approximate model are unrelated to the order of integrator. This feature shows benefits on extending the algorithm to the systems containing various fractional orders. Then a unified approximate method is derived for general fractional order linear or nonlinear dynamic systems via combining the proposed new method with the distributed frequency model approach. Numerical examples are given to show the wide applicability of our method and to illustrate the acceptable accuracy for approximations as well.     

一种核壳结构复合磁性纳米粒子的设计与制备

利用改性葡聚糖作为表面活性剂参与的化学共沉积法制备了壳核结构的磁性复合纳米粒子,核心为氧化铁,外包葡聚糖.在优化实验条件下,可得复合粒子的平均粒径为7.7 nm,核心氧化铁的平均粒径为5 nrn.详细研究了制备过程中各种影响因素碱源采用快速滴加的方法;控制n(Fe2+)n(Fe3+)的摩尔比;葡聚糖的用量;控制反应时间和反应温度.并对磁性复合纳米粒子的形态、结构、磁化率和平均粒径进行了表征.     

Coordinating efficiency and equity in disaster relief logistics via information updates

This paper addresses a multi-supplier, multi-affected area, multi-relief, and multi-vehicle relief allocation problem in disaster relief logistics. A multi-objective optimisation model based on disaster scenario information updates is proposed in an attempt to coordinate efficiency and equity through timely and appropriate decisions regarding issues such as vehicle routing and relief allocation. An optimal stopping rule is also proposed to determine the optimum period of delay before responding to disaster, because decision making requires accurate disaster information. The main contribution of this paper is solving relief allocation problem in a novel way by correlating operational research with statistical decision making and Bayesian sequential analysis. Finally, a case is presented based on the post-disaster rescue in Eastern China after supertyphoon Saomai to test the applicability and show the potential advantages of the proposed model.     

焦化柴油不安定因素考察

对焦化柴油的不安定因素进行了研究.通过研究发现,焦化柴油中的酸性物质、碱性物质、微量金属及可见光均是影响焦化柴油安定性的因素,空气对焦化柴油的安定性影响较小.