Kinetics of two-step anionic polymerization

This article deals with the kinetics of two-step anionic polymerization by way of a non-steady state method. Several molecular parameters can be evaluated using the formulae developed. A bimodal molecular weight distribution function for the resulting polymer is derived from the set of kinetic differential equations, which is in agreement with the experimental data reported.     

测定钠中杂质的手动阻塞计的研究

文章介绍了测定钠中杂质浓度的手动阻塞计的原理、装置和实验结果。为了减少测量误差,我们研究了影响准确测定阻塞温度的因素,并且找到了减少测量误差的办法。在同样的杂质饱和温度下,该阻塞计测得的高、低阻塞温度所对应的杂质浓度差是很接近的。对氧其差值为1.03ppm;对氢为0.0763ppm。     

气缸可靠性试验装置的研制

为了进行气缸可靠性试验研究,针对缸径为50mm、行程为160mm的气缸研制了一套气缸可靠性试验装置.5个月的不间断试验测试及获得的大量数据表明,该装置运行稳定可靠,满足了气缸可靠性试验的要求.详细介绍了装置试验回路的构成、工作原理和具体实现,测控子系统的硬件构成和软件流程,气缸性能参数测量方法及获得的部分数据.     

应用事故树法对深水井控进行风险评估

深水井喷事故危害极大，严重时可导致井眼报废、船毁人亡等恶性后果，预防和控制深水井喷是国内外石油界的一个技术难题。文中利用风险树分析引发深水钻井工程事故的顶事件，重点讨论各底事件的相互联系及对系统的影响程度，分析顶事件的发生概率，为最大程度地减少深水井控事故的发生提供理论依据。通过对深水钻井过程中存在的风险进行分析，构建了深水井控风险分析事故树，并对其进行了定性与定量分析。通过风险分析，认为深水井控最主要的影响因素是关井及压井时设备故障、设计方法及操作失误的影响超过安全极限。分析表明，降低基本事件的发生概率对预防井喷作用明显，基本事件发生概率提高1倍，井喷发生概率提高近10倍。针对深水井控过程中存在的风险因素，从工艺、装备及人员要求方面提出了预防深水井喷的措施。     

N,N''-取代邻苯二胺的合成

通过2-取代苯并咪唑盐的还原开环反应制备了8个N,N′-不同取代的邻苯二胺,并经1HNMR、IR、MS及元素分析表征,其中5个未见文献报道.这是一条由邻苯二胺和羧酸经2.取代苯并咪唑制取该类化合物的简洁合成路线.     

Dye adsorption characteristics of alginate/polyaspartate hydrogels

This study examined the removal of some basic dyes, such as Methylene Blue, Malachite Green and Methyl Orange, using alginate or alginate/polyaspartate composite gel beads. The adsorption of dyes from aqueous solutions at 25 °C was examined using a batch sorption technique. The effects of CaCl₂ and the dye concentration on the adsorption were examined. Type-S adsorption isotherms were obtained, which is characteristic of a weak solute–solid interaction. The ionic interaction between the dye molecule and gel matrix appears to be responsible for the efficient adsorption of cationic dyes in this system. These results suggest that an alginate/polyaspartate gel can be used as an effective sorbent for water pollutants such as dyes, and the immobilization of these organic contaminants in the hydrogels from wastewater can solve one of the most important environmental problems in the related industry.