Due to their unique optical properties, diamonds are the most valued gemstones. However, beyond the sparkle, diamonds have a number of unique properties. Their extreme hardness gives them outstanding performance as abrasives and cutting tools. Similar to many materials, their nanometer‐sized form has yet other unique properties. Nanodiamonds are very inert but still can be functionalized on the surface. Additionally, they can be made in very small sizes and a narrow size distribution. Nanodiamonds can also host very stable fluorescent defects. Since they are protected in the crystal lattice, they never bleach. These defects can also be utilized for nanoscale sensing since they change their optical properties, for example, based on temperature or magnetic fields in their surroundings. In this Review, in vivo applications are focused upon. To this end, how different diamond materials are made and how this affects their properties are discussed first. Next, in vivo biocompatibility studies are reviewed. Finally, the reader is introduced to in vivo applications of diamonds. These include drug delivery, aiding radiology, labeling, and use in cosmetics. The field is critically reviewed and a perspective on future developments is provided. 相似文献
Cloud computing environment is getting more interesting as a new trend of data management. Data replication has been widely applied to improve data access in distributed systems such as Grid and Cloud. However, due to the finite storage capacity of each site, copies that are useful for future jobs can be wastefully deleted and replaced with less valuable ones. Therefore, it is considerable to have appropriate replication strategy that can dynamically store the replicas while satisfying quality of service (QoS) requirements and storage capacity constraints. In this paper, we present a dynamic replication algorithm, named hierarchical data replication strategy (HDRS). HDRS consists of the replica creation that can adaptively increase replicas based on exponential growth or decay rate, the replica placement according to the access load and labeling technique, and finally the replica replacement based on the value of file in the future. We evaluate different dynamic data replication methods using CloudSim simulation. Experiments demonstrate that HDRS can reduce response time and bandwidth usage compared with other algorithms. It means that the HDRS can determine a popular file and replicates it to the best site. This method avoids useless replications and decreases access latency by balancing the load of sites. 相似文献
This study investigated the carbon nanotube's aspect ratio's influence on the nanocomposite foams' cellular structure and mechanical, acoustic absorption characteristics. The free-rising foaming process has been used for producing different flexible polyurethane (PU) foams embedded with other multi-walled carbon nanotubes (MWCNT's). Dynamic mechanical and thermal analysis, flow resistivity, and compressive mechanical measurements were achieved on the prepared samples. The acoustic absorption coefficient in a wide range of frequencies was estimated for the prepared PU/CNT foamed nanocomposite samples. Results indicated that by increasing the aspect ratio of MWCNT, the absorption coefficient's peak shifts toward the lower frequencies and improved sound absorption characteristics of PU foam in the low-frequency region. Moreover, the Young modulus of nanocomposite samples increases by increasing the aspect ratio of MWCNT's, whereas the stored strain energy or area under the stress–strain curve increases. Based on the obtained results, it is observed that the acoustic absorption coefficient of produced nanocomposite foams at the frequency of 800 Hz has been reported to have a 70% improvement in 2 cm samples and a 40% improvement in 3 cm samples compared to obtained results from pure PU foam. 相似文献
This work explores the effect of ternary nanostructure for the enhanced photocatalytic degradation of pollutants and dyes. One-pot solvothermal-assisted approach was used for producing nanosized Pt@TiO2 hybrid nanoparticles (NPs) decorated on reduced graphene oxide (rGO) layers. The microstructure, morphology, chemical composition, and optical absorption of the designed photocatalyst was successfully characterized (using XRD, TEM, Raman, UV–visible absorption spectra, and XPS techniques). The ternary Pt@TiO2-rGO photocatalyst consist of monodisperse quasi-spherical Pt@TiO2 NPs with an average size of 11 nm deposited on the rGO nanosheets. Furthermore, Pt@TiO2-rGO was further investigated for the photodegradation of pesticide and dyes under UV and visible light. The ternary Pt@TiO2-rGO photocatalyst proved a significant improvement on the photodecomposition of pollutants compared to hybrid Pt@TiO2. The Pt@TiO2-rGO photocatalyst was found to show seven- and threefold increase in the photocatalytic activity compared to TiO2 and Pt@TiO2 NPs, respectively which resulted from the high surface area of rGO and as well as the strong Pt/TiO2/rGO interactions which ensured excellent properties of charge separation. On the other hand, the ternary photocatalyst exhibited very good recycle and reuse capacity up to five cycles.