Efficiency,recovery and productivity of continuous reverse osmosis systems: new closed expressions

Numerical and approximate analytical solutions for salt concentration polarization in hyperfiltration with laminar flow in a flat sheet configuration are presented. The analysis accounts for the variation of the water flux in the longitudinal direction. Approximate solutions were obtained with an integral method which was found to provide good agreement with the numerical solution. The integral method allows one to obtain closed expressions for the productivity Q, the recovery R and the efficiency E of a reverse osmosis system which can be applied relatively quickly in design calculations.In this analysis the physical properties of the solution are taken to be constant.     

ATOMISTIC MOLECULAR DYNAMICS SIMULATIONS OF GAS DIFFUSION AND SOLUBILITY IN RUBBERY AMORPHOUS HYDROCARBON POLYMERS

Diffusion coefficients D of H 2 , He, O 2 , N 2 , and CO 2 in different rubbery amorphous polymeric matrices were estimated by atomistic molecular dynamics simulations at 298 K using the Einstein relationship, and compared with the relevant experimental values, where available. The simulated diffusion coefficients D of all the gases in all polymers considered almost regularly decreased with increasing molecular gas volumes and increasing polymer glass transition temperature. Further, solubility coefficients and heats of solution were obtained for all gases from Grand Canonical Monte Carlo simulations, which were also used to calculate sorption isotherms. In general, there is a good agreement between experimental and simulated values of diffusion and solubility coefficients for all gases considered.     

Fabrication of hybrid proton-exchange membranes using a brandnew high temperature ionic liquid as charge transporting and clay modifier

The search for more compatibility between ionic liquids (ILs) and polymer matrices in proton-exchange membrane fuel cells (PEMFCs) is one of the ways in which IL leaking from proton-exchange membranes could be minimized. In this work, it is presented the synthesis of an aromatic high temperature ionic liquid (HTIL), which, incorporated into an aromatic matrix such as sulfonated polyether ether ketone (sPEEK), is expected to diminish the IL leaking that normally affects PEMFC. Phenylethylammonium trifluoromethane sulfonate (PhetaTfO) was successfully synthesized and characterized. Its melting point of 88°C makes it to classify as a HTIL and it was employed as modifier of natural Montmorillonite, forming the phenylethylammonium intercalated montmorillonite (MmtPheta) and thus, ternary membranes containing PhetaTfO, MmtPheta, and sPEEK were prepared and characterized. Immersion tests demonstrated a higher compatibility of PhetaTfO with matrix when compared to the reference DemaTfO, which was reflected in up to 30% lower IL loss by the synthesized IL than the DemaTfO; X-rays diffraction (XRD) patterns demonstrated that the modified clay was properly dispersed inside the membranes, while dynamic mechanical analyses (DMA) results indicated a strong plasticizer effect along the increase of PhetaTfO content inside the membrane, while at the same time, the conductivity increased in an exponential manner, which permitted to identify an empiric exponential equation to evaluate the effect of concentration on ionic conductivity. The maximum conductivity obtained at IL concentrations of around 38 wt% was 0.2 mS/cm. It could expect high ionic conductivities of 10 mS/cm when the concentration of this IL is 60%; nevertheless, in order to achieve that, crosslinking treatments should be done to give the membranes enough mechanical resistance.     

An alternative,layout‐driven approach to the clustering of documents

Internet has become a huge repository of information and knowledge, based on the sharing of the electronic documents. Last trends in knowledge management focus on the knowledge representation based on the document content. In fact, most accustomed approaches achieve the document understanding by analyzing the “portions of information'' in the document which describe the content, through techniques of text parsing and extraction. This paper presents an alternative approach that departs from the consolidated techniques of document management and focuses on the logical structure of a PDF document as a discriminating source of document knowledge. The main idea is based on the fact, when the reader looks at a paper, his first perception is related to the layout of the document. The analysis of layout, typesetting, paginating, and graphical arrangement of a document provides interesting information about its content understanding; in general, the documents that are in the same category present similar page layout, fonts, and figures arrangement. In this sense, this work presents an alternative way to deal with documents recognition and understanding, through the analysis of the layout of electronic PDF documents and their classification. © 2008 Wiley Periodicals, Inc.     

Solid state bonding of Al2O3 with Cu, Ni and Fe: characteristics and properties

A solid state bonding technique under hot pressing was used for joining alumina with thin metal sheets of Ni, Cu and Fe. The microstructure and microchemistry of the ceramic–metal interface and of the fracture interface were examined using scanning electron microscopy (SEM) energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD), in order to identify the adhesion mechanisms and the nature of strength limiting flaws. Interaction between the selected metals and alumina can be physical or physico-chemical in nature: very low amounts of interfacial compounds were formed, depending on the processing conditions and on the presence of oxygen in the system. Fracture and toughness tests indicated that high ceramic–metal interface strengths (up to 177 MPa) were achieved under the adopted processing conditions and that strength and toughness were directly related. Moreover, an increase in hardening in the metal interlayer at a distance of 2–3 m from the interface was observed in the samples with high strength values. The mechanical behaviour was related to several factors that strongly depend on the bonding conditions: plastic deformation of the metal, metal creep, metal intrusion and diffusion into alumina, and chemical reactions at the interface. © 1998 Chapman & Hall     

Boosting learning and inference in Markov logic through metaheuristics

Markov Logic (ML) combines Markov networks (MNs) and first-order logic by attaching weights to first-order formulas and using these as templates for features of MNs. State-of-the-art structure learning algorithms in ML maximize the likelihood of a database by performing a greedy search in the space of structures. This can lead to suboptimal results because of the incapability of these approaches to escape local optima. Moreover, due to the combinatorially explosive space of potential candidates these methods are computationally prohibitive. We propose a novel algorithm for structure learning in ML, based on the Iterated Local Search (ILS) metaheuristic that explores the space of structures through a biased sampling of the set of local optima. We show through real-world experiments that the algorithm improves accuracy and learning time over the state-of-the-art algorithms. On the other side MAP and conditional inference for ML are hard computational tasks. This paper presents two algorithms for these tasks based on the Iterated Robust Tabu Search (IRoTS) metaheuristic. The first algorithm performs MAP inference and we show through extensive experiments that it improves over the state-of-the-art algorithm in terms of solution quality and inference time. The second algorithm combines IRoTS steps with simulated annealing steps for conditional inference and we show through experiments that it is faster than the current state-of-the-art algorithm maintaining the same inference quality.     

Textures on Rank‐1 Lattices

Storing textures on orthogonal tensor product lattices is predominant in computer graphics, although it is known that their sampling efficiency is not optimal. In two dimensions, the hexagonal lattice provides the maximum sampling efficiency. However, handling these lattices is difficult, because they are not able to tile an arbitrary rectangular region and have an irrational basis. By storing textures on rank‐1 lattices, we resolve both problems: Rank‐1 lattices can closely approximate hexagonal lattices, while all coordinates of the lattice points remain integer. At identical memory footprint texture quality is improved as compared to traditional orthogonal tensor product lattices due to the higher sampling efficiency. We introduce the basic theory of rank‐1 lattice textures and present an algorithmic framework which easily can be integrated into existing off‐line and real‐time rendering systems.     

小议JavaScript库——Dojo、jQuery和PrototypeJS的比较

这是一篇小文章,讨论了JavaScript的应用库,JavaScript是最近两年飞速发展的技术领域,希望这篇文章能引发你的兴趣,帮助你进入这个领域。     

理解LINQ-to-SQL

大多数Web应用程序都是以数据驱动的,并且以关系数据库为中心。然而,多年来架构师已经设计了通过对象来建模问题域的应用程序。对象和关系数据库之间的通信一直都不流畅和简单。建立这类通信时遇到的困难通常称为“对象/关系阻抗失配”（O/ RM）。需要一个持久层来保存对象和从关系表载入对象。这些年来,产生了许多设计样式,为从事这项任务的架构师提供指南。现在,开发人员可以自己编写整个持久层,或者借助像NHibernate或Genome等O/RM工具的帮助,进行设计。     

The effect of ionising radiation on photosynthetic oxygenic microorganisms for survival in space flight revealed by automatic photosystem II-based biosensors

Photosynthetic microorganisms are expected to be useful to maintain an oxygenic atmosphere and to provide biomass for astronauts in the International Space Station as well as in future long-term space flights. However, fluxes of complex ionizing radiation of various intensities and energies make space an extreme environment for the microorganisms, affecting their photosynthetic efficiency. To automatically monitor the photosynthetic Photosystem II (PSII) activity of microorganisms under space conditions an optical biosensor, which utilizes chlorophyll fluorescence as biological transduction system, was built; the PSII activity was monitored by the biosensor during balloon flights at stratospheric altitudes of about 40 km. The effect of space stress on quantum yield of PSII varied among the tested species depending on the growth light conditions at which they were exposed during the flights.