Simulation-based optimization of ecological leasing: a step toward extended producer responsibility (EPR)

In recent years, due to severe environmental legislations and extended producer responsibility, leasing has been recommended as a strategy for increasing resources productivity and minimizing waste generation during consumption and product end-of-life (EOL) phase. Hence, it is essential to develop a model that can help leasing company for achieving sustainable production management. In this paper, a model is developed which optimizes the environmental and economical impact of product during leasing and its EOL phase from customers and leasing company point of view. To solve the problem, simulation-based optimization approach is investigated and the integrated mathematical and simulation model is developed for incorporating uncertainty during leasing period. Finally a case study with data from industry is used to validate the approach and potential applications of the developed model are illustrated.     

Lean blowoff of bluff body stabilized flames: Scaling and dynamics

This paper overviews the dynamics of bluff body stabilized flames and describes the phenomenology of the blowoff process. The first section of the paper provides an overview of the fluid mechanics of the non-reacting and reacting bluff body wake flow. It highlights the key features of the flow (the boundary layer, separated shear layer, and wake), the flow instabilities that influence each of these features, and the influences of the flame on these instabilities. A key point from these studies is the large differences between the non-reacting wake (dominated by an absolutely unstable, sinuous instability associated with vortex shedding from the bluff body) and the reacting wake of high dilatation ratio flames. The latter are dominated by the lower intensity, convective instability of the shear layer. Very low dilatation ratio flames begin to approach the behavior of the non-reacting wake, as might be expected.     

Synergistic evaluation of AgO2 nanoparticles with ceftriaxone against CTXM and blaSHV genes positive ESBL producing clinical strains of Uro‐pathogenic E. coli

The silver oxide nanoparticles (AgO₂ ‐NPs) were synthesised using silver foil as a new precursor in wet chemical method. X‐ray diffraction analysis shows crystallographic structures of AgO₂ ‐NPs with crystallite size of 35.54 nm well‐matched with standard cubic structure. Scanning electron microscopy analysis clearly shows the random distribution of spherical‐shaped nanoparticles. Energy dispersive X‐ray analysis confirmed the purity of the samples as it shows no impurity element. Fourier transforms infra‐red analysis confirmed the formation of AgO₂ ‐NPs with the presence of Ag‐O‐Ag stretching bond. All the techniques also confirmed the loading of ceftriaxone drug on the surface of AgO₂ ‐NPs. This study also described the effect of AgO₂ ‐NPs having synergistic activity with β lactam antibiotic i.e. ceftriaxone against ESBL generating Escherichia coli (E. coli). Among isolated strains of E. coli, 60.0% were found to be ESBL producer. The synergistic activities of AgO₂ ‐NPs with ceftriaxone suggest that these combinations are effective against MDR‐ESBL E. coli strains as evident by increase in zone sizes. The present study observed rise in MDR‐ESBL E. coli with polymorphism of blaCTXM and blaSHV causing UTI infections in Pakistani population. The antibiotic and AgO₂ ‐NPs synergistic effect can be used as an efficient approach to combat uro‐pathogenic infections.Inspec keywords: antibacterial activity, nanofabrication, nanomedicine, drugs, nanoparticles, microorganisms, crystallites, scanning electron microscopy, silver compounds, X‐ray diffraction, X‐ray chemical analysis, Fourier transform infrared spectra, organic compounds, geneticsOther keywords: synergistic evaluation, clinical strains, silver oxide nanoparticles, silver foil, wet chemical method, X‐ray diffraction analysis, crystallographic structures, standard cubic structure, spherical‐shaped nanoparticles, energy dispersive X‐ray analysis, ceftriaxone drug, synergistic activity, ESBL producer, scanning electron microscopy, Fourier transform infrared analysis, Escherichia coli, blaSHV gene positive ESBL, crystallite size, random distribution, β lactam antibiotics, MDR‐ESBL E. coli strains, polymorphism, blaCTXM, uro‐pathogenic infections, uro‐pathogenic E. coli, AgO₂      

Response surface optimization of the purification process of cyclotrimethylenetrinitramine explosive via digestion in binary solvent mixtures of acetone/water

The present study introduces a new route for the purification of cyclotrimethylenetrinitramine (RDX) explosive containing cyclotetramethylenetetranitramine (HMX) impurity, based on the digestion of crude materials in the binary solvent of acetone/water. Here, first, the solubility data, enthalpy of dissolution and mixing of RDX and HMX were determined experimentally in binary solvent. Then, the effects of various factors on the purification of RDX were studied statistically via response surface methodology (RSM) experimental design. In this technique, unlike the solubility data, unexpectedly HMX was dissolved with higher ratio and solid RDX was obtained with purity >99.5 wt.% and improved crystal morphology.     

Configuration and installation design of optical diagnostic systems on KSTAR

The optical diagnostic system of KSTAR consists of visible diagnostics including toroidal and poloidal Hα monitors, a visible survey spectrometer, and filterscopes. A re-entrant cassette made of stainless steel, containing five optical quartz windows has been developed to allow easy access of the visible diagnostics to the plasma. The configuration and manufacturing design of the diagnostic cassette and the installation of optical diagnostic systems within the cassette are described. The structural and thermal analysis of the diagnostic cassette and in situ calibration of optical diagnostics have also been performed. The optical lens system showed good image quality by spot diagram analysis.     

Large magnetocaloric effect and magnetoresistance in ErNi single crystal

The magnetic properties,magnetocaloric effect and magnetoresistance in ErNi single crystal have been investigated in detail.With decreasing temperature,ErNi single crystal undergoes two successive mag-netic transitions:a paramagnetic to ferromagnetic transition at Tc=11 K and a spin-reorientation transition at TSR=5 K.Meanwhile,a sharp field-induced metamagnetic transition is observed below the Tc along the a axis.ErNi single crystal possesses a giant magnetocaloric effect around Tc.The maximum magnetic entropy change is-36.1 J(kg K)-1 along the a axis under the field change of 0-50 kOe.In par-ticular,the rotating magnetocaloric effect in ErNi single crystal reaches its maximum under a relatively low field,and the maximum rotating entropy change with a value of 9.3 J(kg K)-1 is obtained by rotat-ing the applied field from the[011]to[100]directions under 13 kOe.These results suggest that ErNi could be a promising candidate for magnetic refrigeration working at liquid-helium temperature region.Moreover,a complicated transport behavior is uncovered in ErNi single crystal,which is attributed to the complex magnetic states and magnetic polaronic effect.Both positive and negative magnetoresistance are observed.A considerable large magnetoresistance with the value of-34.5％is acquired at 8 K under 50 kOe when the field is along the[100]direction.     

Nonlinear fractional‐order power system stabilizer for multi‐machine power systems based on sliding mode technique

This paper presents two novel nonlinear fractional‐order sliding mode controllers for power angle response improvement of multi‐machine power systems. First, a nonlinear block control is used to handle nonlinearities of the interconnected power system. In the second step, a decentralized fractional‐order sliding mode controller with a nonlinear sliding manifold is designed. Practical stability is achieved under the assumption that the upper bound of the fractional derivative of perturbations and interactions are known. However, when an unknown transient perturbation occurs in the system, it makes the evaluation of perturbation and interconnection upper bound troublesome. In the next step, an adaptive‐fuzzy approximator is applied to fix the mentioned problem. The fuzzy approximator uses adjacent generators relative speed as own inputs, which is known as semi‐decentralized control strategy. For both cases, the stability of the closed‐loop system is analyzed by the fractional‐order stability theorems. Simulation results for a three‐machine power system with two types of faults are illustrated to show the performance of the proposed robust controllers versus the conventional sliding mode. Additionally, the fractional parameter effects on the system transient response and the excitation voltage amplitude and chattering are demonstrated in the absence of the fuzzy approximator. Finally, the suggested controller is combined with a simple voltage regulator in order to keep the system synchronism and restrain the terminal voltage variations at the same time. Copyright © 2014 John Wiley & Sons, Ltd.     

Effect of surface properties of polysulfone support on the performance of thin film composite polyamide reverse osmosis membranes

In this work, influence of initial conditions and surface characteristics of porous support layer on structure and performance of a thin film composite (TFC) polyamide reverse osmosis (RO) membrane was investigated. The phase inversion method was used for casting of polysulfone (PSf) supports and interfacial polymerization was used for coating of polyamide layer over the substrates. The effect of PSf concentrations that varied between 16 wt % and 21 wt %, and kind of the solvent (DMF and NMP) used for preparation of initial casting solution were investigated on the properties of the final RO membranes. SEM imaging, surface porosity, mean pore radius, and pure water flux analysis were applied for characterization of the supports. The substrate of the membrane, which synthesized with 18 wt % of PSf showed the most porosity and the synthesized RO membrane had the lowest salt rejection. In case of the solvents, the membranes synthesized with DMF presented better separation performance that can be attributed to their lower thickness and sponge‐like structure. The best composition of support for TFC RO membranes reached 16 wt % PSf in DMF solvent. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44444.     

Estimation of Clark’s Instantaneous Unit Hydrograph Parameters and Development of Direct Surface Runoff Hydrograph

We present a method to estimate Time of Concentration (T _c) and Storage Coefficient (R) to develop Clark’s Instantaneous Unit Hydrograph (CIUH). T _c is estimated from Time Area Diagram of the catchment and R is determined using optimization approach based on Downhill Simplex technique (code written in FORTRAN). Four different objective functions are used in optimization to determine R. The sum of least squares objective function is used in a novel way by relating it to slope of a linear regression best fit line drawn between observed and simulated peak discharge values to find R. Physical parameters (delineation, land slope, stream lengths and associated drainage areas) of the catchment are derived from SPOT satellite imageries of the basin using ERDAS: Arc GIS is used for geographic data processing. Ten randomly selected rainfall–runoff events are used for calibration and five for validation. Using CIUH, a Direct surface runoff hydrograph (DSRH) is developed. Kaha catchment (5,598 km²), part of Indus river system, located in semi-arid region of Pakistan and dominated by hill torrent flows is used to demonstrate the applicability of proposed approach. Model results during validation are very good with model efficiency of more than 95% and root mean square error of less than 6%. Impact of variation in model parameters T _c and R on DSRH is investigated. It is identified that DSRH is more sensitive to R compared to T _c. Relatively equal values of R and T _c reveal that shape of DSRH for a large catchment depends on both runoff diffusion and translation flow effects. The runoff diffusion effect is found to be dominant.