X-ray investigation of sintered cadmium doped hydroxyapatites

Pure and cadmium (Cd) doped hydroxyapatites (HA, Ca₁₀(PO₄)₆(OH)₂) were synthesized by a precipitation method from aqueous solutions of Ca(NO₃)₂4·H₂O for the former and Cd(NO₃)₂4·H₂O for the latter, by using (NH₄)₂HPO₄ as the phosphate source, while pH was kept in the range of 11–12. The effect of incorporation of Cd²⁺ ions into the structure of HA was investigated after the air sintering at 1100 °C for 1 h. The results indicate that Cd²⁺ addition into HA yields nearly fully densified products with respect to pure stoichiometric HA. The XRD patterns showed that Cd doping increases the crystallinity of HA. The 2, 4.4, and 8.8 mol% Cd doped HAs had calcium oxide (CaO) impurity phase in their lattice. The CaO phase in the HA structure gradually disappeared with increasing Cd amount, and was replaced with cadmium oxide (CdO) in the CdHA doped with 11 mol% Cd. Cd²⁺ ion incorporation decreased the a- and c-axis lattice constants and unit cell volume of HA.     

Tuning fuzzy PD and PI controllers using reinforcement learning

In this paper, we propose a new auto-tuning fuzzy PD and PI controllers using reinforcement Q-learning (QL) algorithm for SISO (single-input single-output) and TITO (two-input two-output) systems. We first, investigate the design parameters and settings of a typical class of Fuzzy PD (FPD) and Fuzzy PI (FPI) controllers: zero-order Takagi–Sugeno controllers with equidistant triangular membership functions for inputs, equidistant singleton membership functions for output, Larsen’s implication method, and average sum defuzzification method. Secondly, the analytical structures of these typical fuzzy PD and PI controllers are compared to their classical counterpart PD and PI controllers. Finally, the effectiveness of the proposed method is proven through simulation examples.     

Electric load forecasting by using dynamic neural network

Electrical energy is fundamental for the wellbeing and for the economic development of any country. However, all countries must ensure access to essential resources and ensure the continuity of its supply. Due to the non-storable nature of electrical energy, the amount of consumed active power should always be equal the produced active power just to avoid power system frequency deviation problem. In order to keep the relationship production–consumption relation in compliance with different standards and to secure profitable operations of power system, electric load consumption must be predicted and controlled instantaneously. Several statistical and classical techniques are proposed in the literature but unfortunately all these methods are not accurate in a satisfactory manner. In this paper, a dynamic neural network is used for the prediction of daily power consumption. The suitability and the performance of the proposed approach is illustrated and verified with simulations on load data collected from French Transmission System Operator (RTE) website. The obtained results show that the accuracy and the efficiency are improved comparatively to conventional methods widely used in this field of research.     

Antennas and Propagation for On-Body Communication Systems

On-body communication channels are of increasing interest for a number of applications, such as medical-sensor networks, emergency-service workers, and personal communications. This paper describes investigations into channel characterization and antenna performance at 2.45 GHz. It is shown that significant channel fading occurs during normal activity, due primarily to the dynamic nature of the human body, but also due to multipath around the body and from scattering by the environment. This fading can be mitigated by the use of antenna diversity, and gains of up to 10 dB are obtained. Separation of the antenna's performance from the channel characteristics is difficult, but results show that for many channels, an antenna polarized normal to the body's surface gives the best path gain. Simulation and modeling present many challenges, particularly in terms of the problem's scale, and the need for accurate modeling of the body and its movement.     

Influence of weathering on adhesion strength of chemically treated and coated Scotch pine

The objective of this study was to evaluate the effect of weathering on adhesion strength of Scotch pine (Pinus sylvestris L.) samples treated with three concentrations of Tanalith-E. Treated samples were also coated with polyurethane, synthetic and water based varnishes prior to 500 h accelerated weathering test. Adhesion strength between varnishing materials and substrate samples was determined employing pull-off type equipment. Based on the findings in this work adhesion strength values of samples decreased with increasing concentration of treatment chemical. The highest average strength value was found as 3.48 MPa for untreated control samples while 2.88 MPa was the lowest average value for the samples treated with Tanalith-E having 9% concentration and coated with water based varnish. Majority of the failures took place within the adhesion line between coating and the substrate with a very limited torn fibers. Results of statistical analysis revealed that samples coated with three different types of varnishes did not show any significant difference from each other at 95% confidence level. It was also found that chemical treatment of the samples adversely influenced their overall adhesion strength characteristics.     

Fatigue Crack Tip Plasticity for Inclined Cracks

The evaluation of the crack tip deformation is essential to the estimation of crack growth under either static or cyclic loading. A 3-D elastic–plastic finite element analysis was developed to simulate the crack tip deformation along mixed mode inclined edge cracks in a steel plate subjected to either monotonic or cyclic loading at selected R-ratios. In this paper, two types of crack configurations were investigated: inclined cracks with equal inclined lengths (EICL) and inclined cracks with equal horizontal projection length (ECHP). The development of the monotonic (Δm) and cyclic (Δc) crack tip plastically zones and the monotonic (CTOD) and cyclic (ΔCTOD) crack tip opening displacements were traced to find the effect of the crack inclination angle, which significantly affected the size and shape of the crack tip plastic zone. The finite element results compared well with the analytical results based on modified Dugdale’s model. It was observed that Mode II has a significant effect on the plastic zone in the case of equal inclined crack length (EICL), i.e., Mode II increases as the crack angle decreases. Also, it is interesting to note that for the EICL case, the magnitude of Δc is delayed to appear with decreasing the inclination angle, for example, for θ?=?90° the cyclic plastic zone appeared at Δσ?=?103.32 MPa, while for θ?=?45° the cyclic plastic zone appeared at Δσ?=?132.84 MPa. Whereas, the variation of monotonic and cyclic plastic zone size in the equal crack horizontal projection (ECHP) case is not affected by the crack inclination angle. Furthermore, it was observed that the static crack tip opening displacement (CTOD) and the cyclic (ΔCTOD) are independent of the crack inclination angle in case of ECHP, due to such cracks take into consideration the effect of inclination angle through its length.     

Adaptation of machining toolpath to distorted geometries: application to remove a constant thickness on rough casting prosthesis

This study proposes a method to adapt the geometry of the toolpath to a specified target. In the case study presented, the geometrical target is to remove a constant thickness on the rough workpiece. This case is normally present in the polishing of the femoral component of knee prostheses. In fact, an operator carries out these operations manually. The aim of this study is to contribute to the automation of prosthesis production, notably, in the preparation of surface polishing. The proposed method can deform and adapt a toolpath to ensure the required geometry of the machined surface. The proposed toolpath deformation method is composed of three steps: alignment, toolpath deformation, and toolpath smoothing. Alignment between the measured surface of the roughcast prostheses and the nominal toolpath is carried out by an Iterative Closest Point (ICP) algorithm. The principle of this algorithm is to find the optimal rigid transformation to readjust the toolpath on the measured surface. Subsequently, the toolpath is deformed to remove the constant thickness of the roughcast prostheses. Next, to increase the machined quality, a smoothing stage is carried out on the obtained toolpath. Experimental tests on industrial prostheses geometry are conducted to validate the effectiveness of this method.     

Xylitol: A Review on Bioproduction,Application, Health Benefits,and Related Safety Issues

Xylitol is a pentahydroxy sugar-alcohol which exists in a very low quantity in fruits and vegetables (plums, strawberries, cauliflower, and pumpkin). On commercial scale, xylitol can be produced by chemical and biotechnological processes. Chemical production is costly and extensive in purification steps. However, biotechnological method utilizes agricultural and forestry wastes which offer the possibilities of economic production of xylitol by reducing required energy. The precursor xylose is produced from agricultural biomass by chemical and enzymatic hydrolysis and can be converted to xylitol primarily by yeast strain. Hydrolysis under acidic condition is the more commonly used practice influenced by various process parameters. Various fermentation process inhibitors are produced during chemical hydrolysis that reduce xylitol production, a detoxification step is, therefore, necessary. Biotechnological xylitol production is an integral process of microbial species belonging to Candida genus which is influenced by various process parameters such as pH, temperature, time, nitrogen source, and yeast extract level. Xylitol has application and potential for food and pharmaceutical industries. It is a functional sweetener as it has prebiotic effects which can reduce blood glucose, triglyceride, and cholesterol level. This review describes recent research developments related to bioproduction of xylitol from agricultural wastes, application, health, and safety issues.     

Analysis of cooling curve to determine the end point of freezing

The cooling curve method used for the measurement of freezing point of food is further analyzed to explore whether it can be used to identify the end point of freezing or glass transition. In this method, slope of the cooling curve is determined and plotted as a function of time to identify the end point of freezing (T′_m). Initially, the slope is decreased and then reached a minimum value, which is identified as the nucleation of ice. Then the slope is increased until the end point of freezing. The end point of freezing is identified when the slope starts to decrease from its highest value or plateau. Sucrose solutions and starch gels were used to measure its T′_m in identifying validity of the proposed method. The measured values of T′_m by the proposed method is very close to the literature values.