An experimental study on multi‐purpose desiccant integrated vapor‐compression air‐conditioning system

In this paper, a multi‐purpose hybrid desiccant integrated vapor‐compression air‐conditioning system of a small capacity is experimentally investigated. The system, referred as hybrid desiccant‐assisted air conditioner (HDAC), is designed to meet the cooling load of spaces having large latent heat portions and at the same time to extract water from atmospheric air. The system is mainly consisted of a liquid‐desiccant dehumidification unit integrated with a vapor‐compression system (VCS). The dehumidification unit uses lithium chloride (LiCl) solution as the working material. The effect of different parameters, such as desiccant solution flow rate, process airflow rate, evaporator and condenser temperatures, strong solution concentration and regeneration temperature on the performance of the system, is studied. This system has a water recovery rate of 6.7 l/h TR (1.91 l/h kW) of pure water at typical north Egyptian climate (20–30°C dry bulb and 35–45% relative humidity). The HDAC system has a COP as high as 3.8 (an improvement of about 68% over the conventional VCS). The system offers a total cooling capacity of about 1.75 TR (6.15 kW) using a 0.75 TR (2.6 kW) VCS unit. Finally, the proposed system is found to have a payback time of about 10 months without any considerable extra capital cost compared with the known split air‐conditioning system. The results emphasize the potential benefits of the HDAC system. Copyright © 2010 John Wiley & Sons, Ltd.     

Curcumin antifungal and antioxidant activities are increased in the presence of ascorbic acid

The objective of this study was to evaluate the antifungal and antioxidant activities of curcumin, ascorbic acid and the mixture of these two compounds. For the antifungal assay, the minimum inhibitory concentrations (MIC) were determined using Candida strains (ATCC and clinical isolates). Curcumin alone inhibited growth of Candida albicans yeast cells, whereas ascorbic acid did not present effects. However, when the mixture of ascorbic acid and curcumin was assayed to determine the association of the two compounds, the curcumin MIC decreased 5- to 10-fold. In the antioxidant assays, the sum of the alone activities of curcumin and ascorbic acid were lower than the activity of the two-compound mixture. This study highlights the importance of the association between two common antioxidants in foods, to improve the antifungal and antioxidant activities of curcumin (in vitro), and can be applied to Candida spp. infection and diseases associated with oxidative stress.     

Determination of dyers’ perceived components of colour difference (depth,brightness and hue) between two similar colours from their spectral reflectance values

The partitioning of colour differences into ΔL^*, ΔC^* and ΔH^* is not directly equivalent to the dyer’s method of partitioning. The dyer’s method involves separation into the components of depth (ΔD), brightness (ΔB) and hue (ΔH), of which only hue difference has a qualitative (and quantitative) equivalent in the CIELAB system. Depth and brightness are important terms to dyers. Depth is related to the amount of dye taken up by a textile material and brightness to that component of colour difference that is neither depth nor hue. Brightness is best defined as the opposite of dullness, dullness being related to the amount of neutral grey present in the colour. An algorithm, called the Wardman–Smith–Farooq algorithm, has been developed to compute the dyers’ variables of ΔD,ΔB and ΔH from spectral reflectance values, enabling dyers to take full advantage of colorimetry. The algorithm is based on extensive experimental work to map surfaces of constant visual depth through the colour space and this paper describes the methodology of the calculation. The correlations of the values of ΔD,ΔB and ΔH, determined using the Wardman–Smith–Farooq algorithm with other empirical models for 117 sample pairs, are given.     

Assessment of organic acid-rich bio-sap to generate electricity

The study has focused on electricity generation from organic acid-rich bio-substrate like star fruit (Averrhoa carambola). The sap of star fruit was selected as an electrolyte due to the presence of significant amounts of organic acids such as citric acid and ascorbic acid. To preserve the sap, 2% phenol by volume was used to reduce the growth of microorganisms, and the addition of phenol did not affect the initial pH. It was observed that due to an increase in the electrode surface area, reaction rate and current generation had been amplified. Internal resistance also decreased rapidly because of the large electrode surface area. Furthermore, internal resistance was the significant barrier in electricity generation, which was also successfully controlled by the baffle flow agitation system. Moreover, the baffle flow agitation system reduces the formation of dead zones and increases the total dissolved solids inside the electrochemical cell compartments during operation.     

Formulation and characterisation of nanosuspension of herbal extracts for enhanced antiradical potential

Nanotechnology is a promising technique to increase the bioavailability of herbal medicines. This paper presents the nanosuspension approach for increasing the aqueous solubility and thereby bioactivity of important herbal extracts. Nanosuspensions of the seeds of three plants extract (Silybum marianum, Elettaria cardamomum and Coriandrum sativum) were prepared by using polyvinyl alcohol (1.5% w/v) as a stabiliser. Prepared nanoparticles were characterised by scanning electron microscope. Activity of nanosuspension formulation was assessed by using four in vitro antioxidant assays. S. marianum, E. cardamomum and C. sativum particle size was observed to fall in range of 446.1 ± 112.6, 456.63 ± 339.2 and 432.1 ± 172.8 nm, respectively, most of the particles were having spherical shape and smooth topology. These synthesised nanoparticles were found to be more effective against quenching free radical than their crude extracts and standards [butylated hydroxyl toluene and ascorbic acid]. C. sativum nanosuspension showed most free radical scavenging potential against 2,2-diphenyl-1-picrylhdrazyl (DPPH) and superoxide free radical scavenging assays (IC₅₀ 0.59 ± 0.01 and 0.81 ± 0.11 mg/ml). S. marianum nanosuspension was found to be most effective against DPPH radicals scavenging (IC₅₀ 0.34 ± 0.02 mg/ml). It was concluded that nanosuspension of herbal medicines potentiates the antioxidant potential.     

Thin-film iron-oxide nanobeads as bifunctional electrocatalyst for high activity overall water splitting

Developing only Fe derived bifunctional overall water splitting electrocatalyst both for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) while performing at low onset overpotential and with high catalytic stability is a rare instance. We present here the first demonstration of unique iron-oxide nanobeads (FeO_x-NBs) based electrocatalyst executing both OER and HER with high activity. Thin-film electrocatalytic FeO_x-NBs assembly is surface grown via simple spray coating (SC). The unique SC/FeO_x-NBs propels OER initiating water oxidation just at 1.49 V_RHE (η = 260 mV) that is the lowest observable onset potential for OER on simple Fe-oxide based catalytic films reported so far. Catalyst also reveals decently high HER activity and competent overall water splitting performance in the FeO_x-NBs two-electrode system as well. Catalyst also presents stable kinetics, with promising high electrochemically active surface area (ECSA) of 1765 cm², notable Tafel slopes of just 54 mV dec^1? (OER) and 85 mV dec^1? (HER), high exchange current density of 1.10 mA cm^2? (OER), 0.58 mA cm^2? (HER) and TOF of 74.29s^1?@1.58V_RHE, 262s^1?@1.62V_RHE (OER) and 82.5s^1?@-0.45V_RHE, 681s^1?@-0.56V_RHE (HER).     

Entanglement and Entropy Squeezing for Moving Two Two-Level Atoms Interaction with a Radiation Field

In this paper, we analyzed squeezing in the information entropy, quantum state fidelity, and qubit-qubit entanglement in a time-dependent system. The proposed model consists of two qubits that interact with a two-mode electromagnetic field under the dissipation effect. An analytical solution is calculated by considering the constants for the equations of motion. The effect of the general form of the time-dependent for qubit-field coupling and the dissipation term on the temporal behavior of the qubit-qubit entanglement, quantum state fidelity, entropy, and variance squeezing are examined. It is shown that the intervals of entanglement caused more squeezing for the case of considering the time-dependent parameters. Additionally, the entanglement between the qubits became more substantial for the case of time dependence. Fidelity and negativity rapidly reached the minimum values by increasing the effect of the dissipation parameter. Moreover, the amount of variance squeezing and the amplitude of the oscillations decreased considerably when the time dependence increased, but the fluctuations increased substantially. We show the relation between entropy and variance squeezing in the presence and absence of the dissipation parameter during the interaction period. This result enables new parameters to control the degree of entanglement and squeezing, especially in quantum communication.     

Synthesis of Ion Imprinted Polymers by Copolymerization of Zn(II) and Al(III)8-hydroxy Quinolone Complexes with Divinylbenzene and Methacryclic Acid

In this research work, Zinc(II) and Aluminum(III)-IIP's were synthesized by optimizing the amount of methacrylic acid as monomer, divinylbenzene as cross-linker. The IIP's were functionalized with 8-hydroxy quinolone complexes of the two metal ions under thermal conditions by copolymerization with monomer and cross-linker. The IIP's and Non-IIP's were characterized using FT-IR, TGA, and SEM analysis. A quite remarkable difference in the size was observed of the polymers (Zn(II) 1.0 µm and Al(III) 0.1 µm). A stronger affinity was observed with IIP in comparison with Non-IIP at pH 3.1 and 4.5 for Zn(II) and Al(III) ions on their respective polymers.