A Robust Experimental Methodology for Polymer Bubble Inflation

In thermoforming technique thermoplastic sheets are heated up well above their glass transition temperature and formed to the required shape by using an appropriate mold. Characterization of thermoplastic materials for thermoforming can be accomplished by employing polymer bubble inflation and rheology tests instead of undertaking expensive biaxial tensile testing. Polymer bubble inflation technique is very sensitive to process condition variations, so a robust experimental methodology is essential. Design and development of one such experimental system was undertaken by carrying out a variety of preliminary tests. This paper presents the experimental methodology developed for polymer bubble inflation. The developed experimental system demonstrates highly repeatable polymer bubble inflations. Bubble inflations were conducted at different temperatures and different diameter circular clamping using acrylonitrile butadiene styrene (ABS) thermoplastic. Polymer sheet initial sag due to heating and its influence on bubble inflation have been captured by using the experimental system.     

Adhesion and Debonding of Soft Elastic Films on Rough and Patterned Surfaces

With the help of simulations based on energy minimization, we have studied the effect of roughness of a rigid contactor with sinusoidal and step patterns on the adhesion-debonding cycle of a soft thin elastic film. The surface instability engendered by attractive forces between the contactor and the film produces a regularly spaced array of columns in the bonding phase. The inter-column spacing is governed largely by periodicity of the contactor pattern. Decreased periodicity of the pattern favors intermittent collapse of columns rather than a continuous peeling of contact zones. An increase in the amplitude of roughness decreases the maximum force required for debonding and increases the snap-off distance. The net effect results in a reduced work for debonding. Introduction of noise and increased step-size in simulations decreases the pull-off force and the snap-off distance, as in the case of a smooth contactor. Finally the study reveals that a patterned contactor can be used as a potential template in the patterning of soft interfaces.     

Entropy-Based Flow and Sediment Routing in Data Deficit River Networks

The reliable estimate of the sediment load and streamflow is essential for water resources and flood management. In this study, the entropy-based technique and HEC-RAS are used for flow routing followed by sediment routing in HEC-RAS. The paper’s novelty is its application to data-deficit river networks, where observed sediment load and flow on tributaries are absent. The proposed method accommodates the flow and sediment contribution from the tributaries to the downstream station on a reach, despite unavailable observed data on it. The adopted flow routing techniques are applied to predict downstream flow on three different reaches (on the Mahanadi and the Godavari River). The prediction accuracy is evaluated using three statistical indices ? Nash–Sutcliffe efficiency (NSE), relative error (RE), and Coefficient of determination (R²). Both flow routing techniques showed good performance for all three reaches (with or without tributaries), having NSE, R²?>?0.8, and RE?<?13%. Despite the comparable performance, the entropy-based routing is suggested for natural rivers with or without tributary as it avoids the iterative calibration process to determine the roughness coefficient. Further, the sediment routing is performed on the data-deficit reach of the Mahanadi River to obtain the best-suited sediment transport function. The simulated sediment load using the Yang transport function matched satisfactorily with the observed data with NSE, R²?>?0.85, and RE?<?–27%. Subsequently, the Yang transport function and entropy-based flow routing are utilized for the sediment and flow estimation at an ungauged station on the Mahanadi river.

     

Waves in nonlocal thermoelastic solids of type II

The present article deals with the investigation of the propagation of thermoelastic plane harmonic waves in a nonlocal thermoelastic medium. The Green and Naghdi theory II (without energy dissipation) of generalized thermoelasticity with elastic nonlocal effect is adopted to address this problem. The problem of reflection of thermoelastic waves due to an incident coupled longitudinal elastic wave from the rigid and thermally insulated boundary of a homogeneous, isotropic nonlocal thermoelastic half-space is also studied. The amplitude ratios of the reflected waves and their respective energy ratios are determined analytically. For a particular model, the effect of elastic nonlocality parameter on the variations of phase speeds, attenuation coefficients, amplitude ratios and corresponding energy ratios of the reflected waves is presented graphically and analysis of these results is given.     

Direction of arrival estimation based on temporal and spatial processing using a direct data domain (D/sup 3/) approach

The purpose of this paper is to estimate the direction of arrival (DOA) of the signal of interest (SOI) in the presence of both coherent and noncoherent interferences and multipath components utilizing a combined temporal and spatial processing technique based on a direct data domain approach. The concept of cyclostationarity, which deals with the temporal information of the SOI, is used to extract signals having the same cycle frequency and out the co-channel interferences and additive noise. Hence, the signal detection capability can be significantly increased over conventional filtering when the length of the data record is limited. The main contribution of the paper is that by combining temporal and spatial processing based on a direct data domain approach one can handle number of signals along with their various coherent and noncoherent multipaths and interferences which can exceed the number of antenna elements. Hence, this methodology may be advantageous over conventional spatial processing when the number of degrees of freedom can never exceed the number of antenna elements in the array. However, the number of multipaths and interferers at the same cycle frequency has to be less than approximately 66 % of the antenna elements. Since we do not form a covariance matrix of the data, this method is quite suitable for short data lengths or when the environment is quite dynamic. Hence, in the proposed algorithm, while the estimation of the cyclic array covariance matrix is avoided, we develop a new matrix form using extremely short data samples. As a result, the computational load in the proposed approach is relatively reduced and the robustness of the estimation of SOI is significantly improved when the number of available snapshots is extremely limited. Numerical results are presented to illustrate the efficiency and accuracy of this method.     

Self-assembled polyaniline nanorods synthesized by facile route of dispersion polymerization

We report the preparation of ordered polyaniline nanorod arrays by a simple method without the use of any template. The synthesis method is by a chemical route, viz. dispersion polymerization of aniline in polyvinyl alcohol. The nanorods obtained have a diameter of 100-500 nm and a length of a few micrometers. Films containing the nanorod assembly have been characterized by SEM, XRD and FTIR spectroscopy. We have also measured I-V characteristics and the temperature dependence of the conductivity of the films. We discuss the formation mechanism of the self-assembled nanostructures, the morphology of the films, and the crystallinity and the transport mechanism.     

Large Area Self-Assembled Ultrathin Polyimine Nanofilms Formed at the Liquid–Liquid Interface Used for Molecular Separation

Separation membranes with higher molecular weight cut-offs are needed to separate ions and small molecules from a mixed feed. The molecular sieving phenomenon can be utilized to separate smaller species with well-defined dimensions from a mixture. Here, the formation of freestanding polyimine nanofilms with thicknesses down to ≈14 nm synthesized via self-assembly of pre-synthesized imine oligomers is reported. Nanofilms are fabricated at the water–xylene interface followed by reversible condensation of polymerization according to the Pieranski theory. Polyimine nanofilm composite membranes are made via transferring the freestanding nanofilm onto ultrafiltration supports. High water permeance of 49.5 L m^-2 h⁻¹ bar⁻¹ is achieved with a complete rejection of brilliant blue-R (BBR; molecular weight = 825 g mol⁻¹) and no more than 10% rejection of monovalent and divalent salts. However, for a mixed feed of BBR dye and monovalent salt, the salt rejection is increased to ≈18%. Membranes are also capable of separating small dyes (e.g., methyl orange; MO; molecular weight = 327 g mol⁻¹) from a mixed feed of BBR and MO. Considering a thickness of ≈14 nm and its separation efficiency, the present membrane has significance in separation processes.