全文获取类型
收费全文 | 1190篇 |
免费 | 73篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 10篇 |
化学工业 | 298篇 |
金属工艺 | 20篇 |
机械仪表 | 16篇 |
建筑科学 | 12篇 |
能源动力 | 42篇 |
轻工业 | 298篇 |
水利工程 | 5篇 |
石油天然气 | 2篇 |
无线电 | 123篇 |
一般工业技术 | 209篇 |
冶金工业 | 95篇 |
原子能技术 | 3篇 |
自动化技术 | 138篇 |
出版年
2024年 | 9篇 |
2023年 | 26篇 |
2022年 | 85篇 |
2021年 | 94篇 |
2020年 | 78篇 |
2019年 | 83篇 |
2018年 | 91篇 |
2017年 | 62篇 |
2016年 | 52篇 |
2015年 | 54篇 |
2014年 | 60篇 |
2013年 | 79篇 |
2012年 | 46篇 |
2011年 | 48篇 |
2010年 | 43篇 |
2009年 | 35篇 |
2008年 | 36篇 |
2007年 | 31篇 |
2006年 | 22篇 |
2005年 | 11篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2002年 | 10篇 |
2001年 | 5篇 |
2000年 | 16篇 |
1999年 | 10篇 |
1998年 | 31篇 |
1997年 | 25篇 |
1996年 | 12篇 |
1995年 | 8篇 |
1994年 | 14篇 |
1993年 | 11篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1271条查询结果,搜索用时 15 毫秒
41.
Rheology of polyacrylonitrile‐based precursor polymers produced from controlled (RAFT) and conventional polymerization: Its role in solution spinning 下载免费PDF全文
Polymer solutions in dimethyl sulfoxide (DMSO) as a solvent, made from reversible addition fragmentation chain transfer (RAFT)‐mediated polyacrylonitrile (RAFT¥ PAN) terpolymer with molecular weight (MW) of 260,000 g/mol and dispersity (Ð) of 1.29, behave differently under applied shear stress than polymer solutions made from conventional PAN (Control PAN) with similar MW (258,000 g/mol) but Ð of 2.05 in the same solvent. The unique rheology of RAFT PAN is because of the reduced amount of high MW polymer fractions. Specifically, a 25% (w/v) polymer solution of RAFT PAN had a viscosity of 198 Pas while the equivalent control PAN polymer solution had a viscosity of 968 Pas at a shear rate of 1 s?1. Also, RAFT PAN polymer solutions had a longer Newtonian plateau than control PAN polymer solutions. This exhibits more liquid character in RAFT PAN polymer solutions than control PAN polymer solutions at same temperature and concentration. In dynamic tests, RAFT PAN polymer solutions gelled slower than their equivalent control PAN polymer solutions because of their longer polymer chain relaxation times. Slow gelling and higher liquid character in RAFT PAN polymer solutions can result in obtaining stronger and finer precursor fibers during wet spinning. Since RAFT PAN polymer solutions exhibit low viscosity and higher liquid character when compared to its equivalent control PAN at same concentration and temperature, these can allow a wider working window for wet spinning and can also allow higher solid content in the polymer solutions that remain easy to wet spin. This is expected to lead to compact and finer fibers with less voids and higher strength. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44273. 相似文献
42.
Silicon - Today, Fin shaped Field Effect Transistors (FinFETs) are the framework of the sub-nanometer technology node. The leading semiconductor industry deploys it in low-power (LP) and... 相似文献
43.
Synthesis,characterization and use of polymer‐supported phase transfer catalyst in organic reactions
A polymer‐supported (PS) phase transfer catalyst, polyethylene‐g‐quaternary ammonium salt (PE‐g‐QN+), is prepared through a three‐step graft copolymerization of maleic anhydride (MAn) onto polyethylene (PE) by photochemical method using 1% benzophenone (Bz) as photosensitizer. Post grafted acid hydrolysis of polyethylene‐g‐maleic anhydride (PE‐g‐MAn) results in the preparation of PE‐g‐succinic acid which on further treatment with tetrabutylammonium bromide (TBAB) under basic conditions in tetrahydrofuran (THF) gives PE‐g‐QN+. Optimum conditions pertaining to maximum percentage of grafting have been evaluated as a function of concentration of maleic anhydride, amount of photosensitizer, and time of reaction. Maximum percentage of grafting (25%) was obtained using 3.57 mol of MAn and 0.5 mL of 1% Bz in 120 min. The PE and graft copolymers, PE‐g‐MAn, and PE‐g‐QN+ were characterized by FTIR Spectroscopy and thermogravimetric analysis (TGA). The ionic nature of quaternary ammonium salt, PE‐g‐QN+ has also been confirmed by conductance measurements. PE‐g‐QN+ reagent have been used successfully for polymerization, amidation, and esterification reactions. The products obtained were characterized by FTIR and H1NMR spectral methods. The reagent was reused for the further reactions and it was observed that the polymeric reagent polymerize, amidate, and esterificate the compounds successfully but with little lower product yield. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
44.
Ghanshyam S. Chauhan Surya K. Dhiman Lalit K. Guleria Inderjeet Kaur 《应用聚合物科学杂志》2002,83(7):1490-1500
In an attempt to develop an alternative to petro‐based polymers, we graft‐copolymerized cellulose isolated from the needles of Pinus roxburghii with styrene in a limited aqueous medium in air by simultaneous irradiation using gamma rays as the initiator. The optimum conditions for obtaining maximum grafting were determined as a function of monomer concentration, total dose of irradiation, and amount of water. Maximum percentage of grafting (Pg; 79.9) was obtained at a total dose of 1.152 × 104 Gy with 1.325 × 10?4 mol of styrene. The effect of methanol, LiNO3, Cu(NO3)2, Mohr's salt, H2SO4, HNO3, and AcOH on Pg was studied. All the additives were found to decrease graft yield, contrary to some reported studies. Total percentage conversion and rates of polymerization, grafting, and homopolymerization were evaluated. Evidence of grafting was provided by the characterization of cellulose and its graft copolymers by Fourier transform infrared spectroscopy, thermogravimetry, and observation of the swelling behavior in some solvents. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1490–1500, 2002 相似文献
45.
We report on the effect of phase immiscibility on the structure and optical properties of spin-coated polyvinylpyrrolidone (PVP) and polyphenylene oxide (PPO) polyblends using X-ray diffraction, IR absorption, optical absorption and florescence spectroscopic techniques. The broad diffraction halos in the X-ray diffraction patterns reveal the semi-crystalline nature for the synthesized polyblends. The change in q value for both the deconvoluted halos confirms the variation in the molecular interactions while the decrease in their fwhm values signify the enhancement in crystalline nature with the blending. The infrared absorption studies were used to elucidate the interaction of functional groups in the spin-coated polyblends. The position of three excitonic bands and the red shift in the optical absorption edge with the increase in the PPO content has been observed for these polyblends. The six time enhancement in fluorescence peak intensity in visible region (~500 nm) for immiscible blend (50/50) composition has been of importance for the design of low cost luminescent and photovoltaic devices. 相似文献
46.
ABSTRACTThe efficacies of UV photolysis, UV-activated persulfate (UV/PS), and combined UV/Fe2+-activated persulfate (UV/PS/Fe2+) systems for degrading of different organic micropollutants in ultrapure water and groundwater were examined and compared. The studied micropollutants belonging to the different classes involved an artificial sweetener acesulfame K (ACE), beta-lactam antibiotic amoxicillin (AMX), and endocrine disrupting compound 4-nonylphenol (NP). Among the studied systems, the UV/PS/Fe2+ process showed the highest performance both in degradation and in mineralization of ACE (UVA-induced systems; kapp = 0.126 1/min and 80.3% TOC removal) and AMX (UVC-induced systems; kapp = 1.383 1/min and 85.4% TOC removal), followed by the UV/PS process. In the case of NP trials, the application of UVC/PS systems was the most promising, and after careful adjustment of oxidant concentration, it demonstrated a considerable improvement in the target compound degradation (at a NP/PS molar ratio of 1/4 kapp = 0.024 1/min) compared with the UVC photolysis (kapp = 0.016 1/min). Irrespective of the applied UV-induced treatment process, the efficacy of target compounds degradation was lower in groundwater as compared with ultrapure water trials. 相似文献
47.
Cardiovascular disease (CVD) is a leading cause of death worldwide. Elevated concentrations of serum total cholesterol (TC) and low-density lipoprotein cholesterol (LDL-C) are major lipid biomarkers that contribute to the risk of CVD. Phytosterols well known for their cholesterol-lowering ability, are non-nutritive compounds that are naturally found in plant-based foods and can be classified into plant sterols and plant stanols. Numerous clinical trials demonstrated that 2 g phytosterols per day have LDL-C lowering efficacy ranges of 8–10%. Some observational studies also showed an inverse association between phytosterols and LDL-C reduction. Beyond the cholesterol-lowering beneficial effects of phytosterols, the association of phytosterols with CVD risk events such as coronary artery disease and premature atherosclerosis in sitosterolemia patients have also been reported. Furthermore, there is an increasing demand to determine the association of circulating phytosterols with vascular health biomarkers such as arterial stiffness biomarkers. Therefore, this review aims to examine the ability of phytosterols for CVD risk prevention by reviewing the current data that looks at the association between dietary phytosterols intake and serum lipid biomarkers, and the impact of circulating phytosterols level on vascular health biomarkers. The clinical studies in which the impact of phytosterols on vascular function is investigated show minor but beneficial phytosterols effects over vascular health. The aforementioned vascular health biomarkers are pulse wave velocity, augmentation index, and arterial blood pressure. The current review will serve to begin to address the research gap that exists between the association of dietary phytosterols with CVD risk biomarkers. 相似文献
48.
Pooja Kaur Dr. Alice Johnson Joshua Northcote-Smith Dr. Chunxin Lu Dr. Kogularamanan Suntharalingam 《Chembiochem : a European journal of chemical biology》2020,21(24):3618-3624
Immunogenic cell death (ICD) offers a method of stimulating the immune system to attack and remove cancer cells. We report a copper(II) complex containing a Schiff base ligand and a polypyridyl ligand, 4 , capable of inducing ICD in breast cancer stem cells (CSCs). Complex 4 kills both bulk breast cancer cells and breast CSCs at sub-micromolar concentrations. Notably, 4 exhibits greater potency (one order of magnitude) towards breast CSCs than salinomycin (an established breast CSC-potent agent) and cisplatin (a clinically approved anticancer drug). Epithelial spheroid studies show that 4 is able to selectively inhibit breast CSC-enriched HMLER-shEcad spheroid formation and viability over non-tumorigenic breast MCF10 A spheroids. Mechanistic studies show that 4 operates as a Type II ICD inducer. Specifically, 4 readily enters the endoplasmic reticulum (ER) of breast CSCs, elevates intracellular reactive oxygen species (ROS) levels, induces ER stress, evokes damage-associated molecular patterns (DAMPs), and promotes breast CSC phagocytosis by macrophages. As far as we are aware, 4 is the first metal complex to induce ICD in breast CSCs and promote their engulfment by immune cells. 相似文献
49.
Polymer Bulletin - The present paper is focused on the synthesis and optimization of a green PVA-co-poly(MAA) adsorbent by free radical polymerization using N,N′-methylene-bis-acrylamide and... 相似文献
50.
An efficient method for C-N bond formation via aza-Michael addition of γ-aminopropylsilatranes to substituted N-phenylmaleimides under mild conditions is described. The five receptors enclosing the maleimide moiety have been synthesized by the aza-Michael addition to strong nucleophile γ-aminopropylsilatrane producing silatranes possessing substituted N-phenylsuccinimide at the axial position without any catalyst. All the compounds have been characterized by elemental analysis, spectroscopic techniques and thermo-gravimetric analysis. The synthesized compounds have been screened for possible antimicrobial properties and results have shown modest activity. 相似文献