Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis,Characterization, and Single-Molecule Force Spectroscopy

Self-assembly by H-bonding and by metal-coordination of functionalized calix[4]arenes and cavitands to large supramolecular capsules is described. In addition, a new method of analyzing supramolecular recognition processes at the single molecule level is discussed. By measuring interaction forces in a hydrogen-bonded assembly using single-molecule force spectroscopy (SMFS), the dynamics of the self-assembly process can be evaluated. In the future, consequent application of this new technique will influence supramolecular design principles and the use of non-covalent interactions as construction elements in the field of nanotechnology.     

A Call-Admission Control (CAC) Algorithm for Providing Guaranteed QoS in Cellular Networks

Future broadband wireless access systems are expected to integrate various classes of mobile terminals (MTs), each class with a different type of quality of service (QoS) requirement. When the load on a wireless network is high, the guarantee of QoS for each class of MTs is a challenging task. This study considers two classes of MTs—profiled MTs and nonprofiled or regular MTs. It is assumed that profiled users require a guaranteed QoS. The measure of QoS is the probability of forced termination of a call that was allowed to access the network. Two previous handoff prioritization schemes—(i) prerequest scheme and (ii) guard channel scheme—decrease handoff failure (and hence forced termination). In this work, we compare and contrast both the schemes through extensive simulation and we find that neither guard channel nor channel prerequest scheme can guarantee a desired level of QoS for the profiled MTs. We then propose a novel call-admission control (CAC) algorithm that can maintain any desired level of QoS, while the successful call completion rate is very high. In the proposed algorithm, the new call arrival rate is estimated continuously, and when the estimated arrival rate is higher than a predetermined level, some new calls are blocked irrespective of the availability of channels. The objective of this new call preblocking is to maintain a cell's observed new call arrival rate at no more than the predetermined rate. We show that the proposed method can guarantee any desired level of QoS for profiled users.     

Solid-State Polymerization Behavior of 1,3-Bis(3-quinolyl)-1,4-butadiyne

Summary 1,4-Bis(3-quinolyl)-1,3-butadiyne (DQ) is known to be polymerized in solid state to give the corresponding polydiacetylene. However, the polymer yield of DQ bulk crystals is low. Thus, we prepared several types of DQ crystals by different procedures to find the reason for the low polymer yield. We found three modifications of DQ crystals and they were evaluated by spectroscopic measurements and X-ray diffraction. DQ bulk crystals (Crystal I) and thermally grown DQ crystals on Crystal I (Crystal II) have the same structure classified to Type A, which gives regular polydiacetylene structure in low polymer yields. DQ crystals grown on glass plates by sublimation (Crystal III) belong to the second modification of Type B. DQ nanocrystals prepared by the reprecipitation method (Crystal IV) are Type B, and thermally grown DQ crystals on nanocrystals (Crystal V) are Type C. Crystals of Types B and C could be polymerized in low yields without showing excitonic absorption of polydiacetylene indicating irregular polymerization other than 1,4-addition. For crystals of Type A, we found that the 1,4-addition polymerization proceeded only in near-surface portions of the crystals. It can be plausibly explained that mobile monomers in the near-surface portion are only able to take part in their polymerization, resulting in low polymer conversion.     

Doppler-broadened positron annihilation studies in Y-Ba-Cu-O,Tl-Ca-Ba-Cu-O and Bi-Ca-Sr-Cu-O superconductors

Doppler-broadened annihilation radiation spectra have been measured as a function of temperature from 77 K to 300 K, for several high temperature oxide superconductors viz single-phase YBCO, single- and mixed-phase Tl-Ca-Ba-Cu-O and Bi-Ca-Sr-Cu-O compounds. The temperature-dependent parameters extracted respond to a change at the onset of superconducting transition. The observations point to involvement of oxygen valence electrons at the onset of superconducting transition. Also a possible structural change and/or increase in electron density at the oxygen vacancy/defect sites seem to accompany the transition. In addition, the parameters derived are seen to be sensitive to the presence of more than one superconducting phases in mixed phase samples.     

Bead fusion in polystyrene foams

A quantitative technique has been developed to measure the extent of fusion between expanded beads in molded polystyrene foams. Experiments were conducted with ASTM D638 tensile test specimens that were molded under conditions to produce various levels of bead fusion in the foam. The tensile properties of the foam for various levels of bead fusion were measured according to ASTM D638 standards. The fracture surfaces of the tensile specimens were analysed by quantitative image analysis techniques to measure the degree of bead fusion in the sample. This technique was then used on a commercial pattern to map the variations in bead fusion at numerous locations in the molded part. The results indicate that there is a good correlation between the tensile properties and the measured bead fusion. Significant variations in bead fusion may be present in a single molded part.     

Influence of EPS bead fusion on pattern degradation and casting formation in the lost foam process

The effects of bead fusion in the pattern on foam degradation and on casting formation have been studied. Injection molded ASTM D638 tensile specimens have been used to develop a microscopic technique to quantify the extent of bead fusion in the pattern. The tensile properties of the polymer have been correlated with the measured degree of bead fusion. A variety of experiments have been conducted to highlight the effects of fusion on foam degradation. The flow behavior of a molten aluminum alloy has been studied in patterns with various levels of fusion. The results indicate that the degree of fusion has a significant effect on bead collapse and viscous residue formation in the polymer. The mold fill times generally increase with increasing bead fusion in the pattern. The temperature at the metal front drops more rapidly as the bead fusion increases.     

Optimization of on-chip ESD protection structures for minimal parasitic capacitance

Diodes are key components in on-chip electrostatic discharge (ESD) protection design. As the operating frequency of the microchip being protected against the ESD continues to increase, the parasitic capacitance associated with the diodes in the ESD structure starts to impose problems for RF operation. This paper presents a systematic approach to optimize the diode structure for minimal parasitic capacitance based on the requirements of breakdown voltage and heat dissipation. Device simulator Atlas with mix-mode simulation capability is calibrated against measurement data and used to carry out the optimization. An optimized diode structure with a parasitic capacitance of less than 30 fF at an operating frequency of 10 GHz and ESD charging voltage of 1 kV has been suggested. Furthermore, a case study to implement and optimize the ESD protection structure based on an existing 0.13-μm CMOS technology has been presented and verified.     

Mixed finite element models for plate bending analysis: A new element and its applications

With a few exceptions, finite element packages available in today's commercial software environment contain in their libraries displacement-type elements only. The present paper aims to demonstrate the feasibility that properly formulated mixed-type elements compete most favorably with displacement-type elements and should, therefore, be considered as potential candidates for inclusion in general purpose finite element packages. In doing so, the development of a new triangular doubly—curved mixed-hybrid shallow shell element and its extensive testing in carefully chosen example problems are reported on.