Influence of Whey Protein Addition and Feed Moisture Content on Chosen Physicochemical Properties of Directly Expanded Corn Extrudates

Production of extrudates from cereals is an often-used technological process in today’s world food industry. Extrudates from corn flour produced using the twin-screw extrusion process and enriched with whey protein concentrate represent high-quality source of proteins and fats. Whey protein concentrate (WPC) as a valuable source of proteins and minerals is one of the highest-quality components for possible extrudate enrichment. In this paper, the influence of various WPC addition and some extrusion process parameters such as feed moisture content ( Q_{\textH\text2 \textO} Q_{{{\text{H}}_{\text{2}} {\text{O}}}} ) on physicochemical properties of directly expanded corn flour extrudates manufactured in twin-screw co-rotating extruder was investigated. Whey protein concentrate was added in the following ratios 7.5%, 15% and 22.5% and water in 10.08, 12.18 and 14.28 L/h. Final composition of products is determined with measuring of protein, fat and water shares, water absorption index (WAI) and water solubility index (WSI). With added WPC and with increase of water volume flow, there was a significant rise in total protein, fat and water content in final products, as well as lowering of WSI and rising of WAI indexes. The statistical analysis of the obtained data shows that the lowest WSI and the highest WAI had samples with the largest share of WPC (22.5%) and water volume flow of 14.28 L/h. Colour is measured for each sample, and results were represented with hue angle (H), chroma (C) and lightness (L) values. Process parameters, WPC and Q_{\textH\text2 \textO} Q_{{{\text{H}}_{\text{2}} {\text{O}}}} influence the increase of saturation of C and lightness of L colour value, while H value stays unchanged. Mean value of H was 90.14 ± 1.06, which corresponds to dominance of yellow colour of samples.     

Contour diagram fuzzy model for maximum surface ozone prediction

A contour diagram approach is presented for the identification of surface ozone concentration feature based on a set of rules by considering the meteorological variables such as the solar radiation, wind speed, temperature, humidity and rainfall. A fuzzy rule system approach is used because of the imprecise, insufficient, ambiguous and uncertain data available. The contour diagrams help to identify qualitative ozone concentration variability rules which are more general than conventional statistical or time series analysis. In the methodology, ozone concentration contours are based on a fixed variable as ozone precursor, namely, NO_x and as the third variable one of the meteorological factors. Such contour diagrams for ozone concentration variation are prepared for six months. It is possible to identify the maximum ozone concentration episodes from these diagrams and then to set up the valid rules in the form of IF-THEN logical statements. These rules are obtained from available daily ozone, NO_x and meteorological data as a first approximate reasoning step. In this manner, without mathematical formulations, expert maximum ozone concentration systems are identified. The application of the contour diagram approach is performed for daily ozone concentration measurements on European side of Istanbul city. It is concluded that through approximate reasoning with fuzzy rules, the maximum ozone concentration episodes can be identified and predicted without any mathematical expression.     

Comparison of additive effects on the PVA/starch cryogels: Synthesis,characterization, cytotoxicity,and genotoxicity studies

The research goal of this study is to produce suitable scaffolds for tissue engineering applications. Different ratios of polyvinyl alcohol (PVA)/starch (90:10, 70:30, 50:50) and crosslinking methods have been used to prepare cryogels. Chemically crosslinked cryogels were synthesized using glutaraldehyde as the crosslinking agent. For the physically crosslinked cryogels, sodium dodecyl sulfate was used during cryogelation as the foaming agent. Chemical structure and pore morphology were demonstrated by Fourier transform infrared spectroscopy and scanning electron microscopy (SEM). Swelling ratio and degradation profile of the scaffolds were also determined. 3-(4,5-dimethylthiazoyl-2-yl)-2,5-diphenyltetrazolium bromide assay and SEM were used to investigate the biocompatibility of the scaffolds and cell morphology. Genotoxicity test was performed to show DNA fragmentation. The overall results demonstrated that PVA/starch cryogels could have potentially appealing application as scaffolds for tissue engineering applications and additives affect the architecture and characteristic properties of the cryogels.     

Synthesis of bio‐based polymeric nanocomposites from acrylated epoxidized soybean oil and montmorillonite clay in the presence of a bio‐based intercalant

Polymeric nanocomposites were synthesized from functionalized soybean‐oil‐based polymer matrix and montmorillonite (MMT) clay using an in situ free radical polymerization reaction. Acrylated epoxidized soybean oil combined with styrene was used as the monomer. Organophilic MMT (OrgMMT) was obtained using a quaternized derivative of methyl oleate, which was synthesized from olive oil triglyceride, as a renewable intercalant. The resultant nanocomposites were characterized using X‐ray diffraction and atomic force microscopy. The effect of increased nanofiller loading on the thermal and mechanical properties of the nanocomposites was investigated using thermogravimetric analysis and dynamic mechanical analysis. It was found that the desired exfoliated nanocomposite structure was achieved when the OrgMMT loading was 1 and 2 wt%, whereas a partially exfoliated or intercalated nanocomposite was obtained for 3 wt% loading. All the nanocomposites were found to have improved thermal and mechanical properties as compared with virgin acrylated epoxidized soybean‐oil‐based polymer matrix. The nanocomposite containing 2 wt% OrgMMT clay was found to have the highest thermal stability and best dynamic mechanical performance. Copyright © 2010 Society of Chemical Industry     

Extraction of caffeine from tea stalk and fiber wastes using supercritical carbon dioxide

The purpose of this study was to investigate obtaining of caffeine from tea plant wastes by supercritical carbon dioxide extraction. Experiments were carried out with tea stalk and fiber wastes of Turkish tea plants that has no economical value. Stalk and fiber wastes were supplied from tea factories. These wastes were ground, sieved and dried at 105 °C temperature in an oven. Parameters affecting caffeine leaching from tea wastes were determined to be, extraction time, extraction temperature, carbon dioxide flow rate, process pressure and particle size. The maximum yield of caffeine from tea stalk wastes and fiber wastes were 14.9 mg/g tea stalk and 19.2 mg/g tea fiber, respectively. The yield increase had been recorded as 61.9% and 65.5%, respectively, in comparison with the chloroform extraction of tea stalk and fiber wastes.     

Modeling the energy potential of biomass – H2RES

Modeling biomass as a renewable energy source poses many challenges with respect to feedstock variability, which are difficult to account for. It is found that at the preliminary stages of energy planning, heating value and moisture content of the feedstock are the most important factors. In addition, the effects of harvesting, transportation and storage are found to be significant even though they are often overlooked. Using the gathered information a biomass module for energy planning is created and integrated to H₂RES, a renewable energy planning program. Using this excel based software, a case study for a wood processing factory is performed, using the waste wood as feedstock. Comparing various scenarios, it is concluded that using a combination of solid oxide fuel cells, solar panels and steam turbines can satisfy the factories energy requirements with excess sold to the grid.     

Respirometric Assessment of Primary Sludge Fermentation Products

This study investigates the potential of primary sludge fermentation for the generation of readily biodegradable substrate. Experimental evaluation indicates that uncontrolled fermentation converted 22% of the initial volatile suspended solids in the sludge into soluble biodegradable chemical oxygen demand (COD). More than 85% of the soluble COD generated was associated with the formation of short chain volatile fatty acids (VFAs). The recoverable fraction of the fermented sludge supernatant may potentially increase the biodegradable COD content of the primary effluent by 5%. The VFA composition predominantly involved acetic and propionic acids as reported in the literature. Due to the high VFA content, activated sludge Model No. 1 could not predict the COD fractionation in the primary sludge; activated sludge Model No. 3 provided a better interpretation of the oxygen uptake profile through initial storage of the VFAs in the sludge.