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111.
This research work focuses on the utilization of coconut shell powder (CSP) as filler in recycled polypropylene (rPP). Sodium Dedecyl Sulfate (SDS) was used as coupling agent in these composites. The effect of filler content and SDS on tensile properties, thermal properties, water absorption and morphology of rPP/CSP composites were investigated. In this study, modified rPP/CSP composites with SDS show significant increased tensile propertied, thermal stability, crystallinity and low water absorption compared unmodified rPP/CSP composites. Those improvements were contributed by the coupling effect of SDS. 相似文献
112.
Se Woong Lee Seong Wook Lim Soon Hee Park Kwang Ha Keun Sik Kim Se Min Oh Jin Yong Lee Gon Seo 《Korean Journal of Chemical Engineering》2013,30(12):2241-2247
The reaction of m-xylylenediamine (mXD) with carbon dioxide was examined and its feasibility as a sequestration material of carbon dioxide was discussed. The reaction was monitored by using the FT-IR and gravitational methods, while the crystalline structure of the reaction product was investigated with elemental analysis, powder Xray diffraction, single crystallography, and 13C MAS NMR spectroscopy. Even at ambient temperature, mXD reacted with carbon dioxide of low partial pressure in the atmosphere and produced a 1: 1 molar adduct which appeared as a white crystalline material. The hydrogen bonds that formed between the adduct molecules resulted in the formation of a stable crystal. The sequestration capacity of mXD was very great, ~280 mg g mXD ?1 below 50 °C. An adsorbent prepared by dispersing mXD on silica was capable of capturing carbon dioxide, but it could be regenerated by evacuating at 25 °C. 相似文献
113.
Seong Min Oh Kyung Min Oh Trung Dung Dao Hyung‐il Lee Han Mo Jeong Byung Kyu Kim 《Polymer International》2013,62(1):54-63
Graphene prepared by the thermal reduction of graphite oxide was modified by reactions with methanol or 1‐butanol using aqueous HBF4 solution as a catalyst. Results showed that the reaction created hydroxyl groups on the graphene and at the same time reduced the number of defects. Gravimetry, thermogravimetry, X‐ray photoelectron spectroscopy and Fourier transform infrared spectroscopy showed that the alcohols had reacted with epoxide groups on graphene. Raman spectroscopy showed that the defects in the graphene were repaired through other accompanying reactions. The reinforcing effect of graphene, observed in the tensile properties and the shape memory behavior of graphene/polyurethane composites, was increased when the graphene was modified with methanol. However, decreases in density and glass transition temperature were evident for the composites made with alcohol‐modified graphene. These results show that the newly created hydroxyl groups on graphene produce effective covalent bonds with the polyurethane chains of the matrix; however, the increased number of bonds restricts the rearrangement of the matrix molecules for dense packing. The covalent bonds between graphene and polyurethane chains enhanced shape recoverability and reduced the hysteresis brought about by repeated thermomechanical cycles. Copyright © 2012 Society of Chemical Industry 相似文献
114.
Jung‐Jae Park Do‐Yeon Kim Jong‐Gun Lee Donghwan Kim Joon‐Ho Oh Tae‐Yeon Seong Maikel F.A.M. van Hest Sam S. Yoon 《Journal of the American Ceramic Society》2013,96(5):1596-1601
Photocatalytic and hydrophilic TiO2 thin‐film applications include water purification, cancer therapy, solar energy conversion, self‐cleaning devices, and antifogging windows. We demonstrate superhydrophilicity of aerosol‐deposition (AD) TiO2 films on a glass substrate without use of a carrier solvent, thereby removing the possibility of impurity contamination. AD films exhibit high visible light transmittance (greater than 80%) and superhydrophilicity (0° contact angle) with even minimal UV‐light irradiation exposure. This AD method represents a significant step toward the realization of economically viable, functional thin films for the aforementioned applications. 相似文献
115.
Su-Gwang Jeong Seong Jin Chang Seunghwan Wi Yujin Kang Hwayoung Lee 《Journal of Adhesion Science and Technology》2013,27(3):297-309
Latent heat thermal energy storage using phase change materials (PCMs) is considered to be the method with the most potential to solve the energy shortage problem. In this study, paraffin-based mixed shape-stabilized PCM (SSPCM) (PBMS) was made by vacuum impregnation method. The prepared PBMS was added to gypsum powder as a fine aggregate. In the experiment, the n-hexadecane and n-octadecane was used as the PCM and the materials have latent heat capacities of 254.7 and 247.6 J/g, and melting points of 20.84 and 30.4 °C, respectively. The PBMS was prepared by an impregnation method in a vacuum, following the manufacturing process. The physical and thermal properties of the PBMS gypsum board were analyzed by Fourier transform infrared spectrometry (FTIS), differential scanning calorimetry, enthalpy analysis, and thermogravimetric analysis. From the Fourier transform infrared analysis, PBMS could be maintained in the structure of the gypsum board due to its physical rather than chemical bonding. From the specific heat and enthalpy analysis, the PBMS has high enthalpy and thermal inertia property. In addition, the gypsum board with PBMS has high latent heat capacity and high thermal efficiency. 相似文献
116.
Kyoung Suk Kim Byung Soo Oh Joon Wun Kang Deuk Mo Chung Woo Hyeun Cho Yon Kyu Choi 《臭氧:科学与工程》2005,27(1):69-79
To improve the quality of water supplied to the City of Seoul in Korea, a pilot-scale evaluation of how the conventional treatment process could be upgraded was conducted. Three candidate processes were evaluated and compared: a conventional process (consisting of coagulation, sedimentation, and rapid sand filtration) plus GAC (Train A); a conventional process plus ozone and GAC (Train B); and a process consisting of coagulation, sedimentation, intermediate ozone, sand filtration, and GAC (Train C). Treatment efficiency of the unit process and overall treatment trains were evaluated using several parameters such as turbidity, dissolved organic carbon (DOC), UV absorbance at 254 nm (UV254), specific ultraviolet absorbance (SUVA), micropollutants (pesticides, benzenes, and phenols), disinfection by-products (trihalomethanes (THMs), haloacetic acids (HAAs) and aldehydes), and total organic halogen (TOX). Results showed that ozone and/or GAC was effective for removing micropollutants and controlling chlorinated by-products such as THMs and HAAs. However, any synergistic effect of ozonation (adsorption and biodegradation) on GAC was observed due to the low concentration of aldehydes in raw and process water. 相似文献
117.
A new class of thermogelling poly(organophosphazenes) bearing a hydrophilic methoxypoly(ethylene glycol) (MPEG) and a hydrophobic tri or tetrapeptide such as GlyPheLeuEt, GlyPheIleEt, GlyLeuPheEt, and GlyPheLeuGlyEt have been synthesized and characterized by means of multinuclear (1H, 31P) NMR spectroscopy, gel permeation chromatography, viscometry, and elemental analysis. The gelation of the present polymers is presumed to be attributed to the intermolecular interaction between the hydrophobic oligopeptide side groups, which can form strong physical junction zones in the polymer aqueous solution. The gelation properties of the polymer were affected by the subtle change in the nature of the hydrophobic oligopeptide, composition of the hydrophilic to hydrophobic side groups, and the concentration of the polymer solutions. Among the present thermogels, the copolymer with equimolar MPEG and GlyPheIleEt as side groups showed the excellent gel phase persisting over 35-43 °C, which indicates that it is a new promising material for drug delivery and tissue engineering. 相似文献
118.
Woon Jin Chung Bong Je Park Hong Seok Seo Joon Tae Ahn Myung-Hyun Lee Yong Gyu Choi 《Journal of the American Ceramic Society》2005,88(5):1205-1208
Selenide glass optical fibers were fabricated for Ge30 Sb10 Se58 S2 and Ge20 Sb10 Se70 glasses. Their transmission loss has been measured and compared with the theoretical attenuation loss that was calculated taking into account the electronic transition absorption, Rayleigh scattering, and multiphonon absorption. A low attenuation loss of the Ge20 Sb10 Se70 glass composition in 1.2–1.7 μm range has been expected due to its high optical band gap energy compared with the Ge30 Sb10 Se58 S2 glass. However, the measured attenuation loss of the Ge30 Sb10 Se58 S2 glass fiber was ∼13 dB/m at 1.5 μm while Ge20 Sb10 Se70 glass showed ∼82 dB/m. An enhanced weak absorption tail due to the localized states of the Ge20 Sb10 Se70 glass was responsible for this behavior. Structural defects are related to the localized states and discussed for the present glass compositions. 相似文献
119.
Jung Joon Lee Heeyeon Kim Jae Hyun Koh Ara Jo Sang Heup Moon 《Applied catalysis. B, Environmental》2005,61(3-4):274-280
The performance of a new type of CoMoS/Al2O3 catalyst, with added fluorine and prepared by sonochemical and chemical vapor deposition (CVD) methods, was investigated in the hydrodesulfurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT). The catalyst, which was designed to contain optimum amounts of fluorine and cobalt, exhibited a higher activity, ca. 4.6 times higher activity particularly in the HDS of 4,6-DMDBT, than a fluorine-free catalyst prepared by a conventional impregnation method. The enhanced activity of the new catalyst can be attributed to the cumulative effects of individual factors involved in the catalyst preparation. That is, the use of a sonochemical synthesis led to a high dispersion of small MoS2 crystallites on the alumina, and the addition of the Co species to the catalyst by CVD caused a close interaction between the Co species and the MoS2 crystallites to produce numerous CoMoS species, which are the catalytically active species for HDS. The addition of fluorine increased the amounts of acidic sites in the catalyst, which promoted hydrogenation (HYD) route to a greater extent than the direct desulfurization (DDS) route in DBT HDS and both HYD and DDS routes to similar extents in the case of 4,6-DMDBT HDS. Accordingly, the addition of fluorine led to a greater increase in catalytic activity for 4,6-DMDBT HDS than for DBT HDS. 相似文献
120.
Gun Dae Lee Myung Jun Moon Jeong Hwan Park Seong Soo Park Seong Soo Hong 《Korean Journal of Chemical Engineering》2005,22(4):541-546
Catalytic activity, in conjunction with reaction mechanism, was studied in the methanation of CO and CO2 on three Raney Ni catalysts derived from different Ni-Al alloys using different leaching conditions. Main products were CH4 and CO2 in CO methanation, and CH4 and CO in CO2 methanation. Any other hydrocarbon products were not observed. Over all catalysts, CO methanation showed lower selectivity
to methane and higher activation energy than CO2 methanation. The catalyst derived from alloy having higher Ni content using more severe leaching conditions, namely higher
reaction temperature and longer extraction time, showed higher specific activity and higher selectivity to methane both in
CO and CO2 methanation. In CO and CO2 methanation on Raney Ni catalyst, catalytic activity was seen to have close relation with the activity to dissociate CO
This paper was presented at the 2004 Korea/Japan/Taiwan Chemical Engineering Conference held at Busan, Korea between November
3 and 4,2004. 相似文献