Syngas suitability for solid oxide fuel cells applications produced via biomass steam gasification process: Experimental and modeling analysis

The technologies and the processes for the use of biomass as an energy source are not always environmental friendly. It is worth to develop approaches aimed at a more sustainable exploitation of biomass, avoiding whenever possible direct combustion and rather pursuing fuel upgrade paths, also considering direct conversion to electricity through fuel cells. In this context, it is of particular interest the development of the biomass gasification technology for synthesis gas (i.e., syngas) production, and the utilization of the obtained gas in fuel cells systems, in order to generate energy from renewable resources. Among the different kind of fuel cells, SOFCs (solid oxide fuel cells), which can be fed with different type of fuels, seem to be also suitable for this type of gaseous fuel. In this work, the syngas composition produced by means of a continuous biomass steam gasifier (fixed bed) has been characterized. The hydrogen concentration in the syngas is around 60%. The system is equipped with a catalytic filter for syngas purification and some preliminary tests coupling the system with a SOFCs stack are shown. The data on the syngas composition and temperature profile measured during the experimental activity have been used to calibrate a 2-dimensional thermodynamic equilibrium model.     

Characterisation of pear distillates from wild and cultivated varieties in Sardinia

The aroma fraction of Italian distillates of wild (Pyrus amygidaliformis, Vill., namely ‘Pirastru’) and cultivated (Pyrus communis, L. cvs. ‘Coscia’, ‘Precoce di Fiorano’ and ‘Butirru de Austu’) pear varieties grown in the northern part of the island of Sardinia was investigated. Distillates from fermented mashes were obtained from the same producer and, in most cases, for 3 years following the same production process. Aroma analyses were performed by GC‐FID and GC‐MS techniques with direct GC injection of full proof distillates. Differences were found in the aromatic profile of all the distillates depending on their varietal origin. Wild Pirastru pear distillates were the richest in isoeugenol (0.186 g hL^?1 a.a.), ethyl benzoate (0.388 g hL^?1 a.a.) and ethyl phenylacetate (0.12 g hL^?1 a.a.) but the poorest in 1‐hexanol (2.69 g hL^?1 a.a.), n‐hexyl acetate (0.07 g hL^?1 a.a.), Σ‐farnesene isomers (0.80 g hL^?1 a.a.) and citronellol (0.007 g hL^?1 a.a.). Pirastru distillates were also the poorest in methyl and ethyl unsaturated decanoate isomers, the so‐called Williams pear esters (0.002 g hL^?1 a.a.). On the contrary, these compounds that characterise the aroma of Williams pear distillates were abundant in Coscia spirits (1.032 g hL^?1 a.a.). The latter, together with Precoce di Fiorano, were rich in farnesene isomers (6.48 and 9.26 g hL^?1 a.a. respectively). Evaluation of the data by univariate (anova and Kruskal–Wallis) and multivariate (PCA and HCA) statistical analyses revealed that some components (the classes of acetates, farnesene isomers, methyl and ethyl unsaturated decanoate esters and citronellol) are relevant in discriminating the distillates according to variety.     

Combustion of syngas in a pressurized microturbine-like combustor: Experimental results

The different routes for power production from biomass often lead to an intermediary product such as a synthesis gas or syngas, which is typically rich in hydrogen and carbon monoxide. The simple design, fuel flexibility and size, which often matches the amount of waste energy available in industrial sites, makes microturbines an attractive solution for on-site, decentralized power generation using a limited range of alternative fuels such as synthetic gas. The properties of the synthetic fuel differ from properties of natural gas and a detailed experimental study with a separated microturbine-like pressurized combustor is therefore necessary. The present article reviews the experimental results obtained by gradually switching the fuel feed from natural gas to wet syngas in a pressurized, slightly modified lean premix microturbine combustor. Temperature profiles, pressure, emissions and flame imaging were closely monitored to detect possible problems in operability of the combustor caused by the strong difference in fuel characteristics.     

Greenhouse gas emissions from building and operating electric power plants in the Upper Colorado River Basin

As demand for electricity increases, investments into new generation capacity from renewable and nonrenewable sources should include assessment of global (climate) change consequences not just of the operational phase of the power plants but construction effects as well. In this paper, the global warming effect (GWE) associated with construction and operation of comparable hydroelectric, wind, solar, coal, and natural gas power plants is estimated for four time periods after construction. The assessment includes greenhouse gas emissions from construction, burning of fuels, flooded biomass decay in the reservoir, loss of net ecosystem production, and land use. The results indicate that a wind farm and a hydroelectric plant in an arid zone (such as the Glen Canyon in the Upper Colorado River Basin) appear to have lower GWE than other power plants. For the Glen Canyon hydroelectric plant, the upgrade 20 yr after the beginning of operation increased power capacity by 39% but resulted in a mere 1% of the CO2 emissions from the initial construction and came with no additional emissions from the reservoir, which accounts for the majority of the GWE.     

Transport implications resulting from internal redistribution of arsenic and iron within constructed soil aggregates

Soils are an aggregate-based structured media that have a multitude of pore domains resulting in varying degrees of advective and diffusive solute and gas transport. Consequently, a spectrum of biogeochemical processes may function at the aggregate scale that collectively, and coupled with solute transport, determine element cycling in soils and sediments. To explore how the physical structure impacts biogeochemical processes influencing the fate and transport of As, we examined temporal changes in speciation and distribution of As and Fe within constructed aggregates through experimental measurement and reactive transport simulations. Spherical aggregates were made with As(V)-bearing ferrihydrite-coated sand inoculated with Shewanella sp. ANA-3; aerated solute flow around the aggregate was then induced. Despite the aerated aggregate exterior, where As(V) and ferrihydrite persist as the dominant species, anoxia develops within the aggregate interior. As a result, As and Fe redox gradients emerge, and the proportion of As(III) and magnetite increases toward the aggregate interior. Arsenic(III) and Fe(II) produced in the interior migrate toward the aggregated exterior and result in coaccumulation of As and Fe(III) proximal to preferential flow paths as a consequence of oxygenic precipitation. The oxidized rind of aggregates thus serves as a barrier to As release into advecting pore-water, but also leads to be a buildup of this hazardous element at preferential flow boundaries that could be released upon shifting geochemical conditions.     

设计2050年

两年一度的新加坡设计节于2009年11月20日至30日举行。本届的主题是"设计2050年:明日的无限可能",10天的设计节期间,共有大小上百个活动,各类设计与艺术展览遍及新加坡各个角落。除了往年经常举办活动的City Hall,还有IONOrchard、新达城及怡丰城等大型购物中心,以及设计师工作室和建筑事务所都加入到活动中来。通过这些设计系列活动,能看到来自本地、     

Enhancing phenanthrene biomineralization in a polluted soil using gaseous toluene as a cosubstrate

Laboratory experiments were conducted to study the potential of adding gaseous toluene, as a readily degradable carbon source, to enhance phenanthrene mineralization in polluted soil (1,000 mg/kg(dry soil)) aged for 400 days. Experiments were conducted in 0.5-L column reactors packed with a mixture of (80:20 w(wet)/w(wet)) spiked soil and vermiculite and fed with 1 g m(-3)reactor h(-1) toluene load in air. Removal efficiencies of 100% for toluene and greater than 95% for phenanthrene were obtained in 190 h. Evolved CO2 showed that phenanthrene mineralization increased from 39% to 86% in columns treated with gaseous toluene. Phthalic acid was identified as the principal soluble intermediate, which accumulated when no toluene was added. Increased phenanthrene uptake and mineralization with toluene can be attributed to increased biomass and the induction of enzymes involved in the intermediate mineralization. In microcosm experiments, phthalic acid mineralization increased from 19% to 81% within 50 h in the presence of toluene. Experiments with 14C-labeled phenanthrene confirmed the enhancement of phenanthrene mineralization from 45% to 83% in 385 h with toluene as a second carbon source. The results indicate thatthe addition of an appropriate gaseous cosubstrate could be an adequate strategy to enhance mineralization of PAHs in soil.