On the interrelationship of transreaction with viscoelastic properties of poly(ethylene terephthalate)/poly(ethylene naphthalate) blends in the presence of nanoclay

An attempt was made to explore the effects of the interchange reactions on the viscoelastic behavior of binary blends based on poly(ethylene terephthalate) (PET)/poly(ethylene naphthalate) (PEN) and their nanocomposites. It was seen that with an increase in the number of extrusion runs and mixing temperature, the extent of reaction (X) and degree of randomness (RD) both increased, whereas the average sequence block lengths values were decreased. On the contrary, the blend composition did not play a significant role on X and RD values. Addition of nanoclay inhibited the transreactions in PET/PEN blends. The absence of crystallization peaks implied that the crystalline structure was destroyed as a result of blending and an amorphous system was created possibly due to the transreactions simultaneously with the formation of random copolymers inhibiting the crystallization process. The rheological investigations showed that the addition of PEN into the PEN/PET blends enhanced the storage modulus, loss modulus, and complex viscosity. The viscosity upswing observed at low‐frequency region in the case of nanocomposite systems evidently confirmed the occurrence of transreactions. Nonetheless, a significant increment in the viscoelastic properties was perceived in the presence of nanoclay corroborating the proper nanoclay distribution throughout the PET/PEN blend system. POLYM. ENG. SCI., 53:2556–2567, 2013. © 2013 Society of Plastics Engineers     

Roll bonding behaviour of Al-3003/Al-4043 and Al-3003/Zn sheets

In the present study, the roll bonding behaviour of Al-3003/Al-4043 and Al-3003/Zn sheets were compared. The bi-layer sheets were produced by a roll bonding process at different reductions in thickness and rolling temperatures. The joint strengths of the sheets were evaluated by peel and bend testing before and after supplemental annealing treatment. The peeled surfaces were examined using a scanning electron microscope. The results indicated that the Al-3003/Al-4043 sheets were bonded with higher joint strength and lower threshold reductions in thickness with respect to the Al-3003/Zn sheets. In contrast to the Al-3003/Zn sheets, significant improvement was observed in the joint strength of the Al-3003/Al-4043 sheets after annealing treatment. Moreover, electron microscopy examinations showed that the fracture types of the Al-3003/Al-4043 and Al-3003/Zn sheets were predominantly ductile and brittle, respectively.     

Aerodynamic and aeroacoustic performance of airfoils with morphing structures

Aerodynamic and aeroacoustic performance of airfoils fitted with morphing trailing edges are investigated using a coupled structure/fluid/noise model. The control of the flow over the surface of an airfoil using shape optimization techniques can significantly improve the load distribution along the chord and span lengths whilst minimising noise generation. In this study, a NACA 63‐418 airfoil is fitted with a morphing flap and various morphing profiles are considered with two features that distinguish them from conventional flaps: they are conformal and do not rely on conventional internal mechanisms. A novel design of a morphing flap using a zero Poisson's ratio honeycomb core with tailored bending stiffness is developed and investigated using the finite element model. Whilst tailoring the bending stiffness along the chord of the flap yields large flap deflections, it also enables profile tailoring of the deformed structure which is shown to significantly affect airfoil noise generation. The aeroacoustic behaviour of the airfoil is studied using a semi‐empirical airfoil noise prediction model. Results show that the morphing flap can effectively reduce the airfoil trailing edge noise over a wide range of flow speeds and angles of attack. It is also shown that appropriate morphing profile tailoring improves the effect of morphing trailing edge on the aerodynamic and aeroacoustic performance of the airfoil. Copyright © 2015 John Wiley & Sons, Ltd.     

Numerical and performance analysis of one row transonic rotor with sweep and lean angle

In this study,aerodynamic behaviors of swept and leaned blades were investigated.Axial and tangential blade curvatures impacts on compressor＇s operating parameters were analyzed separately.A commercial CFD program which solves the Reynolds-averaged Navier-Stokes equations was used to find out the mentioned impact and the complicated flow field of transonic compressor-rotors.The CFD method that was used for solving flow field＇s equation was validated by experimental data of NASA Rotor 67.The results showed that the compressor with curved rotors had higher efficiency,rotor pressure ratio and stable operating range compared to the compressor with un-curved rotors.Using curved rotors mostly had higher impact on the overall stable operating range compared to the other operating parameters.Operating range involves choking point and stall point that were changed separately by using of bended blade.For finding the detailed impact of sweep and lean angle on transonic blades,various forms of lean and sweep angles were exerted to basic rotor.It was found that sweep angles increased overall operating range up to 30%,efficiency up to 2%and pressure ratio up to 1%.Leaning the blades increased the safe operating range,the pressure ratio and efficiency by 14%,4%and 2%respectively.     

Modeling gas oil spray coalescence and vaporization in gas solid riser reactor

The sprayed feed droplet behavior, including coalescence and vaporization into gas–solid flow, is complex especially near the atomizer region in fluid catalytic cracking (FCC) riser reactor. A three dimensional CFD model of the riser reactor has been developed, which takes into the account three phase hydrodynamics, heat transfer and evaporation of the liquid droplets into a gas–solid flow as well as phase interactions. A hybrid Eulerian–Lagrangian approach was applied to numerically simulate the collision and vaporization of gas oil droplets in the gas–solid fluidized bed. This numerical simulation accounts the possibility of coalescence of feed spray droplets in computing the trajectories and its impact on droplet penetration in the reactor. The modeling result shows that droplet coalescence mainly occurs at the initial part of the atomizing region and where three phase flow hits the reactor wall and bounces back. The model has the ability of inspecting the effects of feed injector geometry on the overall reactor hydrodynamic and heat transfer. The CFD simulation results showed that the evaporated droplet gas caused higher local velocities of the gas and solid particles and gas–solid flow temperature reduction.     

Kinetic study of radical polymerization. VII. Investigation into the solution copolymerization of acrylonitrile and itaconic acid by real‐time 1H NMR spectroscopy

Free radical solution copolymerization of acrylonitrile (AN) and itaconic acid (IA) was performed with DMSO‐d₆ as the solvent and 2,2′‐azobisisobutyronitrile (AIBN) as the initiator. Weight ratio of the monomers to solvent and molar ratio of initiator to monomers were constant in all experiments. The initial comonomer composition was the only variable in this study. On‐line ¹H NMR spectroscopy was applied to follow individual monomer conversion. Mole fraction of AN and IA in the reaction mixture (f) and in the copolymer chain (F) were measured with progress of the copolymerization reaction. Overall monomer conversion versus time and also compositions of monomer mixture and copolymer as a function of overall monomer conversion were calculated from the data of individual monomer conversion versus time. Total rate constant for the copolymerization reaction was calculated by using the overall monomer conversion versus time data and then k_p/k_t^0.5 was estimated. The dependency of k_p/k_t^0.5 on IA concentration was studied and it was found that this ratio decreases by increasing the mole fraction of IA in the initial feed. The variation of comonomer and copolymer compositions as a function of overall monomer conversion was calculated theoretically by the terminal model equations and compared with the experimental data. Instantaneous copolymer composition curve showed the formation of alternating copolymer chain during copolymerization reaction. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3253–3260, 2007     

An agent-based simulation with NetLogo platform to evaluate forward osmosis process (PRO Mode)

Forward osmosis (FO), as an emerging technology, is influenced by different factors such as operating conditions, module characteristics, and membrane properties. The general aim of this study was to develop a suitable (flexible, comprehensive, and convenient to use) computational tool which is able to simulate osmosis through an asymmetric membrane oriented in pressure retarded osmosis (PRO) mode in a wide variety of scenarios. For this purpose, an agent-based model was created in NetLogo platform, which is an easy-to-use application environment with graphical visualization abilities and well suited for modeling a complex system evolving over time. The simulation results were validated with empirical data obtained from literature and a great agreement was observed. The effect of various parameters on process performance was investigated in terms of temperature, cross-flow velocity, length of the module, pure water permeability coefficient, and structural parameter of the membrane. Results demonstrated that the increase in all parameters, except structural parameter of the membrane and the length of module led to the increase of average water flux. Moreover, nine different draw solutes were selected in order to assess the influence of net bulk osmotic pressure difference between the draw solution (DS) and feed solution (FS) (known as the driving force of FO process) on water flux. Based on the findings of this paper, the performance of FO process (PRO mode) can be efficiently evaluated using the NetLogo platform.     

Extended adsorption transport models for permeation of copper ions through nanocomposite chitosan/polyvinyl alcohol thin affinity membranes

Transport of copper ions through nanocomposite chitosan/polyvinyl alcohol thin adsorptive membranes has been mathematical y investigated in the current study. Unsteady-state diffusive transport model was coupled with the Freundlich isotherm to predict the concentration of the ions in dialysis permeation operation. Pristine model was not successful in predicting the experimental data based upon its low coefficients of determination (0.1﹤R2﹤0.65). Well-behaved polynomial and exponential functions were used to describe time-dependency of the inlet-concentration in the first extension of the model with a little improvement in the model adjustment (0.4﹤R2﹤0.69). Similar time-dependent functions were employed for tracking the ion diffusivity and then applied in combination with the optimized functions of inlet-concentration in the second extension of the model. A sensible enhancement was obtained in the adjustment of the second extended models as a result of this combination (0.73﹤R2﹤0.93). APRE, AAPRE, RSME, RMSE, STD and R-square statistical analyses were per-formed to verify the agreement of the models with the experimental results. Concentration distribution versus time and location (inside the membrane) was obtained as 3D plots with the help of the optimized models. Modeling results emphasized on the transiency of diffusivity and feed-side concentration in dialysis permeation through chitosan membranes.     

Cu(II)-Based Ionic Liquid Supported on SBA-15 Nanoparticles Catalyst for the Oxidation of Various Alcohols into Carboxylic Acids in the Presence of CO2

In this paper, we have produced carboxylic acids by the oxidation of various alcohols in the presence of CO₂ using SBA-15/IL supported Cu(II) (SBA-15/IL/Cu(II)) as nanocatalyst. The obtained products showed to have excellent yields by taking into account of SBA-15/IL/Cu(II) nanocatalyst. In addition, the analysis of EDX, SEM, TGA, TEM, XPS, and FT-IR showed the heterogeneous structure of SBA-15/IL/Cu (II) catalyst. It is determined that, after using SBA-15 excess, the catalytic stability of the system was enhanced. Moreover, hot filtration provided a full vision in the heterogeneous catalyst nature. The recycling as well as reuse of the catalyst were studied in cases of coupling reactions many times. Moreover, we have studied the mechanism of the coupling reactions.

Graphic Abstract

     

Multi-level enhancement of structural behavior of bracing systems with coupling beams at floor level

Despite good rigidity, braced frames have weak nonlinear behavior and inadequate distribution of ductility in stories, which cause significant structural damage. In this research, a seismic resistant system called coupled concentrically braced frame (CCBF) is developed to enhance the performance of braced frames by coupling them with a beam. In this case, the coupling beams are the primary source for ductility of the system, and after their yielding in more severe earthquakes, the structure continues to benefit from the ductility of the braces as the secondary source; therefore, the system has two-level behavior caused by different probable seismic excitations. In this case, in addition to maintaining the stiffness of the two concentrically braced frames, the coupling beams resist against the movement of the braced frames, and as a result, the stiffness of the system is increased. Therefore, lighter elements can be used to resist lateral loads. Linear and nonlinear analyses of CCBF, and its comparison with other braced frames, indicate that participation of the coupling beams provides an adequate stiffness and ductility. These frames have more stable nonlinear behavior than conventional ones and continue their nonlinear behavior even after fracture of coupling beams in severe earthquakes.