全文获取类型
收费全文 | 820篇 |
免费 | 32篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 29篇 |
综合类 | 1篇 |
化学工业 | 178篇 |
金属工艺 | 11篇 |
机械仪表 | 31篇 |
建筑科学 | 26篇 |
矿业工程 | 3篇 |
能源动力 | 49篇 |
轻工业 | 65篇 |
水利工程 | 15篇 |
石油天然气 | 8篇 |
无线电 | 111篇 |
一般工业技术 | 110篇 |
冶金工业 | 48篇 |
原子能技术 | 13篇 |
自动化技术 | 157篇 |
出版年
2023年 | 5篇 |
2022年 | 21篇 |
2021年 | 27篇 |
2020年 | 39篇 |
2019年 | 36篇 |
2018年 | 56篇 |
2017年 | 43篇 |
2016年 | 41篇 |
2015年 | 24篇 |
2014年 | 56篇 |
2013年 | 84篇 |
2012年 | 60篇 |
2011年 | 65篇 |
2010年 | 57篇 |
2009年 | 40篇 |
2008年 | 32篇 |
2007年 | 26篇 |
2006年 | 23篇 |
2005年 | 17篇 |
2004年 | 16篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 8篇 |
1998年 | 8篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有855条查询结果,搜索用时 15 毫秒
41.
42.
Hwee Yoong Felicia Gok Shahram Emami Jianhneg Shen Martin J. T. Reaney 《Journal of the American Oil Chemists' Society》2013,90(2):299-305
Biodiesel, fatty acid methyl ester (FAME), was produced by transesterification of canola oil with methanol in the presence of a series of alkoxide/hydroxide base catalysts produced from glycerol, 1,2-propanediol, 1,3-propanediol, xylitol, or sorbitol produced by dehydration reaction of sodium hydroxide in the presence of polyols. Transesterification reactions proceeded efficiently in the presence of sodium alkoxide catalysts prepared at three different mole ratios of sodium hydroxide to glycerol (1:1, 2:1, and 3:1). The production of methyl ester during the course of the reaction was determined repeatedly and the reaction progress was compared with that achieved in a reaction catalyzed by freshly prepared anhydrous sodium methoxide as a standard catalyst. Sodium alkoxide/hydroxide catalysts activity during the first 2 min of the reaction was in the order of: sorbitol < xylitol < sodium methoxide < 1,2-propanediol < 1,3-propanediol < glycerol regardless of the mole ratio of sodium hydroxide to glycerol. All catalysts showed a higher methyl ester accumulation at higher ratios of sodium hydroxide to polyol and had the following order 1:1 < 2:1 < 3:1 (sodium hydroxide:glycerol). Several of these catalysts were as powerful as sodium methoxide in catalyzing the transesterification reaction at the same mole concentration. All alkoxide/hydroxide catalysts resulted in a high FAME accumulation (>95 wt%) in a single transesterification batch reaction. 相似文献
43.
2,6‐Bis (4‐aminophenoxy) pyridine was prepared via reaction of 4‐aminophenol with 2,6‐dichloropyridine in the presence of potassium carbonate in N‐methyl‐2‐pyrrolidone (NMP). This pyridine‐based ether diamine was reacted with two moles of trimellitic anhydride to synthesize related diimide‐diacid (DIDA). A high temperature solution polycondensation reaction of DIDA with different diols in the presence of triethylamine hydrochloride in dichlorobenzene resulted in different poly(ether imide ester)s. The monomer and polymers were fully characterized, and the physical and thermal properties of the polymers were studied. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 570–576, 2005 相似文献
44.
Catalysis Letters - In the present paper, an efficient Cu-catalyzed regioselective acylation of indoles with phenylglyoxals was developed which is the first example of indolyl diketones synthesis... 相似文献
45.
Application of the dry‐spinning method to produce poly(ε‐caprolactone) fibers containing bovine serum albumin laden gelatin nanoparticles 下载免费PDF全文
Bahareh Azimi Parviz Nourpanah Mohammad Rabiee Shahram Arbab Maria Grazia Cascone Andrea Baldassare Luigi Lazzeri 《应用聚合物科学杂志》2016,133(48)
We designed and manufactured a polymeric system with combined hydrophilic–hydrophobic properties by loading gelatin nanoparticles (GNPs) containing bovine serum albumin (BSA) into poly(ε‐caprolactone) (PCL) fibers. Our ultimate goal was to create a device capable of carrying and releasing protein drugs. Such a system could find several biomedical applications, such as those in controlled release systems, surgical sutures, and bioactive scaffolds for tissue engineering. A two‐step desolvation method was used to produce GNPs, whereas PCL fibers were produced by a dry‐spinning method. The morphological, mechanical, and thermal properties of the produced system were investigated, and the distribution of nanoparticles both inside and on the surface of the fibers was examined. The effect of the particles on the biodegradability of the fibers was also evaluated. In vitro preliminary tests were performed to study the release of BSA from nanoparticle‐laden fibers and to compare this with its release from free nanoparticles. Our results indicate that the distribution of particles inside the fibers was quite homogeneous and only a few of them were present on the surface. The presence of the particles in the fibers did not affect the thermal properties of the PCL polymer matrix, although it created voids that affected the degradation characteristics so the PCL fibers favored faster erosion compared to the plain fibers. Preliminary results indicate that the release from GNP‐laden fibers occurred much more slowly compared to that in the free GNPs. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44233. 相似文献
46.
Mohammad Reza Nabid Maryam Golbabaee Abdolmajid Bayandori Moghaddam Ali Reza Mahdavian Mostafa Mohammadpour Amini 《Polymer Composites》2009,30(6):841-846
Peroxidase-catalyzed template-guided polymerization of aniline in the presence of γ- alumina nanosheet (NS) particles have been carried out in aqueous media and γ-Al2O3/PANI nanocomposite was obtained. The polymerization of aniline occurred in aqueous solution in the presence of SPS (sulfonated polystyrene) as a template and SDS (sodium dodecyl sulfate) as a surfactant. Both obtained nanocomposites were comparable by SEM images. It was demonstrated that the γ-Al2O3 NS/PANI-SPS nanocomposite has higher conductivity and the γ-Al2O3 NS/PANI-SDS nanocomposite has higher void areas. The higher conductivity of γ-Al2O3 NS/PANI-SPS nanocomposite is attributed to the higher coated areas of γ-Al2O3 NS during polymerization in comparison with γ-Al2O3 NS/PANI-SDS which are not coated efficiently as the former. The FT-IR studies showed that the γ-Al2O3 NS/PANI nanocomposite was formed by interaction of the polyaniline (PANI) and γ-Al2O3 NS. FTIR also showed that the amount of PANI in γ-Al2O3 NS/PANI-SPS is more than in γ-Al2O3 NS/PANI-SDS. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers 相似文献
47.
Sarah Al-Maawi Eva Dohle Jing Lim Paul Weigl Swee Hin Teoh Robert Sader Shahram Ghanaati 《International journal of molecular sciences》2021,22(4)
Introduction: Resorbable synthetic scaffolds are promising for different indications, especially in the context of bone regeneration. However, they require additional biological components to enhance their osteogenic potential. In addition to different cell types, autologous blood-derived matrices offer many advantages to enhance the regenerative capacity of biomaterials. The present study aimed to analyze whether biologization of a PCL-mesh coated using differently centrifuged Platelet rich fibrin (PRF) matrices will have a positive influence on primary human osteoblasts activity in vitro. A polymeric resorbable scaffold (Osteomesh, OsteoporeTM (OP), Singapore) was combined with differently centrifuged PRF matrices to evaluate the additional influence of this biologization concept on bone regeneration in vitro. Peripheral blood of three healthy donors was used to gain PRF matrices centrifuged either at High (710× g, 8 min) or Low (44× g, 8 min) relative centrifugal force (RCF) according to the low speed centrifugation concept (LSCC). OP-PRF constructs were cultured with pOBs. POBs cultured on the uncoated OP served as a control. After three and seven days of cultivation, cell culture supernatants were collected to analyze the pOBs activity by determining the concentrations of VEGF, TGF-β1, PDGF, OPG, IL-8, and ALP- activity. Immunofluorescence staining was used to evaluate the Osteopontin expression of pOBs. After three days, the group of OP+PRFLow+pOBs showed significantly higher expression of IL-8, TGF-ß1, PDGF, and VEGF compared to the group of OP+PRFHigh+pOBs and OP+pOBs. Similar results were observed on day 7. Moreover, OP+PRFLow+pOBs exhibited significantly higher activity of ALP compared to OP+PRFHigh+pOBs and OP+pOBs. Immunofluorescence staining showed a higher number of pOBs adherent to OP+PRFLow+pOBs compared to the groups OP+PRFHigh+pOBs and OP+pOBs. To the best of our knowledge, this study is the first to investigate the osteoblasts activity when cultured on a PRF-coated PCL-mesh in vitro. The presented results suggest that PRFLow centrifuged according to LSCC exhibits autologous blood cells and growth factors, seem to have a significant effect on osteogenesis. Thereby, the combination of OP with PRFLow showed promising results to support bone regeneration. Further in vivo studies are required to verify the results and carry out potential results for clinical translation. 相似文献
48.
49.
Ali?GhasemiEmail author Reza?Kazemi Shahram?Azadi 《Journal of Mechanical Science and Technology》2015,29(2):799-805
The problem of controlling a string of vehicles moving in one dimension is considered so that they all follow a lead vehicle with constant time headway spacing between successive vehicles. Due to realistic design and execution, the negative effect of the tracking lag parameter and time delay is taken into account. By applying an acceleration feedforward, the distance error of each vehicle will be independent of the behavior of other vehicles. As a result, the vehicle is better able to track a desired trajectory, which improves the string stability. Cluster treatment of characteristic roots (CTCR) paradigm is utilized to reveal the stabilizing parametric regions in the domain of the time delay to render the stability of closed loop system. The string stability analysis is performed to evaluate the disturbance attenuation. Finally, an example of multiple vehicle platoon control is presented, which demonstrates the effectiveness of the proposed method. 相似文献
50.
Mahdi Pourafshari Chenar Houman Savoji Mohammad Soltanieh Takeshi Matsuura Shahram Tabe 《Korean Journal of Chemical Engineering》2010,27(6):1876-1881
Impurities such as hydrogen sulfide, water vapor and heavy hydrocarbons in natural gas have considerable effects on the membrane
performance. Small amounts of condensable and polymer soluble components in the feed gas cause swelling or plasticization
of glassy membranes, leading to a reduction in membrane selectivity. In the present research the influence of ethane was investigated
on the permeance and selectivity of two commercially available hollow fiber membranes, namely Cardo-type polyimide and PPO
hollow fibers for CO2/CH4 separations. It was concluded that the gas mixture permeation rate was increased in the presence of C2H6. However, the CO2/CH4 separation factors remained almost the same in the presence and absence of the C2H6. 相似文献