Mode of zero wear in mechanical systems with dry contact

A theoretical and experimental analysis of a mechanical system with dry contact and subject to harmonic excitation is made. The adopted model is a two-degree-of-freedom system representing two sub-structures in dry contacts from their flat ground surfaces. It is theoretically shown that the two sub-structures move in phase with equal amplitudes at a particular frequency of oscillation. This particular frequency is called the frequency of virtual sticking and depends upon the physical properties of the two contacting sub-structures as well as the ratio between the amplitudes of external forces applied on these two structures in the direction of their friction sliding. Zero wear of contact surfaces can thus be established since relative velocity between encountered asperities of sub-structure surfaces becomes zero. It is shown, theoretically and experimentally, that when one of the applied harmonic forces is zero, the frequency of virtual sticking is equal to the natural frequency of the unforced sub-structure. The displacement ratio of the two contacting structures under the effect of harmonic excitation in their sliding direction is investigated within a frequency range up to 400 Hz. The tangential contact stiffness and the dynamic contact rigidity are theoretically determined and experimentally predicted from the measured forced displacement ratio.     

Comparison of the wear resistance of various grades of cemented carbides that may find application in wood machining

A laboratory test is described in which specimens of rectangular cemented carbide tool inserts of a standard size are allowed to slide against a rapidly rotating fiberboard disc in either the presence or the absence of a mist spray of a dilute organic acid (tannic acid or acetic acid) to simulate the cutting of green wood and cured wood respectively. It is shown that the worn surfaces of cemented carbide tools used in (field) service are remarkably similar to the worn surfaces of specimens used in the laboratory (simulation) tests.Extensive results are presented that show quantitatively the progressive wear of a wide range of cemented carbides as a function of time for sliding under wet and dry conditions. It is shown that wear depends on the type and amount of binder present in the cemented carbide and on the nature of the environment. Materials with Co-Cr and Ni-Cr binders containing significant amounts of chromium showed the greatest resistance to wear.     

Optimal Neural Network Model for Characterization of Process-Induced Damage in Drilling Carbon Fiber Reinforced Epoxy Composites

In this paper, a method for robust design of a neural network (NN) model for prediction of delamination (Da), damage width (Dw), and hole surface roughness (Ra) during drilling in carbon fiber reinforced epoxy (BMS 8-256) is presented. This method is based on a parametric analysis of neural network models using a design of experiments approach. The effects of number of neurons (N), hidden layers (L), activation function (AF), and learning algorithm (LA) on the mean square error (MSE) of model prediction are quantified. Using the aforementioned method, a robust NN model was developed that predicted process-induced damage with high accuracy.     

The role of tool composition and tool geometry in controlling the surface finish in machining wood

An examination of several brazed cemented carbide tool inserts that were used in service for cutting cured (dry) pine is described. A laboratory test is also described where the relative resistance to chipping of the brazed tool inserts was measured.It is shown that tool wear occurs through a continuous increase in the tool cutting edge radius that produces a deterioration in the appearance of the machined surface. It is also shown that an increase in either the binder volume fraction or the tool wedge angle produces an increase in the energy absorbed on impact. It is suggested that if progressive wear determines the useful life of a cemented carbide cutting tool then a low volume fraction of binder is required whereas if tool edge chipping determines the useful life of a cutting tool then a large volume fraction of binder and a large tool wedge angle are required.     

The Hydrogenolysis of Commercial Corn Glucose Syrup

Hydrogenolysis of corn syrup was carried out at 170°C and 60 at pressure. After 3 h 92.3% of the glucose content of the syrup was converted into sorbitol.     

Reactions with 5-substituted 4-arylimino-2-thiazolidinones

The reaction of 5-arylidene-4-arylimino-2-thiazolidinones 4 with GRIGNARD reagents effected 1,4-addition to the exocyclic  CC bond with the formation of 5 . Alkylation of the arylidene derivatives 4 with diazomethane or methyl iodide results in the formation of the N-methyl derivatives 6 . Treatment of 6 with phenylmagnesium bromide effects addition of the reagent to the double bond of the lateral chain to yield products, proved to have structure 8 . The 5-arylazo derivatives 9 of 4-arylimino-2-thiazolidinones were obtained by coupling 4 with aromatic diazonium chlorides. Compounds 9 were N-methylated with diazomethane to yield 10 .     

Green Synthesis of Silymarin–Chitosan Nanoparticles as a New Nano Formulation with Enhanced Anti-Fibrotic Effects against Liver Fibrosis

Background: Silymarin (SIL) has long been utilized to treat a variety of liver illnesses, but due to its poor water solubility and low membrane permeability, it has a low oral bioavailability, limiting its therapeutic potential. Aim: Design and evaluate hepatic-targeted delivery of safe biocompatible formulated SIL-loaded chitosan nanoparticles (SCNPs) to enhance SIL’s anti-fibrotic effectiveness in rats with CCl₄-induced liver fibrosis. Methods: The SCNPs and chitosan nanoparticles (CNPs) were prepared by ionotropic gelation technique and are characterized by physicochemical parameters such as particle size, morphology, zeta potential, and in vitro release studies. The therapeutic efficacy of successfully formulated SCNPs and CNPs were subjected to in vivo evaluation studies. Rats were daily administered SIL, SCNPs, and CNPs orally for 30 days. Results: The in vivo study revealed that the synthesized SCNPs demonstrated a significant antifibrotic therapeutic action against CCl₄-induced hepatic injury in rats when compared to treated groups of SIL and CNPs. SCNP-treated rats had a healthy body weight, with normal values for liver weight and liver index, as well as significant improvements in liver functions, inflammatory indicators, antioxidant pathway activation, and lipid peroxidation reduction. The antifibrotic activities of SCNPs were mediated by suppressing the expression of the main fibrosis mediators TGFβR1, COL3A1, and TGFβR2 by boosting the hepatic expression of protective miRNAs; miR-22, miR-29c, and miR-219a, respectively. The anti-fibrotic effects of SCNPs were supported by histopathology and immunohistochemistry (IHC) study. Conclusions: According to the above results, SCNPs might be the best suitable carrier to target liver cells in the treatment of liver fibrosis.     

Infrared Spectra of Nitrated Polymeric Carbohydrates

Nitrated Polymeric carbohydrates are not very pure when used, as their physical constants are neither sharp nor unique for positive identification purposes. The ingredients of explosives are so numerous and it was considered beyond the scope of this investigation to include them.     

Reactivity of the exocyclic double bond in 4-arylidene-2-phenyl-2-imidazolin-5-ones toward organomagnesium compounds. I

4-Arylidene-2-phenyl-1-substituted-2-imidazolin-5-ones 1a – d react with organomagnesium compounds, in ether at room temperature, to yield, as the main isolable products, the 4-disubstituted-methyl derivatives 2a – h . On the other hand, 1a – d react with phenylmagnesium bromide in a boiling ether-benzene mixture to give, among the reaction products, 2a – d and the 4-diarylmethylene derivatives 3a – d . Spectral data of 2 and 3 are discussed. Treatment of the GRIGNARD products 2a – c with formaldehyde and piperidine or morpholine effects aminomethylation at C-4 with the formation of the MANNICH bases 6a – f .