Well‐Defined Functional Linear Aliphatic Diblock Copolyethers: A Versatile Linear Aliphatic Polyether Platform for Selective Functionalizations and Various Nanostructures

Low‐temperature anionic ring‐opening homopolymerizations and copolymerizations of two glycidol derivatives (allyl glycidyl ether (AGE) and ethoxyethyl glycidyl ether (EEGE)) are studied using a metal‐free catalyst system, 3‐phenyl‐1‐propanol (PPA) (an initiator) and 1‐tert‐butyl‐4,4,4‐tris(dimethylamino)‐2,2‐bis[tris‐(dimethylamino)phosphoranylidenamino]‐2Λ⁵,4Λ⁵‐catenadi(phosphazene) (t‐Bu‐P₄) (a promoter) in order to obtain well‐defined functional linear polyethers and diblock copolymers. With the aid of the catalyst system, AGE is found to successfully undergo anionic ring‐opening polymerization (ROP) even at room temperature (low reaction temperature) without any side reactions, producing well‐defined linear AGE‐homopolymer in a unimodal narrow molecular weight distribution. Under the same conditions, EEGE also undergoes polymerization, producing a linear EEGE‐homopolymer in a unimodal narrow molecular‐weight distribution. In this case, however, a side reaction (i.e., chain‐transfer reaction) is found to occur at low levels during the early stages of polymerization. The chemical properties of the monomers in the context of the homopolymerization reactions are considered in the design of a protocol used to synthesize well‐defined linear diblock copolyethers with a variety of compositions. The approach, anionic polymerization via the sequential step feed of AGE and EEGE as the first and second monomers, is found to be free from side reactions at room temperature. Each block of the obtained linear diblock copolymers undergoes selective deprotection to permit further chemical modification for selective functionalization. In addition, thermal properties and structures of the polymers and their post‐modification products are examined. Overall, this study demonstrates that a low‐temperature metal‐free anionic ROP using the PPA/t‐Bu‐P₄ catalyst system is suitable for the production of well‐defined linear AGE‐homopolymers and their diblock copolymers with the EEGE monomer, which are versatile and selectively functionalizable linear aliphatic polyether platforms for a variety of post‐modifications, nanostructures, and their applications.     

Characteristics of solderable electrically conductive adhesives (ECAs) for electronic packaging

This study investigated the effect of the viscosity of the ECAs using a low-melting-point alloy (LMPA) filler on its bonding characteristics. The curing behaviors of the ECAs were determined using Differential Scanning Calorimetry (DSC), and ECA temperature-dependant viscosity characteristics were observed using a torsional parallel rheometer. The wetting test was conducted to investigate the reduction capability of ECAs and the flow-coalescence-wetting behavior of the LMPAs in ECAs. Electrical and mechanical properties were determined and compared to those with commercial ECAs and eutectic tin/lead (Sn/Pb) solder. In the metallurgically interconnected Quad Flat Package (QFP) joint, a typical scallop-type Cu–Sn intermetallic compound (IMC) layer formed at the upper SnBi/Cu interface after curing process. On the other hand, a (Cu, Ni)₆Sn₅ IMC layer formed on the SnBi/ENIG interface. In addition, the fracture surface exhibited by cleavage fracture mode and the fracture was propagated along the Cu–Sn IMC/SnBi interface. The extremely low-level viscosity of ECAs had a significant influence on the flow-coalescence-wetting behavior of the LMPAs in ECAs and also on the interconnection properties. Stable interconnected assemblies showed good electrical and mechanical properties.     

Design of a laminated current cell relocation 12-bit CMOS D/A converter with a high output impedance technique and a merged switching logic

A compact and low power 12-bit 300 MS/s current steering CMOS D/A converter is presented. The architecture of the D/A converter is based on the current steering 6 + 6 segmented type with a laminated current cell relocation technique. In order to improve the linearity and glitch noise, a high output impedance analog current cell is designed. Furthermore, for the purpose of reducing the chip area and power dissipation, a noble merged switching logic and a compact layout technique are proposed. To verify its performance, the chip was fabricated with 0.13 μm thick-gate 1-poly 6-metal N-well Samsung CMOS technology. The effective chip area is 0.26 mm² (510 × 510 μm) with a power consumption of 100 mW. The measured INL and DNL are within ±3LSB and ±1LSB, respectively. The measured SFDR is about 70 dB, when the input frequency is 1 MHz at a clock frequency of 300 MHz.     

Simple and Accurate Design of Low-Density Parity-Check Codes for Multi-Input Multi-Output Systems

In this paper we design an irregular low-density parity-check (LDPC) code for multiple-input multiple-output (MIMO) systems, using a simple extrinsic information transfer (EXIT) chart method. The MIMO systems considered are the optimal maximum a posteriori probability (MAP) detector and the suboptimal minimum mean square error soft-interference cancellation (MMSE-SIC) detector. The MIMO detector and the LDPC decoder exchange soft information and form a turbo iterative receiver. The EXIT charts are used to obtain the edge degree distribution of the irregular LDPC code which is optimized for the MIMO detector. It is shown that the performance of the designed LDPC code is better than that of conventional LDPC code which was optimized for either the Additive White Gaussian Noise (AWGN) channel or the MIMO channel without an explicit consideration of the given detector structure.     

Fabrication of polymeric large-core waveguides for opticalinterconnects using a rubber molding process

Polymeric large-core (47 μm×41 μm) optical waveguides for optical interconnects have been fabricated by using a rubber molding process. For low-cost low-loss large-core waveguides, our newly developed thick-photoresist patterning process is used for a master fabrication. Also a low-loss thermocurable polymer, perfluorocyclobutane (PFCB), is used in fabricating optical waveguides by rubber molding for the first time. The propagation loss is measured to be 0.4 dB/cm at the wavelength of 1.3 μm, and 0.7 dB/cm at the wavelength of 1.55 μm     

Reverse link capacity analysis of a CDMA cellular system with mixedcell sizes

The demands for mobile communication services are growing rapidly. In heavily populated areas, cell splits are unavoidable to increase the capacity of the cellular system. Cell splitting makes a cellular system have mixed cell sizes. For cell planning, it is necessary to analyze the reverse link capacity of a code-division multiple-access (CDMA) cellular system with mixed cell sizes. In this paper, we propose a method to calculate the reverse link capacity of a CDMA cellular system with mixed cell sizes. When a macro cell is split into three micro cells, as an example, we calculate the reverse link capacities for the three micro cells and the neighboring macro cells. The results show that as the radius of a micro cell decreases, the reverse link capacity of the micro cell increases, while those of the neighboring macro cells decrease     

A low-power Ku-band downconverter in InGaP-GaAs HBT technology

We have developed a low-voltage, low-power Ku-band microwave monolithic integrated circuit (MMIC) downconverter using InGaP-GaAs heterojunction bipolar transistor technology. It consists of a preamplifier, a double-balanced mixer, and an L-band wideband intermediate-frequency (IF) amplifier. The downconverter achieves a conversion gain of 31 dB, with a gain flatness within /spl plusmn/ 1 dB, and an output-referred 1-dB compression power (P/sub 1dB,OUT/) of +2.5dBm. This downconverter dissipates 33mA from a 3-V supply. We believe that the operating voltage and power consumption are lower than those of previously published Ku-band MMIC downconverters.     

Low operating currents of monolithically integrated 780 nm/650 nm-band self-sustained pulsating lasers with silicon nitride current blocking layers

The characteristics of monolithically integrated 780 nm/650 nm-band self-sustained pulsating (SSP) lasers with silicon nitride current blocking layers are reported. The record low operating current of 60 mA at 5 mW, 70/spl deg/C and a characteristic temperature of 90 K over 20 to 70/spl deg/C were obtained from the 650 nm-band SSP lasers. The attenuation factor of the visibility was observed to be as low as 0.3, which ensures SSP operations of the dual-mode lasers.     

DS-CDMA reverse link channel assignment based on interferencemeasurements

The authors propose a DS-CDMA reverse link channel assignment algorithm based on received interference. A new channel is assigned if the required power is less than the `current interference margin'. The proposed algorithm is adaptable to dynamically changing environments with the capability of assigning more channels than conventional channel assignment methods in nonhomogeneous traffic loads and path loss changes     

Simulation of polarization converter formed by poling-inducedpolymer waveguides

A polarization converter using electrooptic (EO) polymer waveguides is proposed and it is simulated by a full vectorial beam propagation method (VBPM) for anisotropic medium. First, an efficient structure of poling electrodes is proposed for the fabrication of TE-mode poling-induced waveguides in EO polymer. For given electrode structures of both TE-mode and TM-mode waveguides, poling-induced dielectric tensors are calculated by the finite-element method to provide refractive index distribution, data for VBPM simulation. It is shown numerically that the poled TE and TM mode waveguides work efficiently as the corresponding polarization filters. Then, new poling electrodes are suggested to fabricate a waveguide device formed by connecting the TE and TM mode waveguides adiabatically with a slowly varying structure. This waveguide device has the optic axis slowly rotating as one moves along the propagation direction, so that it will act as polarization converter. VBPM simulation shows that the polarization of the guided mode rotates following the optic axis distribution. Polarization conversion is demonstrated successfully with high conversion efficiency and low excess loss