ESCA study on the mechanism of adherence of metal to silica glass

Indium oxide films formed on the surface of silica glass samples by selective oxidation have been shown to greatly improve the adherence of gold-indium alloy to the silica glass. In order to clarify the role that the oxide films play in the reaction, thin indium films have been evaporated onto silica glass and heated at temperatures of between 973 and 1473 K, both in air and in hydrogen gas. Electron spectroscopy for chemical analysis (ESCA) measurements have then been made to investigate the chemical environments around oxygen and indium atoms at the reacting interface between the oxide and glass. Measured 01s and In3d _5/2 spectra reveal the formation of non-bridging oxygen atoms at the interface, in addition to the original bridging oxygen atoms in silica glass. Introduction of the non-bridging oxygen atoms and indium ions into the silica glass is concluded to be an essential factor in promoting good adherence between the gold alloy and silica glass.     

Effect ofin Situ cooling on superconductivity of artificially layered BSCCO films with 2223 structure

Thin BSCCO films with the 2223 structure were deposited onto MgO substrate kept at 665°C by applying a sequential sputtering method using metallic Bi and Sr-Ca-Cu-O targets. The resultant films were then cooled under various oxygen partial pressures and cooling rates. It was found that the oxygen partial pressure and substrate temperature during cooling affect significantly the development of superconductivity of the as-deposited films. When the films were cooled stepwise under a critical oxygen partial pressure around 0.3 torr, the as-deposited films showed either superconductivity or nonsuperconductivity behavior. HRTEM images of the films showed no essential difference in the modulated structure, suggesting that the excess oxygen in the Bi-O double layers is the same and not the cause of the different superconducting behavior in the as-deposited films.     

Expansion of a static analysis-based out-of-plane maximum inelastic seismic response estimation method for steel arch bridges to in-plane response estimation

We have previously proposed a static analysis-based method for estimating the maximum out-of-plane inelastic seismic response of upper-deck steel arch bridges. The method is developed on the basis of the numerical examinations of 6 upper-deck steel arch bridge models. It employs free vibration analysis, response spectrum method and equal energy assumption for the estimation of maximum out-of-plane response. Correction functions are proposed to modify the estimates by the equal energy assumption. In the current study, applicability of the same procedure to the estimation of maximum in-plane response is discussed. It is found that the method can be used also for the maximum in-plane response estimation by only modifying the pushover analysis procedure. The validity of the method is demonstrated for the same parametric models through further numerical evaluations.     

Fast and robust training of a probabilistic latent semantic analysis model by the parallel learning and data segmentation

Probabilistic Latent Semantic Analysis （PLSA） is proven to be effective in the information retrieval and the speech recognition technique. In this paper, we modify the calculation procedure of estimation algorithm. It substantially reduces the memory requirements. And, parallelization approach enables making models in less time. Next, we examined data segmentation for PLSA adaptation. Most meetings have a number of topics. We divide the meeting automatically and fit PLSA models with them. The experiment showed recognition performance improvement.     

Effects of material strain rate sensitivity in low speed impact between two identical spheres

This paper investigates the effects of strain rate sensitivity on the impact of two identical spheres. The spheres made of SUJ2 steel were impacted by using pendulum setup. The coefficients of restitution (COR) and contact durations were obtained experimentally. Static tensile test and Split Hopkinson pressure bar tests were conducted to identify the material properties of the sphere. And finite element simulations of the impacts between two identical spheres were carried out using LS-DYNA software. The simulation results fit well to the experimental results and they were compared to the results of elasto-plastic simulations which ignored the material strain rate sensitivity. It was found that the strain rate sensitive sphere showed the higher COR than those from the sphere which ignored the material strain rate sensitivity. Therefore, the material strain rate sensitivity has remarkable effect on the impact of two identical spheres even in the low speed impact. However, the influences of the material strain rate sensitivity on the contact durations were small.     

Direct Patterning of Silver Circuit Using Surface- modification and UV Irradiation on Polyimide Resin

A simplified method is proposed for the formation of a silver circuit pattern on a polyimide resin substrate through modification of the resin surface followed by adsorption of silver(l) ion and UV photoreduction to form patterns. The amide bond and carboxyl group, as a cation exchange group, were formed on the polyimide resin surface by a potassium hydroxide treatment. UV irradiation of the adsorbed silver(I) ion results in the formation of a silver thin film. Silver circuit patterns are easily formed on the modified polyimide resin substrates without using a plating resist by use of a metal-on-quart: mask     

Marangoni convection driven by thermocapillary and solutocapillary forces in the Fe-O alloy pool during the solidification or remelting process

Marangoni convection during the solidification or remelting process was investigated in a small pool of a liquid Fe-O alloy, by experiments and numerical simulations. Most of the studies of such a system, with a low Prandtl number but a high Schmidt number, have taken into account thermocapillary convection but have left the solutocapillary effect out of consideration. However, our experimental and numerical approaches revealed that solutocapillary convection also plays an important role in the generation of peculiar flow patterns with a single roll cell or two roll cells. The Marangoni convection observed was classified into at least four categories based on the thermocapillary and solutocapillary forces.     

Field emission from diamond particles studied by scanning field emission microscopy

Field emission properties from diamond particles (DPs) are studied. The DPs with thin chemically vapor deposited (CVD) diamond overcoat, dispersed onto metal substrate, essentially exhibit negative electron affinity (NEA). Field emission, approximately 1mA/cm(2) under a macroscopic electric field of 3.5kV/mm are observed. Microscopic electrical properties were studied by scanning tunneling microscopy/spectroscopy. Most parts of the DP surface exhibit narrow gap and p-type characteristics. The localized regions, which have wide gap like bulk diamond properties, are randomly distributed near the top of DP. The field emission current distribution depicted by scanning field emission microscopy (SFEM) show that the electron emission is originating from a localized region on the selected DPs. We found, through SFEM measurement, some favorable field emission spots ("hot spots") where measured emission current is several orders higher than that of the other DPs ("normal spots"). Field emission spectroscopy (FES) results suggest that a poorly conducting layer is present along the electron path from the metal electrode to vacuum.We propose two models for field emission from "hot spots", which involve two main mechanisms. One is electron injection from the metal substrate to the DP, which is attributed to the electric field enhancement at intrinsic non-doped diamond (i-diamond) layer sandwiched between the metal substrate and the surface conductive layer (p-diamond) of the CVD diamond overcoat on the DP. The other is electron emission at the top site of NEA DP through the local i-diamond region or the depletion region of the p-diamond, which is caused by the applied electric field.