Thermal and crystallization characteristics of poly(ethylene terephthalate) with poly(oxybenzoate‐p‐trimethylene terephthalate) copolymer

Poly(ethylene terephthalate) (PET) was blended with two different poly(oxybenzoate‐p‐trimethylene terephthalate) copolymers, designated T28 and T64, with the level of copolymer varying from 1 to 15 wt %. All samples were prepared by solution blending in a 60/40 (by weight) phenol/tetrachloroethane solvent at 50°C. The crystallization behavior of the samples was studied by DSC. The results indicate that both T28 and T64 accelerated the crystallization rate of PET in a manner similar to that of a nucleating agent. The acceleration of PET crystallization rate was most pronounced in the PET/T64 blends with a maximum level at 5 wt % of T64. The melting temperatures for the blends are comparable to that of pure PET. The observed changes in crystallization behavior are explained by the effect of the physical state of the copolyester during PET crystallization as well as the amount of copolymer in the blends. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1599–1606, 2002     

江苏省泗洪县湿地公园雕塑创作浅析

江苏省泗洪县有着悠久的历史底蕴和深厚的文化背景,泗洪湿地公园是国家级湿地保护区.笔者受当地县政府委托在湿地公园入口处设计制作一幅大型浮雕壁画,前景是两尊立体的2.8米圆雕人物,照壁30米长,2.8米高,记载历史故事和民俗风情.以当地的泗洪湿地的特色飞禽白鹭贯穿始终,将不同时期的人物与景观自然地连贯穿插.并以文武两位名士的圆雕塑像为主要历史文脉,提升湿地公园的历史和人文内涵.湿地公园的雕塑寓意深刻、内涵丰富、品味高雅.雕塑紧扣泗洪县当地的自然环境和历史文化,为泗洪湿地公园增添了风采和神韵.     

MC(Mid-Century)催化氧化过程的研究进展

介绍了MC催化氧化过程规律；从催化荆体系的改进、新型溶剂体系的开发、反应器构型和配套设施的改进、富氧氧化技术的开发等方面综述了近年来MC技术的发展；探讨了MC液相催化氧化技术应用范围的拓展以及MC液相催化氧化过程的发展方向。     

Crystallization behavior,mechanical properties,and environmental biodegradability of poly(β‐hydroxybutyrate)/cellulose acetate butyrate blends

The miscibility, crystallization behavior, tensile properties, and environmental biodegradability of poly(β‐hydroxybutyrate) (PHB)/cellulose acetate butyrate (CAB) blends were studied with differential scanning calorimetry, scanning electron microscopy, wide‐angle X‐ray diffraction, and polarizing optical microscopy. The results indicated that PHB and CAB were miscible in the melt state. With an increase in the CAB content, the degree of crystallinity and melting temperature of the PHB phase decreased, and this broadened the narrow processability window of PHB. As the elongation at break increased from 2.2 to 7.3%, the toughness and ductility of PHB improved. From the degradation test, it could be concluded that degradation occurred gradually from the surface to the inside and that the degradation rate could be adjusted by the addition of the CAB content. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2116–2122, 2003     

Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

Bone Tissue Response to the Bone-like Tissue Coating on Titanium

The objective of this study was to investigate the effects of mineralized bone nodules, formed in vitro by bone marrow stromal cells(BMSCs), on the new bone formation in bone defect and on implant surface. The mineralized bone nodules were generated by culture of Lewis rats BMSCs on titanium disks in osteogenic induction medium. The gap-healing animal model was used to create the bone defect facing the disk. The titanium disks in the presence of B group or in the absence of NB group bone nodules were randomly placed into one of the rat distal femurs. This self-control design was used to compare the bone formation in defects and on titanium surface, by Micro-CT, fluorescence staining, histological and histomorphometric analysis. The new bone formation parameters in bone defect area of B group were significantly higher than those of NB group at 2 weeks, including bone volume fraction, trabecular thickness and bone area ratio. The bone nodules pre-stained with Alizarin red disappeared mostly at 2 weeks, while the red fluorescence reappeared in the newly formed bone away from the disk surface. For the bone-implant contact, B group showed lower values than NB group at 2 weeks, but no significant difference was found at 4 weeks. Our results indicate that the mineralized bone nodules can be resorbed in vivo and promote the early osteogenesis in the bone defects, and bone nodules may be applicable for new bone generation in bone defect or modification of tissue engineering scaffold.     

微创业:大学生创业实践教育的思考

大学生创业实践是高校创业教育的一个难题。当前国内高校创业教育普遍存在实践教育环节薄弱、效果不显著等问题,本研究同步社会经济发展,尝试以微创业视角思考高校创业实践教育,通过梳理微创业的概念及应用,从契合大学生需求角度分析微创业具有的时代性、低门槛、大众化、创新性等特点。并根据高校实际情况,从完善微创业环境、开设微创业课程、建立微创业实践基地、提供微创业网络平台服务等方面提出推动高校大学生微创业的路径建议。     

超细Al（OH）3的粒度控制研究

采用铝酸钠种子分解法制备超细Al（OH）3.用X射线衍射仪（XRD）表征了样品的晶相组成,用扫描电子显微镜（SEM）观察了样品的形貌,用激光粒度分析仪测定样品的粒度分布.研究了NaOH浓度、NaOH/Al（OH）3摩尔比,分解温度,分解时间、晶种率和搅拌速率等因素对Al（OH）3的粒度的影响.结果表明：NaOH浓度越高,分解温度越低,NaOH/Al（OH）3摩尔比越小,得到的Al（OH）3颗粒的粒度越小.试验条件为：NaOH浓度180 g/L,NaOH/Al（OH）3摩尔比1.15,分解温度40℃,分解时间26 h,晶种率8％,搅拌速率200 rpm时,氢氧化铝颗粒的平均粒度为2.89 μm.