铝矾土种类和用量对锆刚玉莫来石性能影响的灰色关联分析

采用工业氧化铝、锆英石和氧化铈合成锆刚玉莫来石,着重讨论了两种铝矾土部分取代工业氧化铝对锆刚玉莫来石材料性能的影响。通过灰色关联分析,得到结论为:铝矾土中的熔剂数量是影响材料抗折强度的主要因素,当铝矾土中杂质少SiO2含量较高时,试样的吸水率与铝矾土的加入量关联性最大。     

我国耐火材料矿物资源状况与发展问题的讨论

介绍了我国耐火资源的现状和开发利用状况,包括我国耐火资源储量分析、耐火资源的行业配置、耐火矿物资源消耗状况以及耐火矿物资源利用情况。对合理利用耐火资源,走可持续发展道路提出建议;通过改进原料产品生产工艺,提高耐火矿物资源的利用效能;合理使用耐火材料,降低耐火资源的消耗。     

碳纤维片材加固钢筋混凝土梁的问题探讨

碳纤维片材加固钢筋混凝土梁的问题包括碳纤维片材加固钢筋混凝土梁的应用前提、钢筋混凝土梁斜向贴碳纤维抗剪加固承载力计算和使用阶段加固梁的验算公式。这些问题是对现行规范的补充和完善,并提出有待进一步研究的问题。     

蝴蝶兰叶片组织快速繁殖工艺和方法

蝴蝶兰叶片组织在无菌条件下接种于添加1.8 mg·L-1 6-BA和1.5 mg·L-1 NAA的MS培养基(细胞诱导分生培养基)中,培养7 d,叶片细胞逐渐增殖培养生成芽苗;将芽苗切割分离接种于添加1.0 mg·L-1 6-BA和1.0 mg·L-1 NAA的MS培养基(芽苗增殖培养基)中,无菌培养9 d后,蝴蝶兰芽苗诱导生成幼苗;将蝴蝶兰幼苗转接入添加激素0.1 mg·L-1 NAA的MS培养基(生根培养基)中,培养15 d后,幼苗诱导生根,形成完整的蝴蝶兰小植株.     

改性凹凸棒土净化含铬废水的研究

将凹凸棒土进行改性处理，用于对含铬废水中铬离子的吸附。本文研究了改性方式、凹凸棒土用量、吸附时间、pH值对含铬废水中铬离子净化率的影响。     

水解酸化-膜生物反应器处理化工综合废水

采用水解酸化-浸没式膜生物反应器工艺处理化工综合废水。小试结果表明:在进水CODCr的质量浓度为1500～2400mg/L,BOD5与CODCr的质量比为0.28～0.35,pH值为6～9,水解酸化、膜生物反应器HRT分别为12、18h,膜通量约16L/(m2.d),污泥负荷约为0.38[CODCr]/(kg[MLVSS].d)时,经该工艺处理,CODCr、挥发酚去除率分别达到92%、97%以上,且膜生物反应器出水浊度小于1NTU,未检测到SS。     

Effects of K<Subscript>4</Subscript>Fe(CN)<Subscript>6</Subscript> on electroless copper plating using hypophosphite as reducing agent

K₄Fe(CN)₆ was used to improve the microstructure and properties of copper deposits obtained from hypophosphite baths. In electroless copper plating solutions using hypophosphite as the reducing agent, nickel ions (0.0038 M with Ni²⁺/Cu²⁺ mole ratio 0.12) was used to catalyze hypophosphite oxidation. However, the color of the copper deposits was dark or brown and its resistivity was much higher than that obtained in formaldehyde baths. The effects of K₄Fe(CN)₆ on the deposit composition, resistivity, structure, morphology and the electrochemical reactions of hypophosphite (oxidation) and cupric ion (reduction) have been investigated. The deposition rate and the resistivity of the copper deposits decreased significantly with the addition of K₄Fe(CN)₆ to the plating solution and the color of the deposits changed from dark-brown to copper-bright with improved uniformity. The nickel and phosphorus content in the deposits also decreased slightly with the use of K₄Fe(CN)₆. Smaller crystallite size and higher (111) plane orientation were obtained by addition of K₄Fe(CN)₆. The electrochemical current–voltage results show that K₄Fe(CN)₆ inhibited the catalytic oxidation of hypophosphite at active nickel sites and reduced the reduction reaction of cupric ions on the deposit surface by adsorption on the electrode. This results in lower deposition rate and a decrease in the mole ratio of NaH₂PO₂/CuSO₄ consumed during plating.     

薄板坯连铸结晶器技术及钢种开发的几个问题分析(续)

薄板坯连铸结晶器是薄板坯连铸技术的核心,通过对薄板坯连铸结晶器内钢水的流动、传热以及凝固壳的收缩和变形行为的研究,分析了连铸坯几种典型裂纹缺陷的形成原因;并结合实验室和生产实践,对薄板坯连铸连轧生产冷轧基料用B微合金化钢、电工钢、V-N微合金高强度钢等的工艺特性以及钢材性能进行了分析。文章分二次发表,本次是上海金属2006—1期文章的续栽,内容是关于薄板坯连铸连轧典型品种的开发以及薄板坯连铸连轧技术的发展与展望。     

脉冲电流对Al-4.5Cu合金定向凝固组织的影响

研究了脉冲电流对Al-4．5Cu合金定向凝固过程及组织的影响。结果表明，随着脉冲电流峰值和频率的增大，Al—4．5Cu合金柱状晶被熔断，形态由细条状变为不连续，失去其定向凝固的取向性；且柱状晶间距随电流峰值和频率的增大而减小。由脉冲电流的引入而产生的脉冲磁压力及焦耳热效应在固液界面处造成的强烈扰动是定向凝固组织失去取向性的主要原因。     

Synthesis and Characterization of Highly Dispersed Antimony-Doped Stannic Hydroxide Nanoparticles: Effects of the Azeotropic Solvents to Remove Water on the Properties and Microstructures of the Nanoparticles

Highly dispersed antimony (Sb)-doped stannic hydroxide nanoparticles have been successfully prepared using the solution chemistry method. The properties and microstructures of the nanoparticles are investigated in detail by means of infrared, transmission electron microscope, X-ray diffractometer, and Brunauer-Emmett-Teller nitrogen surface area measurements. The results indicate that the properties and microstructures of the nanoparticles strongly depend on the azeotropic solvents used to remove water at the drying stage. Various azeotropic solvents are screened to investigate their effects on the size and dispersivity of dried Sb-doped stannic hydroxide. Three empirical rules are drawn for selecting an effective azeotropic solvent: (1) the solvent molecule should contain at least one atom such as oxygen as the hydrogen (H)-bond acceptor to form H bonds with the surface –OH (acting as an H-bond donor) of polymer particle; (2) the H-bond acceptor should locate in the middle of the alkane chain rather than on the terminal so that the alkane chain can stretch out and cover more surface area, improving the dispersivity of the dried product; and (3) the solvent should have a higher boiling point (∼140°C) to reduce the time of azeotropic distillation for removing water and maintain a lower residual amount of azeotropic agent. Based on the empirical rules, it is discovered that iso-amyl acetate is the most effective azeotropic solvent.