Editorial: Security and Privacy in Internet of Things

Mobile Networks and Applications -     

Advanced characterization technique for mechanochemically synthesized materials: neutron total scattering analysis

Materials that adopt the pyrochlore (A₂B₂O₇) structure show promise for use in a variety of energy-related applications such as immobilization of actinide-rich nuclear waste and oxide fuel cells. Mechanochemical synthesis, a combination of milling and high-temperature treatment, has been successfully applied to fabricate many different pyrochlore compositions. High-resolution neutron total scattering experiments were used to gain fundamental insight into the structural details of milled Er₂Ti₂O₇ pyrochlore and the subsequent evolution under high-temperature treatment. The milling process creates a highly disordered structure in which local atomic ordering is present that is significantly different than the observed long-range behavior. Thermal annealing leads to a complex defect recovery scheme with a gradual local rearrangement from a weberite-type atomic ordering to a pyrochlore phase independent of the sharp long-range crystallization process. Annealing of the milled sample up to 1200 °C does not reproduce the local structure of the same pyrochlore sample prepared by solid-state synthesis. This indicates that despite both samples possessing identical long-range structures, local defects induced by the milling process persist to very high temperatures. These findings provide a direct insight into the mechanochemical synthesis of pyrochlore oxides and help to better elucidate the structural properties of highly disordered complex oxides under extreme conditions from the local atomic arrangement to the macroscale.     

On the use of British standard 7910 option 1 failure assessment diagram to non‐metallic materials

This paper provides a structural integrity assessment methodology for the analysis of non‐metallic materials. The approach uses the British standard 7910 option 1 failure assessment diagram, originally proposed for the fracture‐plastic collapse assessment of metallic materials. The methodology has been applied to 60 fracture specimens, combining 12 different materials and covering polymers, composites, and rocks. The results obtained validate the proposed assessment methodology and demonstrate its safety for the materials analysed here.     

“What do you want for dinner?” – need anticipation and the design of proactive technologies for the home

This paper examines ‘the routine shop’ as part of a project that is exploring automation and autonomy in the Internet of Things. In particular we explicate the ‘work’ involved in anticipating need using an ethnomethodological analysis that makes visible the mundane, ‘seen but unnoticed’ methodologies that household members accountably employ to organise list construction and accomplish calculation on the shop floor. We discuss and reflect on the challenges members’ methodologies pose for proactive systems that seek to support domestic grocery shopping, including the challenges of sensing, learning and predicting, and gearing autonomous agents into social practice within the home.     

Alkaline earth metal-based catalyst and process for selective hydrocarbon conversion to acetylene and carbon monoxide

A multi-step process that employs a Ni-modified mixed alkaline earth metal oxides (AEMO) has been developed for the selective conversion of hydrocarbons to C₂H₂ and CO. The initial process step is the catalytic decomposition of a gaseous hydrocarbon mixture at an elevated temperature (ca. 800 °C) over Ni/AEMO, generating H₂, trace CO, carbon (C), and trace alkaline earth metal carbide (MC₂). The Ni/AEMO/C/MC₂ material is then heated to consume the remaining carbon, generate more MC₂, and evolve CO. Then, Ni/AEMO/MC₂ is cooled and reacted with excess H₂O at a low temperature (20 < T (°C) < 80) to selectively generate C₂H₂ and Ni/AEM(OH)₂·zH₂O. In the final process step, Ni/AEM(OH)₂·zH₂O is decomposed to yield H₂O and Ni/AEMO, which is recycled within the process. The most advanced Ni/AEMO materials developed thus far exhibit intrinsic production capacities exceeding 2000 μmoles of C₂H₂ per gram of Ni/AEMO per process cycle.     

Phase Change Behavior of Nitinol Shape Memory Alloys

Among other special characteristics Shape Memory Alloys (SMAs) have the ability to return to a predetermined shape when heated. In fact, the phase change of an existing element can strongly be influenced by thermal and thermo‐mechanical treatments. Up to now, SMEs have been discovered in various materials, which can generally be classified into noble‐metal based, Cu‐based, Fe‐based, Ni‐Ti‐based alloy systems and non‐metallic SMAs. In this paper a general overview of the Ni‐Ti system and a detailed review over the Ni‐Ti‐Cu system will be given with special regard to the influence of heat treatments upon the phase change behavior.     

Paradigmatic De Novo GRIN1 Variants Recapitulate Pathophysiological Mechanisms Underlying GRIN1-Related Disorder Clinical Spectrum

Background: GRIN-related disorders (GRD), the so-called grinpathies, is a group of rare encephalopathies caused by mutations affecting GRIN genes (mostly GRIN1, GRIN2A and GRIN2B genes), which encode for the GluN subunit of the N-methyl D-aspartate (NMDA) type ionotropic glutamate receptors. A growing number of functional studies indicate that GRIN-encoded GluN1 subunit disturbances can be dichotomically classified into gain- and loss-of-function, although intermediate complex scenarios are often present. Methods: In this study, we aimed to delineate the structural and functional alterations of GRIN1 disease-associated variants, and their correlations with clinical symptoms in a Spanish cohort of 15 paediatric encephalopathy patients harbouring these variants. Results: Patients harbouring GRIN1 disease-associated variants have been clinically deeply-phenotyped. Further, using computational and in vitro approaches, we identified different critical checkpoints affecting GluN1 biogenesis (protein stability, subunit assembly and surface trafficking) and/or NMDAR biophysical properties, and their association with GRD clinical symptoms. Conclusions: Our findings show a strong correlation between GRIN1 variants-associated structural and functional outcomes. This structural-functional stratification provides relevant insights of genotype-phenotype association, contributing to future precision medicine of GRIN1-related encephalopathies.     

Thermal diffusivity of nanofluids containing Au/Pd bimetallic nanoparticles of different compositions

Colloidal suspensions of bimetallic Au/Pd nanoparticles were prepared by simultaneous reduction of the metal ions from their corresponding chloride salts with polymer (PVP) stabilizer. Thermal properties of water containing bimetallic nanoparticles with different nominal compositions (Au/Pd = 12/1, 5/1, 1/1, 1/5) were measured using the mode mismatched dual-beam thermal lens technique to determine the effect of particle composition on the thermal diffusivity of the nanofluids. The characteristic time constant of the transient thermal lens was estimated by fitting the experimental data to the theoretical expression for transient thermal lens. The thermal diffusivity of the nanofluids (water, containing Au/Pd bimetallic nanoparticles) is seen to be strongly dependent on the composition of the particles. The maximum diffusivity was achieved for the nanoparticles with highest Au/Pd molar ratio. A possible mechanism for such high thermal diffusivity of the nanofluids with bimetallic particles is given. UV-Vis spectroscopy, TEM and high-resolution electron microscopy (HREM) techniques were used to characterize the Au/Pd bimetallic nanoparticles.     

In vitro release kinetics and physical, chemical and mechanical characterization of a POVIAC ? /CaCO 3 /HAP-200 composite

Coralline calcium-hydroxyapatite and calcium carbonate from Porites Porites coral were added to a polymeric matrix based on polyvinyl acetate (POVIAC^?), to obtain a novel bone substitute composite as well as a system for the controlled drug (cephalexin) release. Composite samples with different compositions were characterized by physical–chemical and mechanical methods. Furthermore, the in vitro release profile of cephalexin and the kinetic behavior of its release from these composites were analyzed by appropriate mathematical models. It was shown that there is no chemical interaction between the inorganic filler and the polymer matrix, each conserving the original properties of the raw materials. The compressive mechanical strength and Young modulus of the composite with 17.5% of POVIAC^?, has better mechanical properties than those of cancellous bone. The variation of POVIAC^? content can affect the cephalexin release kinetic in the composite. The cephalexin release mechanism from the composites can be considered as the result of the joint contribution of a prevailing Fickian diffusion and of polymer chain relaxation. It was also demonstrated that cephalexin is occluded inside the composites and not on their surface.