Relaxor Behavior of Ge-Doped TlInS2

The dielectric and pyroelectric properties of Ge-doped (0.1 mol %) TlInS₂ crystals are studied. The results demonstrate that TlInS₂ is a ferroelectric relaxor. The experimental data are used to evaluate, using the Vogel–Fulcher relation, the activation energy (0.045 eV), preexponential factor (f ₀ = 2 × 10¹³ Hz), and the dipole-freezing temperature (T _F = 142 K) and to determine the temperature range of the stable relaxor (nanodomain) state and the temperature of the transition to the ferroelectric (macrodomain) state, accompanied by an anomaly in the temperature-dependent pyroelectric coefficient.     

Electrosprayed and selenized Cu/In metal particle films

Nano-particulate copper and indium metal layers of 1-2 μm have been deposited by non-vacuum techniques such as doctor blade, screen printing and electrospray using alcoholic suspension pastes. Electrospray showed a high efficiency of material usage and yielded the most uniform morphology. The metal precursor layers were subjected to a thermal treatment (500-600 °C) in selenium vapor to convert the porous metal layers into CuInSe₂ compound layers. The chemical conversion, investigated by X-ray diffraction, showed the presence of the In₂O₃ impurity phase in the precursor as well as in the selenized layers.     

Preparation and properties of heavy-metal halide glasses

We have studied the effect of In³⁺, Pb²⁺, Gd³⁺, and Cl (heavier ions) substitutions for Al³⁺, Ba²⁺, La³⁺, and F^? on the crystallization stability and UV/IR optical properties of HBLAN fluorohafnatc glasses (HfF₄-BaF₂-LaF₃-AlF₃-NaF system). We obtained stable glasses containing InF₃ and BaCl₂ instead of AlF₃ and BaF₂, respectively, and offering increased IR transmission. The presence of CCl₄ in the process atmosphere and the removal of oxygen-containing impurities via directional solidification are shown to have an advantageous effect on the optical quality of the glasses. The fluoride-chloride glasses are capable of accommodating about 1.5 times higher levels of rare-earth activators in comparison with their fluoride analogs.     

Thermal Stressed State of a Hollow Metallic Cylinder under the Action of Electromagnetic Fields in the Mode of Damped Sinusoid

We determine the temperature fields and stresses formed in a long hollow conducting cylinder under the action of pulsed electromagnetic fields specified by the values of the axial component of the vector of intensity of a uniform magnetic field on the inner and outer surfaces. We consider the case where the electromagnetic action obeys the law of damped sinusoid on the inner and outer surfaces of the cylinder.     

Modeling of the Rheological Behavior of Wood in Compression Processes

A rheological equation of state for wood which allows for the running values of its porosity and humidity is considered.     

Study of phase equilibria in the Al - Pd - Re system

Scanning and transmission electron microscopy have been combined with x-ray diffraction to examine the phase equilibria in the Al - Pd - Re system at 1000°C for compositions from 50 to 100 at.% Al, and the corresponding isothermal section has been constructed. The binary monoclinic Al₃ Re phase has been observed for the first time. It is confirmed that there is a stable icosahedral phase in this system. The boundaries to its homogeneity region have been determined and the phase equilibria in which it participates.     

Biochemical oxidation of caprolactam-containing wastewater from the production of synthetic fibres

Conclusions The chemical mutagenesis method is recommended for use in local purification installations for cleaning up of caprolactam-containing wastewater.Use of this method permits one to carry out a biochemical clean-up of wastewater having a caprolactam content up to 600 mg/liter while increasing the oxidative power of the aeration tank by a factor of two.Translated from Khimicheskie Volokna, No. 6, p. 46, November–December, 1985.     

Convective transfer processes in chemically stable and reacting liquids with an internal structure

Dynamic processes are studied in media with softly and hardly internal destroyable configurations. A method is examined for the measurement of properties of media with spatial separation of the chemical transformation stages and thermal hydrodynamic measurements.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 53, No. 5, pp. 781–789, November, 1987.