Spark Plasma Sintering of fine alpha-silicon nitride ceramics with LAS for spatial applications

Many space systems such as satellite mirrors and their supporting structures require to be made from very low-thermal expansion materials combining both high hydrostability and relatively high mechanical properties. In this study, we have applied the “composite concept” in order to explore the possibility of fabricating near zero thermal expansion silicon nitride based ceramics. Consequently, a negative thermal expansion material belonged to the lithium aluminosilicate family (LAS powder crystallized under de β-eucryptite structure) was introduced in an alpha-silicon nitride fine powder (5 and 20 vol% of LAS) and the resulting composite system was sintered by Spark Plasma Sintering (SPS) at 1400 and 1500 °C. In the case of 20 vol% LAS compositions, relatively well-densified ceramics (94.4% of the theoretical density) were produced without adding any further sintering additive. The addition of yttria and alumina oxides allowed enhancing the densification level up to 98.2% (20 vol% LAS compositions) or from 62.3% up to 96.7% of the theoretical density in 5 vol% LAS materials. Nevertheless, it was impossible to full consolidate silicon nitride/LAS composite ceramics at temperatures lower than the temperature at which β-eucryptite melts, even by using SPS technology. Moreover, because of the relatively low temperatures involved in SPS, the α to β-Si₃N₄ transformation was avoided, resulting in microstructures composed of fine equiaxed α-Si₃N₄ grains (<200 nm) and of a glassy phase. Even if the effect of having a very large negative thermal expansion material was lost during the sintering step (because of the β-eucryptite melting), ceramics containing only 20 vol% of LAS-based phase exhibited very interesting values as regards of mechanical properties (strength, hardness, toughness, and Young's modulus), thermal conductivity and thermal expansion coefficient. We discuss in this work why we are so interested in developing dense silicon nitride/LAS ceramics sintered without any further additive addition, even though β-eucryptite is melted during the process and the transformation to the β phase is avoided.     

Primary vacuum standard for UHV range — Standing experience and present problems

Accurate calibrations of gauges to ever lower pressures (higher vacuum) are increasingly becoming necessary. The calibrations over the entire ultra high vacuum (UHV) range i.e. up to 10⁻¹⁰ Pa are already sometimes demanded by the users of vacuum measuring devices. Standards covering part of this range are available in some national metrological laboratories while primary standards covering the entire UHV range are under development. However, the most suitable principle of the primary standard for generating such a low pressure is still not clear. In spite of some attempts during the last century no sufficiently accurate absolute (“calibration-free”) gauge for high vacuum (HV) and UHV ranges has been developed to date. Apparatuses for generating gas pressure in a dynamic flow control method will continue to be used as primary standards for the UHV range, but, by virtue of technical difficulties, the equilibrium (Maxwellian velocity distribution) will be severely disturbed during the process of pressure generation that the pressure in the chamber will not be defined as a simple scalar quantity. This principal problem must be solved first by the development of a primary UHV standard. Another serious problem in the design of an apparatusfor generating controlled pressures on the order of 10⁻¹⁰ Pa requires the uncontrolled changes of gas pressure to 10⁻¹² Pa or lower. Hence an extremely high vacuum (XHV) apparatus must be used in which the requirements concerning the pumps and the outgassing rate from the materials are kept very strict.     

Effect of high shear stress on microbial viability

Escherichia coli and Saccharomyces cerevisiae suspensions were submitted to controlled shear stress. Above a threshold value shear stress induced a decrease in micro‐organism viability. The threshold of shear stress efficiency depended on the micro‐organisms, being between 1292 Pa and 2770 Pa for S cerevisiae, and about 1250 Pa for E coli. Above 1810 Pa, E coli cells were disrupted whereas the S cerevisiae cells remained intact. The higher the cellular concentration, the greater the rate of decrease in viability. Viability loss was influenced by the number of passages through the experimental shear stress device and by exposure time. © 2001 Society of Chemical Industry     

Preparation and dielectric properties of polymer-derived SiCTi ceramics

SiCTi ceramics were prepared by a polymer-derived-ceramic route, with allylhydridopolycarbosilane (AHPCS) and bis(cyclopentadienyl) titanium dichloride (Cp₂TiCl₂) as starting materials. The cross-linking and ceramization of the AHPCS/Cp₂TiCl₂ hybrid precursors were characterized by means of FT IR, NMR, TGA and EDS. The results indicate that the cross-linking of hybrid precursors was significantly catalyzed by using Cp₂TiCl₂ as a catalyst, which might be responsible for a high ceramic yield of 80.8% at 1200 °C. The polymer-to-ceramic conversion was completed at 900 °C to give an amorphous ceramic. The chemical composition of the final ceramics could be tailored by the weight ratio of Cp₂TiCl₂ to AHPCS in feed. The microstructure and dielectric properties of final SiCTi ceramics were investigated by means of XRD, Raman spectroscopy and vector network analyzer. The results indicate that the 1600 °C SiCTi ceramics are composed of amorphous SiCTi, SiC crystal, TiC crystal and graphite. The dielectric loss of SiCTi is up to 0.34, which is 6 times higher than that of SiC (0.058), indicating that the SiCTi ceramics are promising wave-absorbing materials.     

A decision support system for locating weapon and radar positions in stationary point air defence

In this study, a decision support system (DSS) based on the interactive use of location models and geographical information systems (GIS) was developed to determine the optimal positions for air defence weapons and radars. In the location model, the fire units are considered as the facilities to be located and the possible approach routes of air vehicles are treated as demand points. Considering the probability that fire by the units will miss the targets, the objective of the problem is to determine the positions that provide coverage of the approach routes of the maximum number of weapons while considering the military principles regarding the tactical use and deployment of units. In comparison with the conventional method, the proposed methodology presents a more reliable, faster, and more efficient solution. On the other hand, owing to the DSS, a battery commander who is responsible for air defence becomes capable of determining the optimal weapon and radar positions, among the alternative ones he has identified, that cover the possible approach routes maximally. Additionally, he attains the capability of making such decisions in a very short time without going to the field over which he will perform the defence and hence without being subject to enemy threats. In the decision support system, the digital elevation model is analysed using Map Objects 2.0, the mathematical model is solved using LINGO 4.0 optimization software, and the user interface and data transfer are supported by Visual Basic 6.0.     

Fault detection and identification for a class of continuous piecewise affine systems with unknown subsystems and partitions

This paper establishes a novel online fault detection and identification strategy for a class of continuous piecewise affine (PWA) systems, namely, bimodal and trimodal PWA systems. The main contributions with respect to the state‐of‐the‐art are the recursive nature of the proposed scheme and the consideration of parametric uncertainties in both partitions and in subsystems parameters. In order to handle this situation, we recast the continuous PWA into its max‐form representation and we exploit the recursive Newton‐Gauss algorithm on a suitable cost function to derive the adaptive laws to estimate online the unknown subsystem parameters, the partitions, and the loss in control authority for the PWA model. The effectiveness of the proposed methodology is verified via simulations applied to the benchmark example of a wheeled mobile robot.     

Duane Michals' real dreams

Abstract

The roman-photo, a kitsch, devitalized genre, is at the opposite end of the spectrum to the more experimental, analytical genre of the photo narrative. While the former targets a huge popular audience -like pop music or commercial cinema- the latter is intended for a select circle of intellectuals interested in fringe movements and the creative impact of mass-market publications on art. On the one hand, there is the roman-photo, a medium for outmoded mythology, trapped within a fixed framework and, on the other, there is the slick, self-referential experimental photo narrative, which systematically explores the genre's specificity and encourages the reader to play an active role in the formulation of meaning. Bringing about a genuine renewal of the photo story, however, is by no means an easy task: merely throwing oneself into a scholarly critique of the genre could lead to a dead end, while a continually ironic treatment, serving as a reference to the forms adopted by the romance photo story,¹ represents an inherently flirtatious approach as opposed to a serious attempt to create a new future for the genre.²