Towards an effective integration of cellular users to the structured Peer-to-Peer network

Integration of cellular users into the peer-to-peer (P2P) network is still in limbo due to limitations caused by heterogeneity, mobility and time-varying capacities of the wireless channel. If traditional Chord is employed to include users from the cellular networks, users under the same base station scatter in logical topology randomly. In this paper, we present a novel cellular Chord (C-Chord) P2P system that integrates the cellular users into the well-established structured P2P network in a topology-aware fashion. C-Chord offers the cellular users a choice of downloading contents either from the Internet peers at a faster rate or from other cellular users from the same base station avoiding the Internet data penalty. We also incorporate the peer selection module based on stable marriage problem that chooses the appropriate candidate from the discovered potential senders. We conduct extensive simulations to evaluate the performance of the proposed C-Chord P2P system and the peer selection module. Simulation results show that the path-length per lookup query is smaller than that of the traditional Chord system. Overhead due to renewal of routing information is also smaller for the cellular users in the C-Chord system. We also measure the throughput at the cellular receivers to analyze the effects of selecting peers either from same base station or from outside the Internet gateway. Throughput also increases dramatically due to an intelligent selection of peers among the potential senders.     

Polyaniline‐supported acid catalyst: Esterification of cinnamic acid with alcohols

Polyaniline‐supported acid salts such as polyaniline‐hydrochloride, polyaniline‐sulfate, and polyaniline‐nitrate were prepared by oxidation of aniline using benzoyl peroxide and ammonium persulfate as oxidizing agents. Polyaniline salts were used as catalysts in the esterification of cinnamic acid with alcohols. Polyaniline‐sulfate salt was found to be the best catalyst for the esterification of cinnamic acid. The reusability, handling, and recovery of the catalyst were found to be good. The yield of the ester depended on the type of the polyaniline salt, amount of the catalyst, amount of alcohol, and both the time and the temperature of the reaction. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1584–1590, 2005     

Production and properties of crude enterotoxin of Pseudomonas aeruginosa

Pseudomonas aeruginosa CTM-3 was found to be the most potentially enteroxigenic strain out of the 12 isolates recovered from milk, as a high fluid length ratio, i.e. F/L (1.1) in rabbit gut and a strong permeability response in rabbit skin (38.5 mm² necrotic zone) was obtained with this culture. No clear-cut relationship between the two tests was observed. Six of the ethidium bromide (300 μg/ml) cured variants of this culture completely lost their ability to produce enterotoxin indicating the possible involvement of a plasmid in enterotoxin synthesis. The crude enterotoxin from P. aeruginosa CTM-3 was completely inactivated in 15 s at 72°C. However, it was fairly stable at pH values in the range 4.5–7.5. Both pepsin and trypsin inactivated the enterotoxin activity at a concentration of 40 μg/ml. Organic acids, formalin and hydrogen peroxide had no significant effect on the enterotoxin activity. The need for further investigations with purified preparations is emphasized.     

The effect of mischmetal addition on the structure and mechanical properties of a cast Al-7Si-0.3Mg alloy containing excess iron (up to 0.6 Pct)

The effect of Fe content (0.2 to 0.6 pct) on the microstructure and mechanical properties of a cast Al-7Si-0.3Mg (LM 25/356) alloy has been investigated. Further, 1 pct mischmetal (MM) additions (a mixture of rare-earth (RE) elements) were made to these alloys, and their mechanical properties at room and at elevated temperatures (up to 200 °C) were evaluated. A structure-property correlation on this alloy was attempted using optical microstructure analysis, fractographs, X-ray diffraction, energy-dispersive analysis of X-rays (EDX), and quantitative metallography by image analysis. An increase in Fe content increased the volume percentage of Fe-bearing intermetallic compounds (β and π phases), contributing to the loweryield strength (YS), ultimate tensile strength (UTS), percentage elongation, and higher hardness. An addition of 1 pct MM to the alloys containing 0.2 and 0.6 pct Fe was found to refine the microstructure; modify the eutectic silicon and La, Ce, and Nd present in the MM; form different intermetallic compounds with Al, Si, Fe, and Mg; and improve the mechanical properties of the alloys both at room and elevated temperatures.     

Extraction of fission palladium by Aliquat 336 and electrochemical studies on direct recovery from ionic liquid phase

The wide electrochemical window and ion exchange properties of a room-temperature ionic liquid (RTIL) have been exploited for the extraction of palladium from nitric acid medium into ionic liquid phase — followed by direct electrodeposition of the metal from the organic phase. Extraction of palladium by commercial Aliquat 336 ionic liquids, tri-n-octylmethylammonium chloride (TOMAC) and tri-n-octylmethylammonium nitrate (TOMAN), was studied as a function of [HNO₃], [NO₃⁻] and [TOMAN]. The distribution ratio (D_Pd(II)) of palladium in TOMAN increased with an increase in the concentration of nitric acid and passed through a maximum at 1.0 M nitric acid. In contrast, the D_Pd(II) value of palladium in TOMAC decreased continuously with an increase in the concentration of nitric acid. Substantial amounts of water and nitric acid were also co-extracted into the organic phase with palladium.     

A new open-framework zinc arsenate [C4N3H16]2[Zn5(AsO4)4(HAsO4)2]

A three-dimensional zinc arsenate with an interrupted zeolitic framework (?IIO), [C₄N₃H₁₆]₂[Zn₅(AsO₄)₄(HAsO₄)₂], I has been synthesized solvothermally. The structure is built up from ZnO₄, AsO₄ and HAsO₄ tetrahedral units connected alternatively through their vertices forming the 3-D structure possessing one-dimensional channels bound by 10 T-atoms (T = Zn, As). The framework density of the structure is 10.4 T-atoms which indicates considerable openness in its structure.     

Improved authentication and computation of medical data transmission in the secure IoT using hyperelliptic curve cryptography

The Journal of Supercomputing - Data transmission is a great challenge in any network environment. However, medical data collected from IoT devices need to be transmitted at high speed to ensure...     

Novel genetic algorithm for short-term scheduling of sequence dependent changeovers in multiproduct polymer plants

Polymer plants generally operate to produce different grades of product from the same reactor. Such systems commonly require short-term scheduling to meet market demand. One important requirement in continuous-time scheduling of such systems is to satisfy a variety of constraints, including identifying feasible sequences of the predecessor and successor jobs to effectively handle changeovers. In this study, a new genetic algorithm (GA) is proposed to solve such job sequencing problems. The proposed GA uses real-coded chromosome to represent job orders and their sequences in the schedule. The novelty is that the representation ensures that all constraints are satisfied a priori, except the sequence constraint which is handled by penalizing violations. Three important problems relevant to polymer industry are solved to obtain optimal schedules. The first deals with the sequencing constraint between individual product orders, the second with sequencing constraint between groups of product orders, while the third incorporates batching with scheduling.     

Graph theory augmented math programming approach to identify minimal reaction sets in metabolic networks

Bioprocesses are of growing importance as an avenue to produce chemicals. Microorganisms containing only desired catalytic and replication capabilities in their metabolic pathways are expected to offer efficient processes for chemical production. Realizing such minimal cells is the holy grail of metabolic engineering. In this paper, we propose a new method that combines graph-theoretic approaches with mixed-integer liner programming (MILP) to design metabolic networks with minimal reactions. Existing MILP based computational approaches are computationally complex especially for large networks. The proposed graph-theoretic approach offers an efficient divide-and-conquer strategy using the MILP formulation on sub-networks rather than considering the whole network monolithically. In addition to the resulting improvement in computational complexity, the proposed method also aids in identifying the key reactions to be knocked-out in order to achieve the minimal cell. The efficacy of the proposed approach is demonstrated using three case studies from two organisms, Escherichia coli and Saccharomyces cerevisiae.