Variations of iridoid oleuropein in Italian olive varieties during growth and maturation

This research paper reports on the concentrations of oleuropein in fruits of seven Italian olive cultivars. These oleuropein levels, during fruit growth and maturation, were monitored by taking olive samples from the same olive trees grown in Middle Italy. A novel high‐resolution gas chromatography (HRGC) oleuropein quantification method and a new high‐performance liquid chromatography (HPLC) method were developed. The olive fruits showed high contents of oleuropein, which were greatly influenced by the olive cultivar (genetic store) factor. The stage of fruit growth and maturation was another factor strongly affecting the contents of iridoid oleuropein in olive drupes, whatever the olive cultivar considered. Green olives had much higher concentrations of this biofunctional glucoside, which decreased regularly during fruit growth and ripeness. No differences were observed between the two developed oleuropein quantification methods, which gave, for all the olive cultivars, average values of fruit oleuropein contents that were not statistically different. These two reliable repetitive methods, noticeably the HPLC one (which also showed a lower running time), could be used for routine determination of oleuropein in olive drupes. We observed that, in general, olive cultivars having high oleuropein concentrations in the fruits were also characterized by marked oleuropein contents in the leaves.     

HS-SPME coupled to GC/MS for quality control of Juniperus communis L. berries used for gin aromatization

HS-SPME coupled to GC/MS was applied to the analysis of the volatile fraction of Juniperus communis L. berries, which are the principal ingredient used for gin aromatization. Seventy seven compounds were identified by comparison with reference compounds or tentatively identified by comparing their mass spectra and retention index with those reported in mass spectra libraries and literature, respectively. Seventy four were detected by SPME and sixty eight were detected by solvent distillation extraction (SDE). These were mainly mono- and sesquiterpenic compounds that represented more than the 80% of the gin’s volatile composition. A high percent content was due to monoterpenoids, whose analysis could be important for the assessment of sensory quality control of juniper due to their impact on gin aroma. The main monoterpenoids detected in the headspace of the juniper berries from two periods of collection were terpinen-4-ol, p-cymene, β-myrcene, γ-terpinene, α-pinene and limonene. These represented more than the 70% of the sample’s volatile fraction. The proposed SPME method required short times and the low cost of analysis and enabled to detect a number of compounds comparable with SDE or much higher than the number of compounds reported by other extraction techniques. The results suggested the suitability of this technique for the assessment of the volatile composition of juniper berries intended for gin flavouring.     

Lithiated short side chain perfluorinated sulfonic ionomeric membranes: Water content and conductivity

In view of possible applications as single-ion electrolyte for lithium batteries, some aspects of the lithium form of Hyflon Ion ionomer, a sulfonic short side chain (SSC) electrolyte, have been investigated. The synthesis of the ionomer and the successive membrane preparation is reported. An appropriate methodology for the direct salification of the ionomeric membrane from the SO₂F form to lithium salt, using lithium hydroxide in absence of organic solvent has been found. Utilizing these SSC lithium ionomer membranes and though a particular methodology for the dehydration of the lithium ion membrane in non-aqueous media, it has been possible to achieve an ionic conductivity of 10⁻³ S cm⁻¹ at room temperature [W. Navarrini, S. Panero, B. Scrosati, A. Sanguineti, European Patent 1,403,958 A1 (2003)]. Surprisingly it was observed that the membrane ionic conductivity depends on the dehydration methodologies adopted.     

Proton-conducting membranes based on protic ionic liquids

New classes of proton-conducting membranes formed by incorporating Brönsted acid–base ionic liquids in a poly(vinyldenefluoride-co-hexafluoropropylene) PVdF polymer matrix, are here reported and discussed. We show that these membranes are characterized by high, thermally stable proton conductivity. However, this favourable property is in part contrasted by the release of the ionic liquid component, which may affect the long-term stability of the membranes. Various strategies are underway in our laboratory to solve this issue, and in this work we describe one of them, based on the dispersion of selected ceramic fillers in the polymer matrix. We show that this approach, while successful in enhancing the conductivity of the membranes, is not much effective in preventing the release of the ionic liquid component and thus, that other roads have to be explored to reach a satisfactory improvement of the integrity of the membrane.     

A Comparative Study of Mechanical Properties,Thermal Conductivity,Residual Stresses,and Wear Resistance of Aluminum-Alumina Composites Obtained by Squeeze Casting and Powder Metallurgy

Squeeze casting and powder metallurgy techniques were employed to fabricate AlSi12/Al₂O₃ composites, which are lightweight structural materials with potential applications in the automotive industry. The impact of the processing route on the material properties was studied. Comparative analyses were conducted for the Vickers hardness, flexural strength, fracture toughness, thermal conductivity, thermal residual stresses, and frictional wear. Our results show that the squeeze cast composite exhibits superior properties to those obtained using powder metallurgy.

     

Correction to: A Comparative Study of Mechanical Properties,Thermal Conductivity,Residual Stresses,and Wear Resistance of Aluminum-Alumina Composites Obtained by Squeeze Casting and Powder Metallurgy

Metallurgical and Materials Transactions A -     

A theoretical analysis of a buffer frame size conversion algorithm for audio applications ensuring minimum latency

In implementing digital signal processing (DSP) algorithms for audio real-time applications, one is frequently faced with problems regarding incompatibilities between the hardware buffer length (the internal buffer of a professional sound card) and the software buffer size imposed by the underlying algorithm (due to i.e. multirate or FFT constraints). This mismatch is solved by proper frame size conversion algorithms which inevitably introduce delay. In this context, this paper presents a buffering scheme together with a theoretical proof of the minimum delay property shown by it. Some examples derived from frequently encountered issues in DSP applications are reported.     

Adsorption equilibria of benzodiazepines on a hybrid polymeric chiral stationary phase

The chromatographic behavior of a series of racemic benzodiazepines was evaluated under linear and nonlinear conditions on a new hybrid polymeric (DACH-ACR) chiral stationary phase (CSP). Differently substituted benzodiazepines were employed as probes to make hypotheses concerning possible molecular interaction mechanisms originating between target compounds and active sites on the CSP. Hydrogen bonds were found to be pivotal for chromatographic retention and chiral selectivity. The competitive effect from a mobile-phase (MP) modifier able to interact with the CSP through H-bonds was investigated. The performance of the polymeric DACH-ACR CSP for preparative purposes was also evaluated. The competitive adsorption isotherms of two benzodiazepines, lorazepam and temazepam, were measured at different MP compositions through the so-called inverse method. The adsorption data were fitted with a competitive bi-Langmuir adsorption isotherm. Enantiomeric separations under nonlinear conditions were modeled by using the equilibrium dispersive (ED) model of chromatography. Theoretical overloaded band profiles (obtained by solving the system of partial differential equations described by the ED model) matched, in a significantly accurate way, the profiles experimentally measured.     

Volatile and semi-volatile components of oak wood chips analysed by Accelerated Solvent Extraction (ASE) coupled to gas chromatography–mass spectrometry (GC–MS)

Volatile and semi-volatile compounds of French and American oak wood used in wine and spirits ageing were extracted by an Accelerated Solvent Extractor (ASE) and analysed by gas chromatography–mass spectrometry. More than 90 compounds were isolated, characterised and quantified after being separated on two chromatographic columns with distinct polarity. The main oak wood components were quantitatively determined by using standard reference compounds. In addition, a number of compounds, mainly guaiacol and syringol derivatives, were detected and characterised. In particular, 10 compounds were tentatively identified as lignin dimers derivatives, whose presence in oak wood chips or barrels for wine and spirits ageing had not been previously described. Several of the characterised compounds enabled a distinction to be drawn between medium and high toasted wood chips, independently of their geographical origin.