模糊技术的发展及在相关领域中的应用

本文介绍了模糊技术的发展和现状，以及在相关领域中的应用情况，并且讨论了模糊技术在我国的产业化方向等问题。     

Hybrid integrator backstepping control of robotic manipulators driven by brushless DC motors

In this paper, a hybrid integrator backstepping controller is proposed for robotic manipulators actuated with brushless DC motors in the presence of arbitrary uncertain inertia parameters of the manipulator and the electrical parameters of the actuators. The main features are: 1) the design, requiring at most the joint velocities and stator currents feedback; 2) the semiglobal asymptotic stability of the controller being established in the Lyapunov sense; and 3) suitability of the scheme for multijoint robots. Simulation results are included to demonstrate the tracking performance.     

Instability of diatomic deuterium in fcc palladium

To clarify some of the solid-state aspects of cold fusion in deuterated transition metal electrodes, we have carried out first-principles self-consistent total energy calculations for various configurations of atomic and diatomic deuterium inside fcc palladium. We find that the stability of the Pd+D system is controlled by the relative position of the deuterium-inducedantibonding level with respect to the Fermi energy. The equilibrium D-D distance in dense PdD up to =3 is found to be much larger than the free space value. The calculated Born-Oppenheimer energy surface of diatomic D₂ in crystalline palladiuim is shown to have but metastable local minima whose internuclear separation is at least 0.2 Ålarger than that of the isolated D₂ molecule. We conclude that D₂ incrystalline Pd will have a substantially lower tunneling probability than hitherto thought and that explanation for fusion mechanisms should be sought elsewhere.     

一种简便的饮用水除铀方法及其机理

本文介绍一种利用原水中含有的无机盐,加入廉价的化学试剂除去饮用水中微量铀的简便方法。并对其除铀机理进行了探讨,证明除铀主要是以软化水过程中产生的氢氧化镁表面吸附共沉淀机理进行的。     

铂铑包覆钼合金搅拌器的研制

介绍了铂铑包覆钼合金搅拌器的结构与技术要求,以及搅拌器的制作与使用效果。研制结果表明,国产搅拌器达到了日本同类产品的水平。     

浅谈化工建设项目竣工预验收程序和内容

结合作者的实际工作 ,总结了对工程建设实施“三道质量控制工序”的经验 ,强调了过程质量控制的重要性 ,较为系统地介绍了化工建设项目预验收工作的程序和内容     

Phase behavior of ternary polymer blends

The effect of varying interaction parameters on the phase diagrams of ternary polymer blends was explored by simulating spinodals through use of the Flory-Huggins lattice theory. Results indicate that miscibility is favored for the case of ternary mixtures of marginally miscible or marginally immiscible pairs where all pair interactions are nearly athermal. Miscibility is restricted for asymmetric ternary blends when one of the polymer pairs is either strongly miscible or strongly immiscible. For symmetric blends of partially immiscible pairs, both two-phase and three-phase miscibility gaps are predicted.     

通过细乳液聚合方法制备自交联型有机硅乳液

苯乙烯与甲基丙烯酸-3-三甲氧基硅丙酯(M PS)经细乳液聚合,制得了稳定的自交联型的水分散涂料,用透射电子显微镜(TEM)、动态光散射仪(DLS)和红外光谱(IR)表征了乳胶粒的形态和结构。发现与传统乳液聚合相比,细乳液聚合法可显著提高乳液的稳定性,且M PS加入量的增加会导致乳液稳定性降低。     

A spectroscopic study of the self-association and inter-molecular aggregation behaviour of pH-responsive poly(l-lysine iso-phthalamide)

The pH mediated intra-molecular association and inter-molecular aggregation of a range of amphiphilic poly(l-lysine iso-phthalamide) polymers have been investigated in aqueous solution over a range of pH values and concentrations. The desired functionality of these novel bioresponsive amphiphilic polymers was achieved by incorporating pendant hydrophilic carboxyl groups along the polymer backbone, via the l-lysine moiety, balanced by a degree of hydrophobicity introduced via the iso-phthaloyl moiety. Incorporation of low levels of bis-functional Cy3 (poly-Cy3) and/or Cy5 dye (poly-Cy3/5 or poly-Cy5) co-monomers in the responsive polymer backbone allowed detailed probing of the pH mediated hydrophobic association using a combination of optical spectroscopic techniques. Both steady-state fluorescence spectroscopy and fluorescence lifetime measurements of poly-Cy3 revealed a conformational transition at pH 4.5. Thus, below a critical pH the polymer collapsed into a compact globular structure (hypercoil) bringing the fluorophore molecules into close proximity with one another. This resulted in a dramatic reduction in fluorescence intensity and fluorescent lifetime in the single fluorophore systems (poly-Cy3) accompanied by a red shift in the maximum emission wavelength. Observed redshifts in the emission maxima and enhancements of fluorescent lifetimes with increasing polymer concentration suggested the formation of polymer aggregates. Fluorescence resonance energy transfer (FRET) was measured in mixtures of single fluorophore containing poly-Cy3 (donor) and poly-Cy5 (acceptor) and dual fluorophore containing poly-Cy3 (donor)/Cy5 (acceptor) in an effort to distinguish between intra-molecular versus inter-molecular association. The relevance of the results with respect to potential in vivo applications (drug delivery and biodiagnostics) is discussed.     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.