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941.
Gang Yao William Yi Wang Chengxiong Zou Ke Ren Peixuan Li Xingyu Gao Deye Lin Jun Wang Shufeng Yang Yiguang Wang Haifeng Song Jinshan Li 《Journal of the American Ceramic Society》2022,105(6):4260-4276
High-entropy carbides (HECs) are regarded as potential candidate structural materials with attractive mechanical properties due to their ultra-high hardness. It is essential to reveal the atomic and electronic basis for strengthening mechanism in order to develop the advanced HECs. In the present work, C (M = Nb, Ti, V) are selected as case studies. The effects of transition metals (M) on the lattice parameters, bulk modulus, enthalpy of formation, electron work function (EWF), and bonding morphology/strength of HECs are comprehensively studied by first-principles calculations. It is found that the lattice parameters, equilibrium volumes, and bulk modulus of HECs are improved with the increase of M atomic volumes. The atomic-size differences among various groups of elements not only result in the lattice mismatch/distortion but also contribute to the formation of weak spots. In the view of bonding charge density, the electron redistributions caused by the coupling effect of the lattice distortion and valance electron differences can be revealed obviously, which identify the different bonding strength. Moreover, in terms of EWF, the proposed power-law-scaled hardness of HECs is validated and matches well with those reported theoretical and experimental results, providing a strategy to design advanced HECs with excellent mechanical properties. 相似文献
942.
943.
Summary
Novel sulfonated poly(arylene ether ketone)s were prepared directly by aromatic nucleophilic polycondensation of 4,4'-sulfonyldiphenol
with various ratios of 4,4'-difluorobenzophenone to 5,5'-carbonylbis(2-fluorobenzenesulfonate) in dimethyl sulfoxide. The
resulting polyelectrolytes were characterized by IR, NMR, TGA and DSC. The 10% weight loss temperature of the products is
higher than 510°C, and their glass transition temperature is above 260°C. The introduction of 4,4'-sulfonyldiphenol with powerful
electron-withdrawing group, -SO2−, into the main chain of sulfonated poly(arylene ether ketone)s improves the thermal stability against desulfonation. The
ion-exchange capacity and swelling of the polyelectrolyte membranes were measured, which are higher than 1.23meq/g and not
higher than 20.9%, respectively. The membranes show very good perspectives in polymer electrolyte fuel cell (PEMFC) application.
Received: 27 March 2002 / Revised version: 7 May 2002 / Accepted: 13 May 2002 相似文献
944.
The diffusion coefficient of a dye in fibres is critical to understanding the dyeing process and coloration quality of products. In this paper, the diffusion kinetics of solvent dyes in the thermosol dyeing of polyester fibres was studied by measuring K / S of the dyed polyester fabrics based on the Kubelka–Munk equation. The diffusion coefficients of two model solvent dyes were estimated with Hill's equation using the experimentally measured K / S values and were found to be in good agreement with those calculated from the traditional extraction method. Such a measurement method was applied to several other solvent dyes and pigments that have different molecular sizes and a good correlation between the measured diffusion coefficients and sizes of these dyes and pigments was found. The results indicate that it is feasible to use K / S measurement of dyed fabrics and Hill's equation to evaluate the kinetics of the thermosol dyeing process under certain conditions. 相似文献
945.
946.
采用循环伏安法和恒电流法研究了铁电极在氰化物电解液中的行为,证实了在阴极过程中电极首先极化至铁表面钝态层的还原,实现了表面的活化;随后极化至金属在活化的铁基体上的电沉积过程。 相似文献
947.
研究了钛酸酯类偶联剂和硅烷类偶联剂对钙矿、硅酸盐填充的PVC填允材料力学性能、相态结构、密度、热失重率及吸水伸长率和耐热阻燃性能的影响。结果表明,偶联剂可改善填充PVC的抗冲性能,降低其拉伸强度,扫描电镜分析表明,填料越细,分散越均匀,越易被PVC树脂所包覆,力学性能越好,研究得到了比重大、热失重率低、吸水伸长率小、阻燃耐烧灼性好的高填充PVC硬质塑料地板砖。 相似文献
948.
Benzene alkylation with propane has been studied over HZSM-5 loading 3.1–15.4 wt% Mo in continuous-flow microreactor under
350 °C and atmospheric pressure with the highest activity obtained at 6.7 wt% Mo loading. C7–9 aromatics were obtained as main products while the total amount of benzene rings kept unchanged. i-Propylbenzene and n-propylbenzene are formed primarily, while toluene, ethylbenzene, and ethyl-toluene are formed secondly from the propylbenzenes.
Catalytic performance of 6.7 wt% Mo/HZSM-5(38) partially poisoned by NH3 shows that the strong acid sites play a crucial role in the alkylation. Low SiO2/Al2O3 ratio of HZSM-5 in the Mo modified catalysts gives high propane conversion. Two hydrothermal treatment methods were applied
to the 6.7 wt% Mo/HZSM-5(38) catalyst, caused decrease of propane conversion but result in different product distribution.
A possible reaction mechanism concerning bifunctional active centers resulted from combination of loaded Mo species and strong
acid centers on HZSM-5 is proposed. 相似文献
949.
Ziqi Sun Yanchun Zhou Jingyang Wang Meishuan Li 《Journal of the American Ceramic Society》2007,90(8):2535-2541
In this paper, the mechanical properties of bulk single-phase γ-Y2 Si2 O7 ceramic are reported. γ-Y2 Si2 O7 exhibits low shear modulus, excellent damage tolerance, and thus has a good machinability ready for metal working tools. To understand the underlying mechanism of machinability, drilling test, Hertzian contact test, and density functional theory (DFT) calculation are employed. Hertzian contact test demonstrates that γ-Y2 Si2 O7 is a "quasi-plastic" ceramic and the intrinsically weak interfaces contribute to its machinability. Crystal structure characteristics and DFT calculations of γ-Y2 Si2 O7 suggest that some weakly bonded planes, which involve Y–O bonds that can be easily broken, are the sources of the low shear deformation resistance and good machinability. 相似文献
950.
硫磺制酸的发展与硫铁矿制酸的发展有所不同,没有象大型硫铁矿制酸通过引进国外的先进技术而发展起来的,而是通过消化吸收引进的硫铁矿制酸技术或设备,完全依靠自己的能力发展起来的。我国硫磺制酸起步晚,但发展十分迅速。装置的大型化是从上世纪90年代中期开始发展的,装置规模从200kt/a、300kt/a起,逐步积累经验,直到800kt/a的建设。随着硫酸生产新技术、新装备的不断开发、应用,我国大型硫磺制酸装置的设计、施工、管理正日趋成熟。 相似文献