过磷酸钙含氟尾气处理的新方法

对动态泡沫床处理过磷酸钙含氟尾气的有关技术及费用作了说明 ,指出该方法费用高 ;提出一种新方法 ,该方法不加任何化学助剂 ,采用水作吸收剂 ,只需改变动态泡沫床一些设计参数和选用一种特殊的喷头 (喷头周围设计 1个圆锥形死角区 ,使含氟气体不可能进入该区 )避免了硅胶堵塞。该方法已在湖南浦市化工总厂运行 1年多未发现堵塞 ,同时该法投资少、能耗低、排放尾气达标     

石蜡聚苯乙烯微球的制备

通过悬浮聚合技术合成了石蜡聚苯乙烯微球，研究了合成过程中引发剂浓度及交联剂用量对微球粒径及其分布的影响。     

Catalytic activities and properties of mesoporous sulfated Al2O3–ZrO2

Mesoporous sulfated Al₂O₃–ZrO₂ (MSAZ) catalysts with large surface areas and pore volumes after calcination at high temperature (650 °C) and with higher Al₂O₃ content than 20wt% were successfully prepared from a template of block copolymer (P84). The MSAZ catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption, transmission electron microscopy (TEM), ²⁷Al magic-angle spinning nuclear magnetic resonance (MAS NMR), thermogravimetric analysis (TG–DTG), temperature-programmed desorption of ammonia (NH₃-TPD) and infrared spectra (IR) of adsorbed pyridine. It is shown that the resulting mesostructured sulfated Al₂O₃–ZrO₂ samples have a well-developed textural mesoporosity. The number of acid sites present on MSAZ catalysts is higher than that on conventional sulfated zirconia, and the former catalysts are more active than the latter one for various acid-catalyzed reactions.     

半刚性钢-混凝土组合节点受弯承载力的计算

在半刚性钢 -混凝土组合框架中 ,混凝土板中的纵向钢筋增加了节点的强度和刚度 ,但是 ,传统的设计方法往往忽略纵向钢筋的作用而采用简化的计算模型。因此 ,出于经济效益考虑 ,应该根据半刚性组合节点的实际受力性能建立更加准确的计算方法。这里详细介绍了考虑混凝土板纵向钢筋作用的半刚性组合节点受弯承载力的计算方法 ,计算结果表明 ,建议的公式与试验结果吻合良好 ,可供规范制定和工程应用参考。     

Effect of particle size on the surface oxidation and flotation behavior of galena particles in lime system

ABSTRACT

In this research, the effect of particle size on the surface oxidation and flotation behavior of galena in the lime system was studied. Coarse (?0.074 + 0.038 mm), intermediate (?0.038 + 0.025 mm) and fine (?0.025 mm) galena particles were used in the experiment. The dissolution tests, flotation tests, and sorption tests were accomplished. Through further analysis by XPS, the effect of particle size and lime was observed. The decrease of mineral particle sizes increased the adsorption ratio of collector and the dissolution of galena, while the hydrophilic product OH^?/Ca(OH)⁺ produced by dissolution occupied the dominant position, which led to the minerals hydrophilic.     

微波谐振腔模式数的程序求解法

微波谐振腔在无线通信领域应用广泛。在简要微波谐振腔的基础上,给出了用程序求解谐振模式数的方法,并利用C++实现了对给定尺寸矩形谐振腔模式数的求解。     

Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

X-Ray, Micro-Raman, Optical Absorption/Emission Studies of ErNbO4 Grown by Vapor Transport Equilibration

Vapor transport equilibration (VTE) treatments were performed on a Y-cut bulk Er (1.6 mol%)-doped congruent LiNbO₃ crystal and an X-cut pure congruent crystal, on one surface of which a 40 nm-thick film of erbium metal was coated before the VTE treatment. Scanning electron microscope, powder or single-crystal X-ray diffraction (XRD), polarized infrared absorption/emission of Er³⁺ as well as micro-Raman spectroscopy were used to study the two VTE crystals. The results are discussed in comparison with a corresponding as-grown bulk Er-doped crystal, calcined ErNbO₄ powder, and a locally Er-doped congruent LiNbO₃ crystal prepared by using the standard Er-diffusion technique. The experimental results show that the VTE treatment induces the formation of micrometer-sized ErNbO₄ precipitates with the crystallographic morphology of a flat polyhedron not only on the surfaces of both crystals but also in the bulk of the homogeneously Er-doped one. The optical absorption and emission studies show that the formation of the precipitates results in substantial spectral changes in both the 0.98 and 1.5 μm regions. The micro-Raman studies allow to resolve four additional Raman peaks around 800 cm⁻¹ in the E(TO) spectra of the two VTE crystals. These additional Raman peaks are associated with the characteristic vibrations with respect to the NbO₄³⁻ group. Characteristic XRD, optical absorption, and emission and Raman peaks for identifying the ErNbO₄ phase are proposed. Finally, the formation mechanism and light-scattering effect of the precipitates are discussed.     

国产软硬件环境下图像组织浏览构件设计

针对在国产软硬件环境下,应用系统读取、浏览大量图像数据的速度慢问题,设计了图像组织浏览构件。通过改进图像组织方式,将基础影像和目标对象图像分开组织管理,并对目标对象图像的属性和分层、分类进行探讨,实现图像信息的快速展现。对图像组织浏览构件进行了插件化设计与实现,利用QT跨平台开发工具,实现了应用集成框架,并通过实现统一集成接口,进行各业务插件的集成。     

Morphologies-Controlled Synthesis and Optical Properties of Bismuth Tungstate Nanocrystals by a Low-Temperature Molten Salt Method

Well-crystallized bismuth tungstate (Bi₂WO₆) powders with different morphologies were successfully synthesized via a low-temperature molten salt method. The powders were characterized by X-ray diffraction, transmission electron microscopy, and UV-Vis, respectively. It was found that the variation of morphology of the obtained Bi₂WO₆ powder mainly depends on the different reaction temperatures and the weight ratio of LiNO₃–NaNO₃ salt to precursor. In addition, the UV-Visible absorption spectra showed that the synthesized powders had strong light absorption properties not only in the ultraviolet light but also in the visible light region.