Selective separation of hydroxide from alkaline nuclear tank waste by liquid-liquid extraction with weak hydroxy acids

Recovery and recycle of caustic reagents in industrial processes offer potential means of pollution prevention, as investigated herein for particular needs related to the cleanup of alkaline nuclear waste. Specifically, the recovery of hydroxide from alkaline media by liquid-liquid extraction can be effected utilizing weak hydroxy acids, as demonstrated for NaOH utilizing a series of lipophilic fluorinated alcohols and alkylated phenols dissolved in 1-octanol. Extraction efficiency follows the expected order of acidity of the hydroxy acids, the phenols being the most efficient extractants among the compounds tested. After extraction, NaOH is effectively recoverable from the organic phase upon contact with water. The weakest hydroxy acids are the most efficiently stripped, NaOH recovery being nearly quantitative in a single contact. In competitive extraction experiments, good selectivity for hydroxide recovery over other anions such as nitrate and chloride was demonstrated. Since the order of extraction favors larger anions, the exceptional preference for hydroxide implies that the extraction occurs by deprotonation of the hydroxy acids in a cation-exchange process. Stripping therefore occurs by hydrolysis to regenerate the neutral hydroxy acid, liberating NaOH to the aqueous phase. Since hydroxide equivalents rather than actual hydroxide ions are transferred to the solvent, the process is termed "pseudohydroxide extraction." Hydroxide recovery from a simulant of alkaline nuclear tank waste (Hanford DSSF simulant) was also demonstrated in repeated extraction and stripping cycles.     

Physicochemical Investigation of the Reaction of Components of the Si — Al — O — N — Ti System in the Si3N4 — Al2O3 — AlN — SiO2 — TiN — TiO2 Region. Part 2. Subsystems Si3N4 — AlN,TiN — AlN,Al2O3 — AlN

The reaction of components of the Si — Al — O — N — Ti system in its elements Si ₃N₄ — AlN, TiN — AlN, and Al ₂O ₃ — AlN was investigated by differential thermal and x-ray diffraction analysis. It was established that upon hot pressing mixtures of Si₃N ₄ and AlN (up to 1950°C) free silicon is formed by the decomposition of Si ₃N₄, which reacts with oxygen present as an impurity to form SiO. When TiN reacts with AlN a phase with the spinel structure (Al₂₃O ₂₇N ₅), which can form only in the presence of excess oxygen, appears in addition to the initial components. Spinel is also produced by the reaction of Al ₂O₃ with AlN. In this case a eutectic between Al ₂₃O₂₇N₅ and Al₂O₃ is observed.     

Linking learning goals and educational resources through interactive concept map visualizations

Concept browsing interfaces can help educators and learners to locate and use learning resources that are aligned with recognized learning goals. The Strand Map Service enables users to navigate interactive visualizations of related learning goals and to request digital library resources aligned with learning goals. These interfaces are created using a programmatic Web service interface that dynamically generates interactive visual components. Preliminary findings suggest that these library interfaces appear to help users stay focused on the scientific content of their information discovery task, as opposed to focusing on the mechanics of searching.     

Multimedia displays for conceptual discovery: information seeking with strand maps

This article explores the use of a multimedia search interface for digital libraries based on strand maps developed by the American Association for the Advancement of Science. As semantic-spatial displays, strand maps provide a visual organization of relevant conceptual information that may promote the use of science content during digital library use. A study was conducted to compare users' cognitive processes during information seeking tasks when using a multimedia strand maps interface, versus the textual search interface currently implemented in the Digital Library for Earth System Education. Quantitative and qualitative data from think-aloud protocols revealed that students were more likely to engage with science content (e.g., analyzing the relevance of science concepts with regard to task needs) during search when using the strand maps interface compared to those using textual searching. In contrast, students using a textual search interface engaged more frequently with surface-level information (e.g., the type of a resource regardless of its science content) during search and retrieval. As a multimedia search interface for digital libraries, strand maps appear to be promising tools to promote conceptual discovery and learning through content-based processes that promote learner engagement with relevant science knowledge.     

Using informal notes for sharing corporate technology know-how

Corporate and academic communities have focused a great deal of attention on formalized approaches for creating, capturing, and propagating knowledge. Far less attention has been paid to the informal mechanisms that individuals share and employ to help them navigate complex processes in order to ‘get things done.’ In this paper, we examine the creation, use, and content of informal documents for supporting users of an enterprise resource planning system in a Fortune 500 company. We contend that such notes, which are commonly used for supporting information systems-related work, are an overlooked source of knowledgeability about organizational practices. This study is a first but necessary step in analyzing the types of information that can be derived from informal notes so that organizations can more fully utilize this largely untapped resource.     

Comparative psychometric analysis of vector and isochrone cardiac activation maps

Isochronal cardiac activation maps can be constructed from local activation times associated with spatial locations, and are frequently used to study cardiac arrhythmias. Cardiac velocity vector mapping has been proposed as an alternative method to study cardiac activation in both clinical and research environments. Velocity vectors inherently contain more information than scalar measures of latency, but it is unknown how vector maps and isochronal maps compare when they are used to identify patterns and features associated with arrhythmias. In order to quantitatively compare these two visualization methods, eight cardiologists were asked to complete forced-choice tasks in which they selected ablation sites based on synthetic vector or isochronal maps. Maps varied in arrhythmia complexity, number of vectors or activation times included, and errors in magnitude or angle for maps of velocity vectors. Quantitative comparison was achieved by using psychometric functions to characterize the learning curve and the total number of measurements needed in order to choose a correct ablation site. For simple arrhythmias, performance with vector maps was superior to isochronal maps. Subjects required fewer measurements, and learned more rapidly by studying vector maps. For more complex arrhythmias, there was no significant difference in performance between vector and isochronal maps. However, arrhythmia features were clearer with vector maps, even though this clarity did not necessarily change the ablation site choice. When errors were added to vector maps, performance was satisfactory for angle errors < 55 degrees, and speed errors did not affect performance.     

Molecular modeling of sigma 1 receptor ligands: a model of binding conformational and electrostatic considerations

We have performed molecular modeling studies on several sigma 1 specific ligands, including PD144418, spipethiane, haloperidol, pentazocine, and others to develop a pharmacophore for sigma 1 receptor-ligand binding, under the assumption that all the compounds interact at the same receptor binding site. The modeling studies have investigated the conformational and electrostatic properties of the ligands. Superposition of active molecules gave the coordinates of the hypothetical 5-point sigma 1 pharmacophore, as follows: R1 (0.85, 7.26, 0.30); R2 (5.47, 2.40, -1.51); R3 (-2.57, 4.82, -7.10); N (-0.71, 3.29, -6.40); carbon centroid (3.16, 4.83, -0.60), where R1, R2 were constructed onto the aromatic ring of each compound to represent hydrophobic interactions with the receptor; and R3 represents a hydrogen bond between the nitrogen atom and the receptor. Additional analyses were used to describe secondary binding sites to electronegative groups such as oxygen or sulfur atom. Those coordinates are (2.34, 5.08, -4.18). The model was verified by fitting other sigma 1 receptor ligands. This model may be used to search conformational databases for other possibly active ligands. In conjunction with rational drug design techniques the model may be useful in design and synthesis of novel sigma 1 ligands of high selectivity and potency. Calculations were performed using Sybyl 6.5.     

Environmental and human factors influencing thermal comfort of office occupants in hot - humid and hot - arid climates

The effects of environmental and individual factors on thermal sensation in air-conditioned office environments were analysed for two large, fully compatible thermal comfort field studies in contrasting Australian climates. In the hot - humid location of Townsville, 836 office workers were surveyed; 935 workers participated in hot - arid Kalgoorlie-Boulder. Overall perceived work area temperature and measured indoor operative temperature correlated moderately with thermal sensation for Townsville (T) subjects but only perceived temperature correlated with Kalgoorlie-Boulder (KB) sensation. Multiple regression analyses confirmed that indoor climatic variables (including Predicted Mean Vote) contributed to actual thermal sensation vote (24% T; 15% KB), with operative temperature having more of an effect in T than in KB. Subsequent analyses of individual characteristics showed no linear contributions to thermal sensation. The remaining variances were significantly related to perceived work area temperature (7% additional explained variance in T; 12% in KB). Mann - Whitney analyses (after correction for climatic variables) showed that T subjects with higher job satisfaction had thermal sensations closer to 'neutral'. Males, healthier subjects, non-smokers, respondents with earlier survey times and underweight occupants had lower median thermal sensations in KB. Townsville occupants appeared more adapted to their outdoor climatic conditions than Kalgoorlie-Boulder respondents, perhaps due to limited home air-conditioning. Further research into non-thermal impacts on gender-related thermal acceptability is suggested.     

Authoritative parenting and college students' academic adjustment and success.

This study examined connections between college students' adjustment and success and characteristics of their relationships with their parents. A sample of 236 students completed the Student Attitudes and Perceptions Survey, a 135-item anonymous self-report instrument. Students' grades, confidence level, persistence, task involvement, and rapport with their teachers were generally predicted by both current and childhood levels of parental autonomy granting, demandingness, and supportiveness. Ratings of parenting characteristics were equally predictive of adjustment and success among students living with their parents and those living on their own. They were somewhat less predictive of seniors' adjustment and success than they were for freshmen, sophomores, and juniors. These findings suggest that parenting style continues to play an important role in the academic lives of college students. (PsycINFO Database Record (c) 2010 APA, all rights reserved)