The Effect of van der Waals and Viscous Forces on Aerosol Coagulation

An analysis is carried out to determine the combined effect of van der Waals and viscous fluid forces on coagulation of spherical aerosol particles in the free molecular, transition, and continuum regimes. The effect of viscous forces is taken into account by modifying the particle diffusion coefficient. An asymptotic solution is substituted for the classical formulation of viscous forces. The results of free molecular and continuum regimes are then extended to the transition size range by an interpolation formula.     

Designing feedforward command shapers with multi-objective genetic optimisation for vibration control of a single-link flexible manipulator

This paper presents investigations into the design of a command-shaping technique using multi-objective genetic optimisation process for vibration control of a single-link flexible manipulator. Conventional design of a command shaper requires a priori knowledge of natural frequencies and associated damping ratios of the system, which may not be available for complex flexible systems. Moreover, command shaping in principle causes delay in system's response while it reduces system vibration and in this manner the amount of vibration reduction and the rise time conflict one another. Furthermore, system performance objectives, such as, reduced overshoot, rise time, settling time, and end-point vibration are found in conflict with one another due to the construction and mode of operation of a flexible manipulator. Conventional methods can hardly provide a solution, for a designer-oriented formulation, satisfying several objectives and associated goals as demanded by a practical application due to the competing nature of those objectives. In such cases, multi-objective optimisation can provide a wide range of solutions, which trade-off these conflicting objectives so as to satisfy associated goals. A multi-modal command shaper consists of impulses of different amplitudes at different time locations, which are convolved with one another and then with the desired reference and then used as reference (for closed loop) or applied to system (for open loop) with the view to reduce vibration of the system, mainly at dominant modes. Multi-objective optimisation technique is used to determine a set of solutions for the amplitudes and corresponding time locations of impulses of a multi-modal command shaper. The effectiveness of the proposed technique is assessed both in the time domain and the frequency domain. Moreover, a comparative assessment of the performance of the technique with the system response with unshaped bang–bang input is presented.     

Synthesis and nuclear magnetic resonance properties of all geometrical isomers of conjugated linoleic acids

Pure geometric isomers of conjugated linoleic acid were prepared from castor oil as the primary starting material. Methyl octadeca-9Z, 11E-dienoate (2) and methyl octadeca-9Z, 11Z-dienoate (4) were obtained by zinc reduction of methyl santalbate (1, methyl octadec-11E-en-9-ynoate) and methyl octadec-11 Z-en-9-ynoate (3), respectively, as the key intermediates. Methyl octadeca-9E, 11E-dienoate (8) and methyl octadeca-9E, 11Z-dienoate (9) were prepared by demesylation of the mesyloxy derivative of methyl ricinelaidate (6, methyl 12-hydroxy-octadec-9 E-enoate). A study of the nuclear magnetic resonance spectral properties was carried out and the shifts of the olefinic carbon atoms of 18:2(9Z, 11E) (2) and 18:2(9E, 11Z) (9) were readily identified by a combination of incredible natural abundance double quantum transfer experiment, heteronuclear multiple bond correlation, and ¹H−¹³C correlation spectroscopy correlation techniques. Doubts remain in the absolute identification of the individual olefinic carbon atoms of the 18:2(9Z, 11Z) (4) and 18:2(9E, 11E) (8), except the fact that the shifts of the “inner” (C-10 and C-11) and “outer” (C-9 and C-12) positioned olefinic carbon atoms of the conjugated diene system are distinguishable.     

Dimensional analysis of performance of a solar-cum-wind aspirator developed at ciae

Air flow through a solar-cum-wind aspirator is induced by both thermal buoyancy and wind effects. A similitude study has been conducted to characterize air flow rates through solar-cum-wind aspirators. A relationship between the air flow rate and height and diameter of the aspirator, wind speed, temperature rise inside the stack, and relevant air properties has been developed on the basis of the experimental data collected under field conditions.     

Formamide driven synthesis of well-aligned ZnO nanorod arrays on glass substrate

A cost effective, low-temperature approach has been developed for the large-area deposition of ZnO nanorod/nanotube arrays on a ZnO coated glass substrate by the natural oxidation of zinc metal in formamide/water mixtures. The two-step seed deposition and wet-chemical approach exhibited well-controlled growth of highly oriented and densely packed ZnO nanorod/nanotube arrays with large-area homogeneity and uniform morphologies. In order to investigate the quality and alignment of ZnO nanorod arrays grown on the ZnO seed layer coated substrate, three different methods of ZnO coating have been deposited by ultrahigh vacuum evaporation system, DC sputtering and RF sputtering, respectively. Our results showed that the ZnO seed layer grown by RF sputtering resulted in high quality ZnO nanorod arrays.     

A load-aware energy-efficient and throughput-maximized asynchronous duty cycle MAC for wireless sensor networks

Being a pivotal resource, conservation of energy has been considered as the most striking issue in the wireless sensor network research. Several works have been performed in the last years to devise duty cycle based MAC protocols which optimize energy conservation emphasizing low traffic load scenario. In contrast, considering the high traffic situation, another research trend has been continuing to optimize both energy efficiency and channel utilization employing rate and congestion control at the MAC layer. In this paper, we propose A Load-aware Energy-efficient and Throughput-maximized Asynchronous Duty Cycle MAC (LET-MAC) protocol for wireless sensor networks to provide an integrated solution at the MAC layer considering both the low-and high-traffic scenario. Through extensive simulation using ns-2, we have evaluated the performance of LET-MAC. LET-MAC achieves significant energy conservation during low traffic load (i.e., no event), compared to the prior asynchronous protocol, RI-MAC, as well as attains optimal throughput through maximizing the channel utilization and maintains lower delay in regard to the CSMA/CA-like protocol during a high volume of traffic (i.e., when an event occurs).     

Pollen morphology and its taxonomic potential in some selected taxa of Caesalpiniaceae observed under light microscopy and scanning electron microscopy

Pollen micromorphology is not only used to check the functional and structural evolution in plants but also to solve the taxonomic problem related to the classification of plants. Therefore, keeping in view the significance of pollen traits, selected taxa of the subfamily Caesalpiniaceae was collected from different geographical regions of Pakistan. The species were then analyzed under both light microscopy and scanning electron microscopy techniques to investigate the importance of micromorphological characters of pollen in the identification and classification of species. Great variation was recorded in equatorial shape, surface ornamentation, tectum, polar diameter, equatorial diameter, and exine thickness. However, little variation was observed in pollen type, polar shape, and fertility of pollen. The equatorial shape of five types was observed: prolate, prolate-spheroidal, spheroidal-subprolate, subspheroidal-prolate, and subspheroidal. Four types of surface ornamentation, psilate, granulate, clavate, and perforate, were recorded. Tectum of five types, intactate, reticulate regulate, medium reticulate, tactate, and striate, was observed. Sexine was thicker than nexine in all studied species. The largest polar diameter was observed in Caesalpinia pulcherrima 64.1 μm while the smallest in Parkinsonia aculeata 26.1 μm. The largest equatorial diameter was found in C. pulcherrima of 70.25 μm whereas the smallest in P. aculeata 27.57 μm. All the pollens analyzed were tricolporate. All studied species have a fertility ratio of more than 90%. A taxonomic key was developed to show the variation in pollen features and delimit species for the correct identification. In conclusion, the pollen traits were found useful to define species boundaries at various taxonomic ranks and will strengthen the taxonomy of this subfamily. Besides, this study also explored the palynological traits and their implication in the taxonomy of the subfamily Caesalpiniaceae.     

Effect of Bubble Turbulence and Submergence on Boiling Incipience in Vertical Thermosiphon Reboiler

A detailed study has been carried out to clarify the conditions of boiling incipience phenomena for natural flow in vertical tube thermosiphon reboiler. A semi-empirical model has been proposed that considers the effect of turbulent eddies and submergence for the data available in literature. Boiling incipience in liquid films is influenced both by turbulent eddies and submergence, and their effect is dominant with increasing heat flux. The superheat for boiling incipience was determined experimentally for different types of organic liquids including water, covering a wide range of physical properties. The predicted results from the proposed model and experimental data available in literature show a consistency for all fluids investigated in this study. It has an average absolute relative error of 15% for the proposed unified correlation of all fluid systems together, which have a wide range of thermophysical properties.