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91.
Nikolay Gorshkov Vladimir Goffman Maria Vikulova Igor Burmistrov Vladimir Sleptsov Alexander Gorokhovsky 《应用聚合物科学杂志》2020,137(22):48762
Composite materials with a high permittivity (high-k) and low dielectric loss represent an important research direction for the rapid development of modern electronic. This article is about high-k composite with low dielectric loss (dielectric constant is approximately 11, and dielectric loss is only 0.02 at 1 MHz and about 50 wt % of filler) based on a polytetrafluorethylene (PTFE) compounded with priderite (K1.46Ti7.2Fe0.8O16). The dielectric permittivity about ε' ≈ 103 and the dielectric loss of tgδ ≈ 2 have been found for filler content about 50 wt % (30 vol %) and, respectively, ε' ≈ 11 and tgδ ≈ 0.02 for 1 MHz. To produce filler, amorphous potassium polytitanate was synthesized by molten salt method, modified in aqueous solution of iron sulfate, crystallized at 700 °C and further treated in the aqueous dispersion of PTFE. The obtained product was pressured, dried and investigated by X-ray diffraction and scanning electron microscopy. Dielectric properties of the composite with different ceramic filler content (1–90 wt %) were studied using impedance spectroscopy in the frequency range of 10−2 to 106 Hz. The influence of frequency on electric conductivity, permittivity, and dielectric losses was analyzed taking into account the experimental data on porosity, apparent density obtained for the composites. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48762. 相似文献
92.
Emine Kaplanoglu Igor Kolotilin Rima Menassa Cam Donly 《International journal of molecular sciences》2022,23(7)
Plant-mediated RNA interference (RNAi) holds great promise for insect pest control, as plants can be transformed to produce double-stranded RNA (dsRNA) to selectively down-regulate insect genes essential for survival. For optimum potency, dsRNA can be produced in plant plastids, enabling the accumulation of unprocessed dsRNAs. However, the relative effectiveness of this strategy in inducing an RNAi response in insects using different feeding mechanisms is understudied. To investigate this, we first tested an in vitro-synthesized 189 bp dsRNA matching a highly conserved region of the v-ATPaseA gene from cotton mealybug (Phenacoccus solenopsis) on three insect species from two different orders that use leaf-chewing, lacerate-and-flush, or sap-sucking mechanisms to feed, and showed that the dsRNA significantly down-regulated the target gene. We then developed transplastomic Micro-tom tomato plants to produce the dsRNA in plant plastids and showed that the dsRNA is produced in leaf, flower, green fruit, red fruit, and roots, with the highest dsRNA levels found in the leaf. The plastid-produced dsRNA induced a significant gene down-regulation in insects using leaf-chewing and lacerate-and-flush feeding mechanisms, while sap-sucking insects were unaffected. Our results suggest that plastid-produced dsRNA can be used to control leaf-chewing and lacerate-and-flush feeding insects, but may not be useful for sap-sucking insects. 相似文献
93.
Multifunctional iron-carbon nanocomposites through an aerosol-based process for the in situ remediation of chlorinated hydrocarbons 总被引:1,自引:0,他引:1
Zhan J Kolesnichenko I Sunkara B He J McPherson GL Piringer G John VT 《Environmental science & technology》2011,45(5):1949-1954
Spherical iron-carbon nanocomposites were developed through a facile aerosol-based process with sucrose and iron chloride as starting materials. These composites exhibit multiple functionalities relevant to the in situ remediation of chlorinated hydrocarbons such as trichloroethylene (TCE). The distribution and immobilization of iron nanoparticles on the surface of carbon spheres prevents zerovalent nanoiron aggregation with maintenance of reactivity. The aerosol-based carbon microspheres allow adsorption of TCE, thus removing dissolved TCE rapidly and facilitating reaction by increasing the local concentration of TCE in the vicinity of iron nanoparticles. The strongly adsorptive property of the composites may also prevent release of any toxic chlorinated intermediate products. The composite particles are in the optimal range for transport through groundwater saturated sediments. Furthermore, those iron-carbon composites can be designed at low cost, the process is amenable to scale-up for in situ application, and the materials are intrinsically benign to the environment. 相似文献
94.
Formation of pesticide nonextractable (bound) residues in soil: magnitude, controlling factors and reversibility 总被引:1,自引:0,他引:1
The analysis of the coherent data on nonextractable (bound) residues (NER) from the literature and EU pesticide registration dossiers allows the identification of general trends, in spite of the large variability and heterogeneity of data. About 50% of the pesticides reviewed exhibit a low proportion of NER (less than 30% of the initial amount) while only 12% of pesticides have a proportion of NER exceeding 70%. The lowest proportion of NER was found for dinitroanilines (<20%), and the largest value was obtained for carbamates, and in particular dithiocarbamates. The presence of chemical reactive groups, such as aniline or phenol, tends to yield a larger proportion of NER. NER originating from N-heteroatomic ring were found to be lower than those from phenyl-ring structures. Among the environmental factors affecting the formation of NER, microbial activity has a direct and significant effect. Concerning the NER uptake or their bioavailability, consistent data suggest that only a small percentage of the total amounts of NER can be released. The analysis of NER formation kinetics showed that incubation experiments are often stopped too early to allow a correct evaluation of the NER maturation phase. Therefore, there is a need for longer term experiments to evaluate the tail of the NER formation kinetics. Still, the heterogeneity of the NER data between pesticides and for specific pesticides calls for great care in the interpretation of the data and their generalization. 相似文献
95.
Manganese dioxide nanofibers with length ranged from 0.1 to 1 μm and a diameter of about 4–6 nm were prepared by a chemical
precipitation method. Composite electrodes for electrochemical supercapacitors were fabricated by impregnation of the manganese
dioxide nanofibers and multiwalled carbon nanotubes (MWCNT) into porous Ni plaque current collectors. Obtained composite electrodes,
containing 85% of manganese dioxide and 15 mass% of MWCNT, as a conductive additive, with total mass loading of 7–15 mg cm−2, showed a capacitive behavior in 0.5-M Na2SO4 solutions. The decrease in stirring time during precipitation of the nanofibers resulted in reduced agglomeration and higher
specific capacitance (SC). The highest SC of 185 F g−1 was obtained at a scan rate of 2 mV s−1 for mass loading of 7 mg cm−2. The SC decreased with increasing scan rate and increasing electrode mass. 相似文献
96.
97.
Tomaž Javornik Igor Jelovčan S. Sheikh Muhammad Gorazd Kandus 《AEUE-International Journal of Electronics and Communications》2009,63(7):595-599
In the following paper we propose a new approach for extracting soft values from Mth order pulse position modulation (M-PPM). A new low-complexity algorithm is developed, where soft information for each data bit is calculated based on the power received within the PPM time slots. In order to decrease the computational complexity we simplify the calculation of the conditional probability of data vector a given that PPM symbol Y is received. The Monte Carlo simulations applied to analyze the properties of the algorithm for turbo-coded M-PPM transmission in free space optic communication systems show acceptable degradation of system performance with regard to system simplification. 相似文献
98.
Igor Matutinovi 《Energy Policy》2009,37(11):4251-4258
The key issues concerning oil exploitation are still open for discussion: there is no agreement about where we presently stand in the world oil extraction curve, what is its exact shape, and how far can oil price grow before it changes irreversibly the world economy and consumer behavior. The paper proposes an alternative scenario to the Hubbert's bell-shaped model of oil exploitation, based on more realistic assumptions regarding political agendas in oil-exporting countries and consumer behavior dynamics in oil-importing countries. Under this scenario, the joint impact of markets and public policy in oil importing countries together with “resource pragmatism” policy in oil-exporting countries allows for a less steep oil supply curve with a much fatter tail compared to the Hubbert's model. 相似文献
99.
Victor Prikhodko Igor Yarygin Vyacheslav Yarygin 《Microgravity science and technology》2009,21(Z1):277-281
We present the experimental research on the interaction of co-current gas flow with near-wall liquid film for gas velocities
up to 300 m/s. Local parameters of near-wall liquid film are measured by using capacity-type probes. It is shown that co-current
gas flow has strong influence on near-wall liquid film, leading to intensive wave formation, detachment of droplets from the
film surface and their entrainment by the gas flow. Thus it is shown that the relative amount of liquid carried away by co-current
gas flow is well characterized by Weber number of gas flow. A model for the motion of a film with co-current flow, connecting
a thickness and velocity of the film with value of shearing stress at gas-liquid boundary, is suggested. It is shown that
intensive wave formation leads to essential increase of the interphase friction value. 相似文献
100.
An argument is put forward to show that visual art may actually be translated into tactile objects that produce equivalent aesthetic experiences for blind or visually impaired people. This is shown by delineating the information required for such a translation in general, demonstrating that such a translation is already achievable from color vision to color vision and theoretically possible from spatial vision to spatial touch, and outlining that an analogous procedure could be applied to aesthetic experience. Limitations of such translations of visual works of art into tactile objects, and implications of such a procedure for artistic experience and education, are also mentioned. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献