Argon Implantation in Tetrahedral Amorphous Carbon Deposited by Filtered Cathodic Vacuum Arc

The implantation of argon in tetrahedral amorphous carbon (ta-C), deposited by the filtered cathodic vacuum arc technique and concurrently bombarded with argon ions (Ar⁺), is investigated in this study. The ta-C films were prepared with a 5-ms DC-pulsed arc, a current of 190 A, and a frequency of 3 Hz, and they were deposited on a ground substrate holder. The argon atoms were implanted into the film by simultaneously bombarding the films with a beam of Ar⁺ in the 0-180 eV energy range. The concentration of argon, determined by Rutherford backscattering spectroscopy, was investigated as a function of the Ar⁺ energy. Raman scattering spectroscopy was used to investigate the structure of the films. The stress of the films depends on the Ar⁺ energy and reduces significantly as a function of the annealing temperature. A study of argon effusion, ranging from room temperature up to 1000 °C, shows that the argon atoms evolve from the films at different temperatures depending on the Ar⁺ energy. Scanning electron microscopy revealed the formation of bubbles after argon effusion. It was observed that the structural transformations that promote the relaxation of the carbon matrix and the argon effusion are different from each other.     

Highly translucent nanostructured glass-ceramic

Transparent and translucent glass-ceramics (GCs) are found in an increasing number of domestic and high-technology applications. In this paper, we evaluated and optimized the effects of two-stage heat treatments on the resulting crystalline phases and microstructure of a glass of the SiO₂–Li₂O–P₂O₅–TiO₂–CaO–ZnO–Al₂O₃ system. The objective was to develop a transparent nanostructured glass-ceramic (GC). After numerous heat treatment trials, we found that a long nucleation period of 72 h at 455 °C followed by a crystal growth treatment at 660 °C for 2 h resulted in a highly translucent GC having homogenously distributed nanocrystals. The relatively high amount of P₂O₅ (2.5 mol%) induced the formation of lithium disilicate as the main crystal phase. We thus developed a GC having crystals under 50 nm, with a high crystallized fraction (52%vol. Li₂Si₂O₅ and 26% vol Li₂SiO₃), transmittance of approximately 80% in the visible spectrum for 1.2 mm thick specimens, nano hardness of 8.7 ± 0.1 GPa (load of 400 mN), a high elastic modulus of 138 ± 3 GPa as measured by nanoindentation, and good flexural strength (350 ± 40 MPa) as measured by ball-on-3 balls tests. Due to its high content of Li⁺, this GC has the potential to be chemically strengthened and can be further developed to be used in a number of applications, such as on displays of electronic devices.     

Fundamental Parameters for the Stiffness and Strength Control of Artificially Cemented Sand

The treatment of soils with cement is an attractive technique when the project requires improvement of the local soil for the construction of subgrades for rail tracks, as a support layer for shallow foundations and to prevent sand liquefaction. As reported by Consoli et al. in 2007, a unique dosage methodology has been established based on rational criteria where the voids/cement ratio plays a fundamental role in the assessment of the target unconfined compressive strength. The present study broadened the research carried out by Consoli et al. in 2007 through quantifying quantifies the influence of voids/cement ratio on the initial shear modulus (G0) and Mohr-Coulomb effective strength parameters (c′,?′) of an artificially cemented sand. A number of unconfined compression and triaxial compression tests with bender elements measurements were carried out. It was shown that the void/cement ratio defined as the ratio between the volume of voids of the compacted mixture and the volume of cement is an appropriate parameter to assess both initial stiffness and effective strength of the sand-cement mixture studied.     

Influence of manufacturing process on tabletting ability of powder: comparison between blending, grinding, and spray drying of two formulations made of theophylline and lactose/cellulose or Cellactose

Three manufacturing processes were applied to two formulations composed of 20% anhydrous theophylline associated with either 20% microcrystalline cellulose and 60% lactose or 80% Cellactose®. The processing method (dry blending, grinding, or spray drying) and the formulation were investigated through the comparison of the physical and flow characteristics and the compactibility of the end products. The results demonstrated that the formulation had a major effect on the mechanical properties, with binary blends exhibiting a higher resistance than ternary ones, whereas flow properties and densification depended on the process. Nevertheless, it was also observed that spray drying decreased the difference between the mechanical properties of the two formulations, probably by modifying the texture of the Cellactose® in suspension.     

Experimental Analysis of Approximation Algorithms for the Vertex Cover and Set Covering Problems

Several approximation algorithms with proven performance guarantees have been proposed to find approximate solutions to classical combinatorial optimization problems. However, theoretical results may not reflect the experimental performance of the proposed algorithms. As a consequence, a question arises: how “far” from the theoretically proved performance are the experimental results? We conduct a controlled empirical study of approximation algorithms for the Vertex Cover and the Set Covering Problems. Many authors have proposed approximation algorithms for those problems. Our main goal is to better understand their strengths, weaknesses, and operation. Although we implement more than one algorithm to find feasible solutions to either problems, this work does not emphasize competition between them. The quality of the solutions related to the theoretical performance guarantees are analyzed instead. The computational experiments showed that the proven performance guarantees of all tested algorithms did not forecast well the empirical performance.     

The scientists pyramid

Summary In this short paper I propose a combination of qualitative and quantitative criteria to classify the quality, talent and creative thinking of the scientists of the “hard”, medical and biological sciences. The rationale for the proposed classification is to focus on the impact and overall achievements of each individual scientist and on how he is perceived by his own community. This new method is probably more complete than any other form of traditional judgment of a scientist's achievements and reputation, and may be useful for funding agencies, editors of scientific journals, science academies, universities, and research laboratories.     

The roles of textural images in improving land-cover classification in the Brazilian Amazon

Texture has long been recognized as valuable in improving land-cover classification, but how data from different sensors with varying spatial resolutions affect the selection of textural images is poorly understood. This research examines textural images from the Landsat Thematic Mapper (TM), ALOS (Advanced Land Observing Satellite) PALSAR (Phased Array type L-band Synthetic Aperture Radar), the SPOT (Satellite Pour l’Observation de la Terre) high-resolution geometric (HRG) instrument, and the QuickBird satellite, which have pixel sizes of 30, 12.5, 10/5, and 0.6 m, respectively, for land-cover classification in the Brazilian Amazon. GLCM (grey-level co-occurrence matrix)-based texture measures with various sizes of moving windows are used to extract textural images from the aforementioned sensor data. An index based on standard deviations and correlation coefficients is used to identify the best texture combination following separability analysis of land-cover types based on training sample plots. A maximum likelihood classifier is used to conduct the land-cover classification, and the results are evaluated using field survey data. This research shows the importance of textural images in improving land-cover classification, and the importance becomes more significant as the pixel size improved. It is also shown that texture is especially important in the case of the ALOS PALSAR and QuickBird data. Overall, textural images have less capability in distinguishing land-cover types than spectral signatures, especially for Landsat TM imagery, but incorporation of textures into radiometric data is valuable for improving land-cover classification. The classification accuracy can be improved by 5.2–13.4% as the pixel size changes from 30 to 0.6 m.     

On graph reasoning

In this paper, we study the (positive) graph relational calculus. The basis for this calculus was introduced by Curtis and Lowe in 1996 and some variants, motivated by their applications to semantics of programs and foundations of mathematics, appear scattered in the literature. No proper treatment of these ideas as a logical system seems to have been presented. Here, we give a formal presentation of the system, with precise formulation of syntax, semantics, and derivation rules. We show that the set of rules is sound and complete for the valid inclusions, and prove a finite model result as well as decidability. We also prove that the graph relational language has the same expressive power as a first-order positive fragment (both languages define the same binary relations), so our calculus may be regarded as a notational variant of the positive existential first-order logic of binary relations. The graph calculus, however, has a playful aspect, with rules easy to grasp and use. This opens a wide range of applications which we illustrate by applying our calculus to the positive relational calculus (whose set of valid inclusions is not finitely axiomatizable), obtaining an algorithm for deciding the valid inclusions and equalities of the latter.     

One step gold (bio)functionalisation based on CS2-amine reaction

Dithiocarbamates have been regarded as alternative anchor groups to thiols on gold surfaces, and claimed to be formed in situ through the reaction between secondary amines and carbon disulphide. In this paper, we further exploit this methodology for a convenient one step biomolecule immobilisation onto gold surfaces. First, the reactivity between CS₂ and electroactive compounds containing amines, primary (dopamine), secondary (epinephrine), and an amino acid (tryptophan) has been investigated by electrochemical methods. Cyclic voltammetric characterisation of the modified electrodes confirmed the immobilisation of all the target compounds, allowing the estimation of their surface concentration. The best result was obtained with epinephrine, a secondary amine, for which a typical quasi-reversible behaviour of surface confined electroactive species could be clearly depicted. Electrochemical reductive desorption studies enabled to infer on the extent of the reaction and on the relative stability of the generated monolayers. Bio-functionalisation studies have been accomplished through the reaction of CS₂ with glucose oxidase in aqueous medium, and the catalytic activity of the immobilised enzyme was evaluated towards glucose, by electrochemical methods in the presence of a redox mediator. Scanning tunnelling microscopy (STM) and Atomic force microscopy (AFM) were used respectively, to characterize the gold electrodes and Glucose Oxidase coverage and distribution on the modified surfaces.     

Diamond-like carbon deposited by plasma technique as a function of methane flow rate

Diamond-like carbon (a-C:H) prepared by plasma enhanced chemical vapor deposition (PECVD) as a function of methane gas flow rate is reported. Films deposited at zero flow rate, i.e., without the use of vacuum pumps during the deposition, are also investigated. For that purpose, the reactor chamber was baked and pumped down to about 10^?8 Torr to reduce contamination released from the reactor walls. The films were analyzed by visible, infrared and Raman spectroscopes. It was observed that the deposition rate, hydrogen concentration and optical gap depend on the methane gas flow rate. A maximum for deposition rate found at methane flow was much smaller than the flow usually adopted in conventional procedures.