Study on pH‐sensitive and thermosensitive polymer networks containing polyacetal segments

A series of pH‐sensitive and thermosensitive polymer networks were first obtained by copolymerization of telechelic poly(1,3‐dioxolane) (PDXL) with acrylic acid (AA), acrylamide (AM), and N‐isopropylacrylamide (NIPAM), respectively. The copolymerization of PDXL diacrylate (PDXLDA) with AA, AM, or NIPAM is expected to lead to polymer networks in which homopolymeric segments of the monomer are connected by polyacetal segments. As a combination of these two parts, these polymer networks can have some interesting physical properties. For example, the copolymer networks of poly(AA‐b‐DXL) showed pH sensitivity, and both the copolymer networks of poly(AM‐b‐DXL) and poly(NIPAM‐b‐DXL) showed temperature sensitivity. Moreover, because of the low ceiling temperature of polyDXL, the networks containing polyacetal segments (PDXL) can degrade by treatment with a trace of appropriate cationic initiator. The polymer networks prepared were characterized by Fourier transform infrared, differential scanning calorimetry, and swelling data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 3002–3006, 2002; DOI 10.1002/app.2329     

一种复合各向异性扩散的图像去噪算法

本文提出一种复合各向异性扩散滤波算法,将降斑各向异性扩散(Speckle reducing anisotropic diffusion,SRAD)模型中对边缘敏感的瞬态系数(Instantaneuos coefficient of variation,ICOV)算子运用到了非线性相干扩散(Nonlinear coherent diffusion,NCD)相干模型中,并基于统计学提出ICOV算子的相关系数矩阵对图像的相关度进行度量,系数矩阵的值是每个ICOV算子与其所在行与列的相关度,此相关度的值在边缘附近会取到极大值,这个对图像的边缘检测有很好的度量,根据每个像素与其周围像素的相关度对边缘附近的扩散的强度进行修改,对图像进行更为之有效、更准确的非线性去噪与边缘加强.实验结果表明,与其他各向异性算法相比,本算法可获得更好的性能指标,具有更好的去噪效果和保留边缘功能.     

Soap‐free emulsion copolymerization of perfluoroalkyl acrylates in the presence of a reactive surfactant

Soap‐free emulsion copolymerization of perfluoroalkyl acrylate (FA)/methyl methacrylate (MMA)/n‐butyl acrylate (n‐BA) was carried out in the presence of sodium 2‐acrylamide‐2‐methyl propanesulfonate (AMPSNa) as a reactive surfactant and potassium persulfate (KPS) as an initiator. An analysis of the effects of concentration of AMPSNa, KPS, FA as well as polymerization temperature on the kinetic features (rate of polymerization) and colloidal characteristics (mean particle diameter, particle disperse index, particle numbers, and surface charge density) was followed. NMR, FTIR, AFM, and fluorine‐selective electrode analysis were used to characterize the composition and morphology of the FA copolymers. Both AFM analysis and contact angle measurements strongly implied that the fluorinated segments migrated to the outmost surface and created films with lower surface energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2438–2444, 2007     

WO3/TiO2光催化剂的制备及光催化产氢性能研究

针对催化剂TiO_2禁带宽度较宽、光响应范围较窄的问题,对TiO_2进行改性,采用溶胶凝胶法制备了不同复合比例的WO_3/TiO_2催化剂以提高TiO_2的光催化活性。应用SEM,BET,XRD,UV-Vis,FT-IR等方法对催化剂进行表征,分析了不同复合比对WO_3/TiO_2样品形貌、晶型、比表面积和产氢速率的影响。当入射波长为300~600 nm,2%WO_3/TiO_2的吸光度大于TiO_2的吸光度,吸收带边红移。通过300 W氙灯照射进行光解水制氢的测试,评价了不同WO_3/TiO_2样品的光催化分解水产氢活性。结果表明:复合比为2%时,WO_3/TiO_2的光解水产氢活性最佳,最高可达14 445.3μmol/(h·g),其产氢速率是TiO_2的10倍,同时探讨分析了光催化反应机理。这将在太阳能光解水产氢领域有着广泛的应用前景。     

Automatic 3D Indoor Scene Updating with RGBD Cameras

Since indoor scenes are frequently changed in daily life, such as re‐layout of furniture, the 3D reconstructions for them should be flexible and easy to update. We present an automatic 3D scene update algorithm to indoor scenes by capturing scene variation with RGBD cameras. We assume an initial scene has been reconstructed in advance in manual or other semi‐automatic way before the change, and automatically update the reconstruction according to the newly captured RGBD images of the real scene update. It starts with an automatic segmentation process without manual interaction, which benefits from accurate labeling training from the initial 3D scene. After the segmentation, objects captured by RGBD camera are extracted to form a local updated scene. We formulate an optimization problem to compare to the initial scene to locate moved objects. The moved objects are then integrated with static objects in the initial scene to generate a new 3D scene. We demonstrate the efficiency and robustness of our approach by updating the 3D scene of several real‐world scenes.     

铝酸酯改性滑石粉的反应机理及其在橡胶中的应用

研究了铝酸酯改性滑石粉的反应机理，通过测量其在液体石蜡中的粘度和水渗透速度对改性效果进行评价，结果表明：铝酸酯改性后的滑石粉与普通滑石粉相比，在液体石蜡中的粘度显著减小，水渗透时间增大，有机憎水改性效果明显。由铝酸酯改性的滑石粉代替半补强碳黑填充于橡胶中，提高了橡胶的拉伸强度，长伸率等力学性能。     

An FAR-SW based approach for webpage information extraction

Automatically identifying and extracting the target information of a webpage, especially main text, is a critical task in many web content analysis applications, such as information retrieval and automated screen reading. However, compared with typical plain texts, the structures of information on the web are extremely complex and have no single fixed template or layout. On the other hand, the amount of presentation elements on web pages, such as dynamic navigational menus, flashing logos, and a multitude of ad blocks, has increased rapidly in the past decade. In this paper, we have proposed a statistics-based approach that integrates the concept of fuzzy association rules (FAR) with that of sliding window (SW) to efficiently extract the main text content from web pages. Our approach involves two separate stages. In Stage 1, the original HTML source is pre-processed and features are extracted for every line of text; then, a supervised learning is performed to detect fuzzy association rules in training web pages. In Stage 2, necessary HTML source preprocessing and text line feature extraction are conducted the same way as that of Stage 1, after which each text line is tested whether it belongs to the main text by extracted fuzzy association rules. Next, a sliding window is applied to segment the web page into several potential topical blocks. Finally, a simple selection algorithm is utilized to select those important blocks that are then united as the detected topical region (main texts). Experimental results on real world data show that the efficiency and accuracy of our approach are better than existing Document Object Model (DOM)-based and Vision-based approaches.     

基于LabVIEW的虚拟数字存储示波器的设计

利用 LabVIEW 强大的数据采集、处理和程序设计功能,设计、开发了一款数字存储示波器。它主要是由信号输入模块、数据处理模块和波形显示及存储模块组成,是通过软件编程实现信号的显示和测量等功能的。在虚拟示波器上集成的虚拟信号发生器可以在声卡采集和虚拟信号输入之间切换。实验结果表明,该虚拟示波器基本实现了传统示波器的功能,并且运行可靠、性能良好,能够满足普通实验室正常的使用需求。     

一种基于UML的网络安全体系建模分析方法

在现有法律法规和标准体系的指导下,提出了一种通用的网络安全体系框架,阐述了安全目标、安全边界、安全体系要素与安全服务和安全风险评估之间的关系.在网络安全体系框架的基础上,利用统一建模语言(Unified Modeling Language,UML)在建模表述上的强大性和通用性给出了安全目标、安全边界和安全体系要素的建模方法,以规范化安全体系的表示形式并消除沟通中的歧义性.利用建立的模型,安全管理员使用提出的网络安全建模分析方法,可以验证业务流程的目标满足性并得出可能的安全风险.最后通过一个典型网上银行网络的建模分析,验证了提出的安全体系框架和建模分析方法的有效性和合理性.相比于传统的方法,该方法建模分析要素更为全面,且推导得出的结果指导性更强.