Series resistance determination of Au/Polypyrrole/p-Si/Al structure by current–voltage measurements at low temperatures

The current–voltage (I–V) characteristics of Polypyrrole(PPy)/p-Si/Al structure have been investigated as a function of temperature. A modified Norde function combined with conventional forward I–V method has been used to extract the junction parameters including the ideality factor, barrier height and series resistance. Norde function has been compared with the Cheung functions and it has been seen that there is a good agreement with both method for the barrier height values. However, the values of series resistance have very different especially towards to the lower temperatures. This is attributed to non-ideal I–V characteristics of the Au/PPy/p-Si/Al structure and non-pure Thermionic emission theory due to the low temperature effects.     

Combine Effects of Essential Oils and Packaging on Smoked Rainbow Trout Stored 4°C

In this study, the effect of essential oils (thyme and clove) and packaging treatments (vacuum and modified atmosphere) on the storage of hot smoked rainbow trout (Oncorhynchus mykiss) fillets over a period of 120 days at 4°C was investigated. Fillets were subjected to microbiological (total aerobic mesophilic bacteria, psychrotrophic bacteria, lactic acid bacteria, yeast and mould), chemical analyses (pH, thiobarbituric acid reactive substances and total volatile base nitrogen) and quality testing throughout the storage period. Difference in microbiological and chemical changes between samples was found to be significant (p < 0.05) during storage period. Sensory evaluation showed significant differences between the samples, and V2 and M2 samples were assessed as the most acceptable products by the panellists. In conclusion, essential oils treatment to hot smoking had a positive effect on shelf life of rainbow trout, especially clove oil showed more positive effect when compared with thyme oil. Copyright © 2015 John Wiley & Sons, Ltd.     

The TeO2-Na2O System: Thermal Behavior,Structural Properties,and Phase Equilibria

Thermal behavior, structural properties, and phase equilibria of the (100−x)TeO₂-xNa₂O system were studied in the 5 ≤ x ≤ 50 mol% composition range. Investigation of glass formation behavior in the binary system was realized, and the glass formation range was determined as 7.5 ≤ x ≤ 40 mol%. Differential thermal analysis (DTA) and Fourier transform infrared (FTIR) spectroscopy techniques were used for thermal and structural characterization of the glasses. Influence of Na₂O content on glass transition temperature (T_g), glass stability (∆T), density (ρ), molar volume (V_M), oxygen molar volume (V_O), and oxygen packing density (OPD) values of sodium tellurite glasses was evaluated considering the structural transformations in the glass network. For the phase equilibria studies, DTA, X-ray diffraction (XRD), and scanning electron microscopy/energy dispersive X-ray (SEM/EDS) techniques were utilized to characterize the heat-treated samples. According to the phase equilibria studies, three eutectic regions were detected in the 0 < x < 50 mol% composition range of the (100−x)TeO₂-xNa₂O system. A new invariant endothermic reaction was detected for the compositions between 40 ≤ x ≤ 45 mol%. Na₂O.8TeO₂ (11.11 mol% Na₂O) compound that was claimed to exist in the binary system in the literature was found to be the metastable δ-TeO₂ phase.     

Understanding traditional residential architecture in Anatolia

Traditional architecture and associated environments created by residential buildings provide an important focus of interest in contemporary Turkey.1 1. The main thesis of this article is based upon my paper ‘Traditional Residential Architecture in Anatolia’, presented to a seminar on Conservation and Rehabilitation of Half-Timber Structures, Ankara: METU, 1989 and the doctoral thesis submitted to METU, Faculty of Architecture, Program of Restoration in 1994. The concepts have, however, been revised according to more recent surveys. They are generally accepted as physical witnesses of the past to be preserved and studied. Continuity in the traditional characteristics of the social group living in these environments has been observed in many of the extant settlements in Turkey. The reciprocal relationship between the dwelling and its owners, or users, has led to a dual definition of the ‘traditional dwelling unit’: the social unit being the ‘family’, the architectural unit the ‘dwelling’. The existing, modest-scaled, traditional dwellings in Turkey, which constitute the subject of this study, were mostly constructed after the seventeenth century, but more recent buildings exhibiting similar characteristics are also covered by the term ‘traditional’.2 2. The concepts of ‘tradition’, ‘culture’, ‘vernacular’, ‘historical’, ‘regional’, ‘pre-industrial’, ‘popular’ and ‘folk’ fall outside the limits of this study. The term ‘traditional’ has been used throughout the text; the term ‘Ottoman’ has not been adopted due to its attribution to the 1923 constitution of the Turkish Republic — it cannot, consequently, be used as reference to the continuation of tradition, which is one of the main ‘givens’ of this study. A term referring to a geographical distribution of archetype under investigation has been sought. There is an important building stock incorporating similar architectural characteristics within contemporary political boundaries of other countries, such as Iran, Bulgaria, Greece, etc., which had once formed part of the Ottoman Empire. ‘Turkey’ has not been preferred for its reference to the political boundaries of the Republican era for the same reason. Instead, another geographical term ‘Anatolia’ is considered in a widened context throughout the text to refer to a more generic concept than it implies geographically. Anatolia is considered to be the land of origin on which many cultures have emerged, generated and spread to the affected lands throughout history. Furthermore, the concentration of this study focuses specifically on extant dwellings in Anatolia. Within the confines of the term ‘traditional residential architecture in Anatolia’, there are further limitations. The origin of traditional residential architecture in Anatolia, its typological evolution, its social, cultural and/or historical aspects are not the major concerns of this study, which focuses on existing examples. A limitation of the period covered by this study accords with the construction dates of extant buildings from the seventeenth century onwards. This is an open-ended period because of the continuity in ‘traditional’ aspects in many of the settlements. The concept of ‘privacy’ serves as the basis of evaluation in analysing the interrelation of any two units. The interface of two units can be defined as an hierarchy of privacy represented sociologically by the interrelations of person/family/neighbourhood relationships and architecturally through the interrelations of room/dwelling unit/street/neighbourhood.3 3. This dwelling unit was the subject of the studio course ARCH 405 in 1989—1990, Autumn semester. The project was supervised by the author and Res.Asst. Ertu?rul Morçöl; the students were Önder Kaya, Ufuk Serin, Murat Aya?, Deniz Kutay and Gül Vanl?. This approach will include a brief summary of some previous studies of traditional residential architecture (Fig. 1).     

Adsorption of lead and copper on bentonite and grapeseed activated carbon in single- and binary-ion systems

In this study, bentonite originating from Turkey (Eski?ehir province) and activated carbon obtained from grapeseed were used as adsorbents for the removal of lead (Pb²⁺) and copper (Cu²⁺) ions from aqueous solutions. Experiments were performed in single- and binary-ion systems at constant temperature of 298 K and pH value of 5. In order to describe the adsorption mechanism Langmuir, Freundlich and Temkin isotherms were used. The total adsorption capacity values of adsorbents were compared. It was observed that the total adsorption capacity values were changed depending on the type of adsorbent used, type of metal ion and interaction between metal ions.     

Pt nanoparticles synthesized with new surfactants: improvement in C1–C3 alcohol oxidation catalytic activity

Platinum electrocatalysts were prepared using PtCl₄ as a starting material and 1-decylamine, N,N-dimethyldecylamine, 1-dodecylamine, N,N-dimethyldodecylamine, 1-hexadecylamine, and 1-octadecylamine as surfactants. These surfactants were used for the first time in this synthesis to determine whether the primary and/or tertiary structure and/or chain length of the surfactants, affects the size and/or activity of the catalysts in C₁–C₃ alcohol electro-oxidation reactions. Electrochemical measurements (cyclic voltammetry and chronoamperometry) indicated that the highest electrocatalytic performance was observed for the Pt nanocatalysts that were stabilized by N,N-dimethyldecylamine, and this has a tertiary amine structure with a short chain length (R = C₁₀H₂₁). The high performance may be due to the high electrochemical surface area, Pt(0)/Pt(IV) ratio, %Pt utility, and roughness factor (R _f). X-ray photoelectron spectroscopy, X-ray diffraction, atomic force microscopy, and transmission electron microscopy were used to determine the parameters that affect the catalytic activities.     

Experimental verification of the kinetic model for the reaction yielding linear polyurethanes,claiming dependence of oligomer reactivities on molecular weights. III

Taking advantage of the algorithm developed earlier which makes it possible to calculate rate constants for the parallel-subsequent reactions of the kinetic model for the diisocyanate and diol polyaddition process, a mathematical model was developed for this process which then was subjected to mathematical decomposition. The procedure adopted allowed me to numerically resolve the obtained system of differential equations and to perform the numerical simulation of the polymerization process studied. For the reactions of 2,4-TDI and 1,4-butanediol, the results obtained were compared to experimental concentrations of urethane oligomer fractions found by means of GPC. It was found that the model suggested provides a better fit than does the model claiming dependence of chemical activity of oligomers solely on reactivity specifications for their functional groups. © 1996 John Wiley & Sons, Inc.