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排序方式: 共有1620条查询结果,搜索用时 15 毫秒
11.
Tony Maillet Jacques Barbier Jr. Daniel Duprez 《Applied catalysis. B, Environmental》1996,9(1-4):251-266
A 1% Pd catalyst (38% dispersion) was prepared by impregnating a γ-alumina with palladium acetylacetonate dissolved in acetone. The behaviour of this catalyst in oxidation and steam reforming (SR) of propane was investigated. Temperature-programmed reactions of C3H8 with O2 or with O2 + H2O were carried out with different stoichiometric ratios S(S =[O2]/5[C3H8]). The conversion profiles of C3H8 for the reaction carried out in substoichiometry of O2 (S < 1) showed two discrete domains of conversion: oxidation at temperatures below 350°C and SR at temperatures above 350°C. The presence of steam in the inlet gases is not necessary for SR to occur: there is sufficient water produced in the oxidation to form H2 and carbon oxides by this reaction. Contrary to what was observed with Pt, an apparent deactivation between 310 and 385°C could be observed with Pd in oxidation. This is due to a reduction of PdOx into Pd0, which is much less active than the oxide in propane oxidation. Steam added to the reactants inhibits oxidation while it prevents the reduction of PdOx into Pd0. Compared to Pt and to Rh, Pd has a higher thermal resistance: no deactivation occurred after treatment up to 700°C and limited deactivation after treatment up to 900°C, provided that the catalyst is maintained in an oxygen-rich atmosphere during the cooling. 相似文献
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Tony Proctor 《Creativity & Innovation Management》1997,6(2):94-98
A new kind of computer assisted creative problem solving method is examined in which visual images are provided to support the process. Until now, much attention has been given to developing programmes which help to structure problems and ideas so that they become more meaningful to the people who are concerned with them. Emphasis has been placed almost entirely on the written word as form of expression. It is argued that a combination of pictorial imagery and written words may be more effective in helping users to gain insights into problems and to come up with ideas or solutions to problems. 相似文献
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Differentiation of apple juice samples on the basis of heat treatment and variety using chemometric analysis of MIR and NIR data 总被引:4,自引:0,他引:4
Linda M. Reid Tony Woodcock Colm P. ODonnell J. Daniel Kelly Gerard Downey 《Food research international (Ottawa, Ont.)》2005,38(10):1109-1115
The potential of mid-infrared (MIR) and near-infrared (NIR) spectroscopy for their ability to differentiate between apple juice samples on the basis of apple variety and applied heat-treatment was evaluated. The heat-treatment involved exposure of juice samples (15 ml) for 30 s in a 900 W microwave oven and the apple varieties used to produce the juice samples were Bramley, Elstar, Golden Delicious and Jonagold. The chemometric procedures applied to the MIR and NIR data were partial least squares regression (PLS1 for differentiation on the basis of heat-treatment, PLS2 for varietal differentiation) and linear discriminant analysis (LDA) applied to principal component (PC) scores. PLS1 and PLS2 gave the highest level of correct classification of the apple juice samples according to heat-treatment (77.2% for both MIR and NIR data) and variety (78.3–100% for MIR data; 82.4–100% for NIR data), respectively. 相似文献
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Uncertainty of Predictions of Embankment Dam Breach Parameters 总被引:3,自引:0,他引:3
Tony L. Wahl 《Canadian Metallurgical Quarterly》2004,130(5):389-397
Risk assessment studies considering the failure of embankment dams often require the prediction of basic geometric and temporal parameters of a breach, or the estimation of peak breach outflows. Many of the relations most commonly used to make these predictions were developed from statistical analyses of data collected from historic dam failures. The prediction uncertainties of these methods are widely recognized to be very large, but have never been specifically quantified. This paper presents an analysis of the uncertainty of many of these breach parameter and peak flow prediction methods. Application of the methods and the uncertainty analysis are illustrated through a case study of a risk assessment recently performed by the Bureau of Reclamation for a large embankment dam in North Dakota. 相似文献
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Tony C. Scott Robert Mann Roberto E. Martinez II 《Applicable Algebra in Engineering, Communication and Computing》2006,17(1):41-47
We present a canonical form for a natural and necessary generalization of the Lambert W function, natural in that it requires minimal mathematical definitions for this generalization, and necessary in that it provides a means of expressing solutions to a number of physical problems of fundamental nature. This generalization expresses the exact solutions for general-relativistic self-gravitating N-body systems in one spatial and one time dimension, and a previously unknown mathematical link between the (1+1) gravity problem and the Schrödinger wave equation. 相似文献
19.
Integrated Microfluidic CustomArray Device for Bacterial Genotyping and Identification 总被引:2,自引:0,他引:2
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