Algorithm for the determination of intrinsic optical constants of metal films: application to aluminum

Optical and electron-energy-loss data for evaporated-aluminum films have been critically analyzed and used in an iterative, self-consistent algorithm that represents a combination of the Kramers-Kronig analysis and the semiquantum-model application. The novel values of the intrinsic optical functions of aluminum have been determined in a wide spectral range from 200 μm (6.2 meV) to 0.12 nm (10 keV). These functions are in accordance with recent calculations by Lee and Chang [Phys. Rev. B 49, 2362 (1994)], with dc conductivity measurements, and are in good agreement with both peak positions and line widths obtained from electron-energy-loss experiments. The results are examined for internal consistency by inertial and f-sum rules.     

The influence of adding pitch to resin as a matrix precursor on properties of carbon-carbon composites

Carbon-carbon composites were prepared with commercially available carbonized and graphitized fibres, with a mixture of pitch and phenolic resin as a binder and pitch as an impregnant. The contents of pitch in mixtures were: 0, 10, 20 and 30 wt %. The influence of pitch content in the mixture and fibre type on mass loss, shrinkage and mechanical properties of the composites was examined. With an increase of pitch content mass loss and shrinkage increased, while mechanical properties decreased. After three densification cycles, flexural strength increased with increasing pitch content in the binder, especially for composites with graphitized fibres.     

Special issue on information systems quality management in practice

Software Quality Journal -     

Selective Al-Ti reactivity in laser-processed Al/Ti multilayers

Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200?nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4?mJ and laser spot diameter on the sample surface was 3?mm (fluence 0.057?J?cm^?2). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Young’s modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials.     

Coping with production time variability via dynamic lead-time quotation

In this paper, we propose two dynamic lead-time quotation policies in an M/GI/1 type make-to-stock queueing system serving lead-time sensitive customers with a single type of product. Incorporating non-exponential service times in an exact method for make-to-stock queues is usually deemed difficult. Our analysis of the proposed policies is exact and requires the numerical inversion of the Laplace transform of the sojourn time of an order to be placed. The first policy assures that the long-run probability of delivering the product within the quoted lead-time is the same for all backlogged customers. The second policy is a refinement of the first which improves the profitability if customers are oversensitive to even short delays in delivery. Numerical results show that both policies perform close to the optimal policy that was characterized only for exponential service times. The new insight gained is that the worsening impact of the production time variability, which is felt significantly in systems accepting all customers by quoting zero lead times, decreases when dynamic lead-time quotation policies are employed.     

Defining the e-learner’s security profile: Towards awareness improvement

The paper presents an improved e-learner model that supports monitoring of user behavior related to information security. The model is built upon standardized IMS specification, according to literature research and survey conducted among e-learners. It is positioned as key part of an extended LTSA architecture in which the learner data is used to improve learner security position by continuous delivery of important information and adapting security mechanisms. The implementation is considered in Moodle LMS.     

Differences in cytocompatibility,dynamics of the oxide layers’ formation,and nickel release between superelastic and thermo-activated nickel–titanium archwires

Superelastic (SE) and thermo-activated (TA) nickel–titanium (NiTi) archwires are used in everyday orthodontic practice, based on their acceptable biocompatibility and well-defined shape memory properties. However, the differences in their surface microstructure and cytotoxicity have not been clearly defined, and the standard cytotoxicity tests are too robust to detect small differences in the cytotoxicity of these alloys, all of which can lead to unexpected adverse reactions in some patients. Therefore, we tested the hypothesis that the differences in manufacture and microstructure of commercially available SE and TA archwires may influence their biocompatibility. The archwires were studied as-received and after conditioning for 24 h or 35 days in a cell culture medium under static conditions. All of the tested archwires, including their conditioned medium (CM), were non-cytotoxic for L929 cells, but Rematitan SE (both as received and conditioned) induced the apoptosis of rat thymocytes in a direct contact. In contrast, TruFlex SE and Equire TA increased the proliferation of thymocytes. The cytotoxic effect of Rematitan SE correlated with the higher release of Ni ions in CM, higher concentration of surface Ni and an increased oxygen layer thickness after the conditioning. In conclusion, the apoptosis assay on rat thymocytes, in contrast to the less sensitive standard assay on L929 cells, revealed that Rematitan SE was less cytocompatible compared to other archwires and the effect was most probably associated with a higher exposition of the cells to Ni on the surface of the archwire, due to the formation of unstable oxide layer.     

生物质基碳气凝胶制备及应用研究

生物质材料成本低廉、碳源丰富,是碳气凝胶制备中最经济、环保和可持续性的原料。生物质基碳气凝胶展现出密度低、弹性高、比表面积大和导电性好等优异特性,有望广泛应用于电化学储能器件和吸附净化等领域。综述了生物质基碳气凝胶,如纤维素碳气凝胶、木质素基碳气凝胶、生物质衍生物基碳气凝胶以及碳气凝胶复合结构材料的制备工艺,总结了生物质基碳气凝胶在吸附和电化学等领域的应用研究。最后,分析了大规模制备结构均一和性能优良的生物质基碳气凝胶面临的机遇与挑战。