全文获取类型
收费全文 | 827篇 |
免费 | 33篇 |
国内免费 | 16篇 |
专业分类
电工技术 | 36篇 |
综合类 | 3篇 |
化学工业 | 190篇 |
金属工艺 | 18篇 |
机械仪表 | 29篇 |
建筑科学 | 8篇 |
能源动力 | 40篇 |
轻工业 | 82篇 |
水利工程 | 3篇 |
石油天然气 | 1篇 |
无线电 | 67篇 |
一般工业技术 | 166篇 |
冶金工业 | 68篇 |
原子能技术 | 5篇 |
自动化技术 | 160篇 |
出版年
2024年 | 2篇 |
2023年 | 26篇 |
2022年 | 35篇 |
2021年 | 48篇 |
2020年 | 36篇 |
2019年 | 27篇 |
2018年 | 53篇 |
2017年 | 26篇 |
2016年 | 31篇 |
2015年 | 16篇 |
2014年 | 32篇 |
2013年 | 85篇 |
2012年 | 47篇 |
2011年 | 49篇 |
2010年 | 39篇 |
2009年 | 26篇 |
2008年 | 24篇 |
2007年 | 28篇 |
2006年 | 11篇 |
2005年 | 23篇 |
2004年 | 9篇 |
2003年 | 16篇 |
2002年 | 8篇 |
2001年 | 10篇 |
2000年 | 15篇 |
1999年 | 5篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 18篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 11篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 2篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1976年 | 6篇 |
1970年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有876条查询结果,搜索用时 15 毫秒
21.
M. Jeyakanthan Uma Subramanian R. B. Tangsali 《Journal of Materials Science: Materials in Electronics》2018,29(3):1914-1924
CoWO4/PbWO4 nanocomposites were successfully synthesized at room temperature (RT) by co-precipitation route without using any templates or surfactants and sintered at 600 °C for good crystallization. The sintered samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy and Zeta potential measurements. UV–Visible diffuse reflectance spectroscopy, photoluminescence (PL) and PL lifetime were studied at RT. The results indicate that the composites have two-phase composition: CoWO4 and PbWO4. SEM micrograph and zeta potential measurements reveal particle agglomeration. The intrinsic PL peak emission at 467 nm of CoWO4 nano sample was enhanced upto four times by optimizing the atomic ratio of Pb/Co concentration. The interconnected interface of CoWO4/PbWO4 nanocomposites could have led to increase in number of recombination of electron hole pairs in CoWO4 and enhanced its intrinsic PL emission intensity. The mechanism of enhanced PL emission for the CoWO4/PbWO4 nanocomposites can be attributed to charge transfer between [WO4]2? and [WO6]6? complexes due to intra particle agglomeration leading to possible interface. 相似文献
22.
Ashwini Kumar Dash 《纺织学会志》2019,110(4):614-624
Using weaving technology, possible manipulations can be done so as to derive maximum advantage from the reinforcements towards desired mechanical properties of the composites. Thus with different sets of weaving parameters and tow linear densities, an attempt has been made to investigate tensile, impact and knife penetration performance of different stuffer layers and fibre volume fractions of 3D orthogonal and interlock E-glass fabrics as reinforcements for composite applications. The tensile properties were effectively influenced by warp tow crimp%, number of stuffer tows per unit width of the fabric and fabric assistance. The tow linear density, fabric sett and the number of cross over points play a determining role towards impact energy absorption capacity. The fabric sett along with tow linear densities also play a vital role towards peak energy during knife penetration test. The number of cross over points were found to be least important in the knife penetration results analysis. 相似文献
23.
Pottayil Uma Devi Muralidharan Kannai V. Paulose Jacob Koshy Alathoor D. Damodaran 《Journal of the American Ceramic Society》1991,74(10):2679-2682
The percolation behavior of normal-state thermopower, resistivity, and superconductivity have been studied in YBa2 Cu3 O7-δ ─Ag (YBCO─Ag) composite systems. The normal-state resistivity and thermopower show a percolation threshold at a Ag volume fraction ( V Ag ) of 20% to 30%, whereas the superconducting network shows a threshold at a V Ag of ≅70% to 80%. The results obtained from this study show that the YBCO─Ag composite obtained from Ag2 O and YBCO powders is uniformly distributed with Ag and YBCO remaining as separate phases without changing their characteristics. The measurements of thermopower indicate that the normal-state thermopower and phonon-drag thermopower are affected by the Ag addition. The stability of YBCO is increased when it is in composite form. 相似文献
24.
Barsha Dash Indra Narayan Bhattacharya Bhaskara Venkata Ramanamurthy Raja Kishore Paramguru 《Korean Journal of Chemical Engineering》2011,28(7):1546-1549
An approach to produce molybdenum trioxide from spent hydrodesulfurization (HDS) catalyst, obtained from a petroleum refinery,
is presented here. The spent catalyst was devolatilized at 600 °C so as to make it free from oils, organics and other volatile
species. It was then roasted with sodium carbonate at a temperature of 850 °C for 30 min. The leaching efficiency for 20%
soda roasted sample at 10% pulp density was 99.8%. From the solution molybdenum was precipitated out as ammonium molybdate
at pH 1.0 with HCl and ammonium chloride. This ammonium molybdate was calcined at 750 °C to get MoO3. The product was characterized by XRD. Its purity was determined titrimetrically and by ICP-AES. 相似文献
25.
Nirupama Mallick Shovon Mandal Amit Kumar Singh Moumita Bishai Archana Dash 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2012,87(1):137-145
BACKGROUND: A major bottleneck in microalgal biodiesel production is lipid content, which is often low in microalgal species. The present study examines Chlorella vulgaris as a potential feedstock for biodiesel by identifying and evaluating the relationships between the critical variables that enhance the lipid yield, and characterizes the biodiesel produced for various properties. RESULTS: Factors affecting lipid accumulation in a green microalga, Chlorella vulgaris were examined. Multifactor optimization raised the lipid pool to 55% dry cell weight against 9% control. When C. vulgaris cells pre‐grown in glucose (0.7%)‐supplemented medium were transferred to the optimized condition at the second stage, the lipid yield was boosted to 1974 mg L?1, a value almost 20‐fold higher than for the control. The transesterified C. vulgaris oil showed the presence of ~82% saturated fatty acids, with palmitate and stearate as major components, thus highlighting the oxidative stability of C. vulgaris biodiesel. The fuel properties (density, viscosity, acid value, iodine value, calorific value, cetane index, ash and water contents) are comparable with the international (ASTM and EN) and Indian (IS) biodiesel standards. CONCLUSION: C. vulgaris biomass with 55% lipid content and adequate fuel properties is potentially a renewable feedstock for biodiesel. Copyright © 2011 Society of Chemical Industry 相似文献
26.
Aaron D. Krabill Hao Chen Dr. Sajjad Hussain Dr. Chao Feng Dr. Ammara Abdullah Prof. Chittaranjan Das Dr. Uma K. Aryal Prof. Carol Beth Post Prof. Michael K. Wendt Prof. Paul J. Galardy Prof. Daniel P. Flaherty 《Chembiochem : a European journal of chemical biology》2020,21(5):712-722
The deubiquitinase (DUB) ubiquitin C-terminal hydrolase L1 (UCHL1) is expressed primarily in the central nervous system under normal physiological conditions. However, UCHL1 is overexpressed in various aggressive forms of cancer with strong evidence supporting UCHL1 as an oncogene in lung, glioma, and blood cancers. In particular, the level of UCHL1 expression in these cancers correlates with increased invasiveness and metastatic behavior, as well as poor patient prognosis. Although UCHL1 is considered an oncogene with potential as a therapeutic target, there remains a significant lack of useful small-molecule probes to pharmacologically validate in vivo targeting of the enzyme. Herein, we describe the characterization of a new covalent cyanopyrrolidine-based UCHL1 inhibitory scaffold in biochemical and cellular studies to better understand the utility of this inhibitor in elucidating the role of UCHL1 in cancer biology. 相似文献
27.
Apurv Dash Jürgen Malzbender Robert Vaßen Olivier Guillon Jesus Gonzalez-Julian 《Journal of the American Ceramic Society》2020,103(12):7072-7081
The compressive creep of silicon carbide fiber reinforced Ti3SiC2 MAX phase with both fine and coarse microstructure was investigated in the temperature range of 1000-1300°C. Comparison of only steady-state creep was done to understand the response of fabricated composite materials toward creep deformation. It was demonstrated that the fibers are more effective in reducing the creep rates for the coarse microstructure by an increase in activation energy compared to the variant with a finer microstructure, being partly a result of the enhanced creep rates for the microstructure with larger grain size. Grain boundary sliding along with fiber fracture appears to be the main creep mechanism for most of the tested temperature range. However, there are indications for a changed creep mechanism for the fine microstructure for the lowest testing temperature. Local pores are formed to accommodate differences in strain related to creeping matrix and predominantly elastically deformed fibers during creep. Microstructural analysis was done on the material before and after creep to understand the deformation mechanics. 相似文献
28.
A bio-inspired drug carrier was developed by dual functionalization of chitosan using L-glutamic acid (GA) and phyto-synthesized zinc oxide nanoparticles (ZNPs). A highly porous, three-dimensional network of nanocomposite hydrogel (GA-CHGZ) was obtained upon cross-linking chitosan using biomass-derived dialdehyde cellulose. The hydrogel was optimally loaded with naringenin (NRG) and further characterized using nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and swelling studies. An enhanced NRG loading efficiency of 85.23% was obtained using functionalized hydrogel compared to 52.54% using non-functionalized hydrogel. Delivery studies displayed a maximum release of 69.63% for 1.0 mg/ml of initial NRG concentration at pH 5, which is a highly preferred condition for cancer therapeutics. While ZNPs’ embedment was instrumental in improving the NRG loading and delivery rates, the GA conjugation increased the stability of NRG in the GA-CHGZ, aiding sustained NRG release, which followed a non-Fickian diffusion mechanism with polymer swelling. Antimicrobial potential was explored against Staphylococcus aureus and Trichophyton rubrum strains. The biocompatibility assay using L929 normal cells showed enhanced cell proliferation characteristics for the materials, revealing significant cell viability. The anticancer activity of NRG tested against A431 human skin carcinoma cells increased up to nine-fold with a reduced IC50 value when a functionalized hydrogel was used instead of pure NRG without the nanocomposite carrier. Thus, the bio-functionalized drug–carrier system has a promising application for wound healing and topical skin cancer therapies. 相似文献
29.
This experimental study evaluated the water absorption characteristics of pineapple leaf fiber (PALF)–polyester composites of different fiber content. The degree of water absorption was found to increase with fiber loading. The mechanism of diffusion was analyzed and the effect of fiber loading on the sorption kinetics was studied. The diffusion coefficient was calculated and found to increase with fiber content. Studies were also made to correlate water absorption with the cross‐sectional areas of the specimens. The effects of ageing on the tensile properties and dimensional stability of PALF polyester composites were studied under two different ageing conditions. Ageing studies showed a decrease in tensile strength of the composites. The composite specimens subjected to thermal ageing showed only a slight deterioration in strength. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 503–510, 2004 相似文献
30.