Factors affecting cloud point analysis of palm oleins

Some of the factors affecting cloud point determination of palm oleins are described. These are the type of container used, method of stirring, rate of stirring and bath temperature. The repeatability and reproducibility standard deviations of the method are determined from collaborative trials. Recommendations for the test are made to reduce the large variations among laboratories.     

Stability studies on methyl and ethyl fatty acid esters of sunflowerseed oil

Fatty acid esters, high in linoleic acid, were prepared and stored for long-term engine tests. Storage tests with these esters were undertaken to obtain more information on optimal storage requirements and general stability characteristics. Samples were kept at three temperature levels (20 C, 30 C and fluctuating around 50 C) for a 90-day period and were removed at regular intervals for chemical and physical analysis. The influence of air, temperature, light, TBHQ and contact with mild steel was evaluated by comparing the free fatty acid, peroxide, anisidine, ultraviolet absorption, viscosity and induction periods. A statistical model was used to evaluate the data and to reduce the large number of data points to comparable curves. Storage of esters in contact with air, especially at a temperature above 30 C, resulted in significant increases in peroxide, ultraviolet absorption, free fatty acid, viscosity and anisidine values. Exclusion of air retarded oxidation at all temperature levels. A direct relationship between viscosity increases and oxidation parameters was evident. Exposure to light caused a small increase in the oxidation parameters of esters stored at the highest temperature level. Addition of TBHQ prevented oxidation of samples stored under moderate conditions. Under unfavorable storage conditions the anti-oxidant was no longer effective. Mild steel had very little effect on the oxidation parameters. Only the anisidine values of samples stored at the highest temperature level were slightly increased. Methyl esters performed slightly better than ethyl esters during the storage test. The following practical guidelines for storage of fatty acid ester fuels are: (i) airtight containers should be used; (ii) the storage temperature should be <30 C; (iii) mild steel (rust free) containers may be used, and (iv) TBHQ has a beneficial effect on oxidation stability.     

Performance of combined cobalt—nickel—zirconia and HZSM-5 catalyst systems for carbon monoxide hydrogenation

The synthesis of hydrocarbons via hydrogenation of carbon monoxide was investigated over cobalt—nickel—zirconia catalysts of various compositions in combination with zeolite HZSM-5 in “mixed bed” and “follow bed” arrangements. These combinations resulted in the formation of aromatics in amounts as high as 30-35 wt% under relatively mild operating conditions (1 atm, 250–280°C). Although the olefinicity of C₂ and C₃ fractions in the product stream was higher in the mixed bed compared to the follow bed arrangement, the selectivities to aromatics were comparable in the two bed arrangements. The aromatic selectivity was found to be sensitive to operating conditions. The formation of aromatics was favored at high HZSM-5/metal catalyst ratios, low space velocities and high reaction temperatures. The product distributions obtained using various metal/zeolite bifunctional catalysts have been discussed.     

Semiconductor-insulator structures in the phototargets of vidicons sensitive in the middle infrared region of the spectrum

The kinetics of electronic processes in vidicon phototargets based on semiconductor-insulator structures with a narrow-gap semiconductor is considered taking into account charge drain in the insulator layer and relaxation of the nonequilibrium depletion region in the semiconductor layer. The integration time, threshold sensitivity, and resolution at various intensities of incident radiation are estimated.     

Development of alternative technical systems

This paper considers the integration of alternative technical systems (TS) belonging to a wider class of competing TS, into a supersystem. The paper introduces the notion of alternative TS, shows the peculiarities of their incorporation into a supersystem, reveals the mechanisms used for such incorporation, and shows areas of application for the suggested method.     

Social utility Functions-part II: applications

Social utilities account for agent preferences and, thus, can characterize complex interrelationships, such as cooperation, compromise, negotiation, and altruism, that can exist between agents. Satisficing game theory, which is based on social utilities, offers a framework within which to design sophisticated multiagent systems. Key features of this approach are: a) an N-agent system may be represented by a 2N-dimensional Bayesian network, called a praxeic network; b) the theory accommodates a notion of situational altruism (a willingness to defer to others in a controlled way if so doing would actually benefit others under the condition that others wish to take advantage of such largesse); and c) satisficing games admits a protocol for effective negotiation between agents who, though interested in their own welfare, are also willing to give some deference to others. Three applications are presented. The first two involve well-known two-person games: the Prisoner's Dilemma and the Battle of the Sexes, and the third is a simulated uninhabited aerial vehicle scenario.     

A stochastically optimized adaptive procedure for the location of MAS auxiliary monopoles: the case of electromagnetic scattering by dielectric cylinders

A genetically optimized technique that fully automates the potentially laborious allocation of the auxiliary monopoles for the method of auxiliary sources (MAS) is presented for the problem of electromagnetic (EM) scattering by isotropic dielectric cylinders with various cross sections. The proposed technique uses as input information not only the geometry of the scatterer but also the exciting field and the material properties of the cylinders are implicitly taking part in the optimization procedure. The resulting auxiliary surfaces, where the simulating monopoles are situated, are appropriately adapted to the original boundary surface and the MAS modeling is greatly facilitated. In addition, certain considerations are taken into account in order to avoid undesirable numerical dependencies between the fictitious monopoles. Finally, the accuracy of the numerical method combined with overdetermined systems of equations is examined for isotropic cylinders of various geometries and dielectric characteristics.