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排序方式: 共有1306条查询结果,搜索用时 453 毫秒
41.
Samira Chamyani Alireza Salehirad Nasrin Oroujzadeh Davod Sadeghi Fateh 《Ceramics International》2018,44(7):7754-7760
Due to importance and wide applications, CoCr2O4 ceramic pigment nanoparticles were synthesized via low-temperature solution combustion route by different fuels including ethylenediamine/oxalic acid, ethylenediamine/citric acid, oxalic acid/citric acid and ethylenediamine/oxalic acid/citric acid. Physicochemical properties of the synthesized samples were determined by different techniques such as fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDX) and color/optical properties were evaluated based on CIELAB system by spectrophotometer. Moreover, thermodynamic considerations of combustion reactions for CoCr2O4 nanopigments formation in terms of calculated adiabatic flame temperature and enthalpy of combustion reaction were studied. The Comparison of results and data showed that cobalt chromite pigment nanoparticles synthesized by using ethylenediamine/citric acid and ethylenediamine/oxalic acid/citric acid fuels exhibited higher purity, smaller crystallite size and lower degree agglomeration. 相似文献
42.
Ali Hemmatifar Mohammad Said Saidi Arman Sadeghi Mahdi Sani 《Microfluidics and nanofluidics》2013,14(1-2):265-276
Dielectrophoresis (DEP) is an electrokinetic phenomenon which is used for manipulating micro- and nanoparticles in micron-sized devices with high sensitivity. In recent years, electrode-based DEP by patterning narrow oblique electrodes in microchannels has been used for particle manipulation. In this theoretic study, a microchannel with triangular electrodes is presented and a detailed comparison with oblique electrodes is made. For each shape, the behavior of particles is compared for three different configurations of applied voltages. Electric field, resultant DEP force, and particle trajectories for configurations are computed by means of Rayan native code. The separation efficiency of the two systems is assessed and compared afterward. The results demonstrate higher lateral DEP force, responsible for particle separation, distributed wider across the channel width for triangular shape electrodes in comparison with the oblique ones. The proposed electrode shape also shows the ability of particle separation by attracting negative DEP particles to or propelling them from the flow centerline, according to the configuration of applied voltages. A major deficiency of the oblique electrodes, which is the streamwise variation of the lateral DEP force direction near the electrodes, is also eliminated in the proposed electrode shape. In addition, with a proper voltages configuration, the triangular electrodes require lower voltages for particle focusing in comparison with the oblique ones. 相似文献
43.
44.
Vahid Ghasemzadeh-mohammadi Bahman Zamani Maryam Afsharpour Abdorreza Mohammadi 《Food science and biotechnology》2017,26(5):1281-1290
In this research, optimal conditions for extraction of caffeine and polyphenols were established from Iranian green tea leaves. In the first step, caffeine was extracted with efficacy about 86% versed to 4.5% of EGC + EGCG. The EGCG + EGC was extracted from partially decaffeinated green tea leaves through microwave-assisted extraction (MAE) and ultrasound-assisted extraction (USE) with efficiency levels of 95 and 85%, respectively. The best results for the MAE process were obtained with 7.8 min and three number of extraction cycles and for the USE process were as followed: time 57 min, temperature 65 °C, and the number of extraction cycles 3. The total phenol content values at the best conditions of MAE and the USE processes were 125 ± 5 and 96 ± 6 mg gallic acid/g DW. The 50% inhibition (IC50) on 1,1-diphenyl-2-picrylhydrazyl (DPPH) were 56 and 66 mg/g of phenol for the MAE and USE processes. 相似文献
45.
Ahmed Jawad Qureshi Jean-Yves Dantan Vahid Sabri Paul Beaucaire Nicolas Gayton 《Computer aided design》2012,44(2):132-142
Tolerancing decisions can profoundly impact the quality and cost of the mechanism. To evaluate the impact of tolerance on mechanism quality, designers need to simulate the influences of tolerances with respect to the functional requirements. This paper proposes a mathematical formulation of tolerance analysis which integrates the notion of quantifier: “For allacceptable deviations (deviations which are inside tolerances),there existsa gap configurationsuch asthe assembly requirements and the behavior constraints are verified” & “For allacceptable deviations (deviations which are inside tolerances), andfor alladmissible gap configurations, the assembly and functional requirements and the behavior constraints are verified”. The quantifiers provide a univocal expression of the condition corresponding to a geometrical product requirement. This opens a wide area for research in tolerance analysis. To solve the mechanical problem, an approach based on optimization is proposed. Monte Carlo simulation is implemented for the statistical analysis. The proposed approach is tested on an over-constrained mechanism. 相似文献
46.
Nickel–phosphorus alloys were codeposited with boron carbide particles. Two compositions of nickel-phosphorus, one presenting a low phosphorus content in the order of 4% wt. and another one presenting a high phosphorus content of about 12% wt., were deposited from modified Watts nickel electrolytes using both direct and pulse plating. A strong influence of the deposition method was observed on the phosphorus content in the matrix and on the quantity of codeposited particles. Pulse plating was found to significantly increase both of them. Nucleation of the pure nickel–phosphorus alloy and of the codeposit were studied using chronoamperometry and AFM in potentiostatic mode. An instantaneous nucleation mechanism was evidenced on iron and gold substrates. Microhardness was measured and linked to the phosphorous and particle contents. 相似文献
47.
Synergistic reinforcement of NBR by hybrid filler system including organoclay and nano‐CaCO3
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Rubber nanocomposites containing one type of nanofiller are common and are widely established in the research field. In this study, nitrile rubber (NBR) based ternary nanocomposites containing modified silicate (Cloisite 30B) and also nano‐calcium carbonate (nano‐CaCO3) were prepared using a laboratory internal mixer (simple melt mixing). Effects of the hybrid filler system (filler phase have two kind of fillers) on the cure rheometry, morphology, swelling, and mechanical and dynamic–mechanical properties of the NBR were investigated. Concentration of nano‐CaCO3 [0, 5, 10, and 15 parts per one hundred parts of rubber by weight (phr)] and organoclay (0, 3, and 6 phr) in NBR was varied. The microstructure and homogeneity of the compounds were confirmed by studying the dispersion of nanoparticles in NBR via X‐ray diffraction and field emission scanning electron microscopy. Based on the results of morphology and mechanical properties, the dual‐filler phase nanocomposites (hybrid nanocomposite) have higher performance in comparison with single‐filler phase nanocomposites. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42744. 相似文献
48.
Arman Sadeghi 《American Institute of Chemical Engineers》2016,62(11):4119-4130
A 3D analytical solution is presented for the problem of mass transport in a T‐sensor by taking the axial diffusion effects into account. The solution methodology is based on an eigenfunction expansion of the solute concentration and enjoys the variational calculus for the solution of the associated eigenvalue problem. The method is capable of handling a mixed electroosmotic and pressure‐driven velocity profile and is executed assuming a rectangular channel cross‐section although it can be easily extended to more complex geometries. Two simplified models, one based on a uniform velocity profile, valid for the channel half height to Debye length ratios of above 100, and the other based on a depthwise averaging of the species concentration to be used for cases in which the channel width to height ratio is above 5 are also presented. As a part of the latter, expressions are derived for the Taylor dispersion coefficient of the mixed flow in a slit microconduit. The most interesting finding of this study is that, when the diffusion mechanism significantly contributes to the axial movement of the species, the well‐known heterogeneous mass transport evolves into a nearly uniform pattern in the depthwise direction and the mixing length noticeably increases. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4119–4130, 2016 相似文献
49.
Natural Palm Olein Polyol as a Replacement for Polyether Polyols in Viscoelastic Polyurethane Foam
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H. Nurul ‘Ain T. I. Tuan Noor Maznee M. N. Norhayati M. A. Mohd Noor S. Adnan P. P. Kosheela Devi S. Mohd Norhisham S. K. Yeong A. H. Hazimah Irma Campara Vahid Sendijarevic Ibrahim Sendijarevic 《Journal of the American Oil Chemists' Society》2016,93(7):983-993
The impact of replacing three polyether polyols with different levels of a single palm olein‐based natural oil polyol (NOP) was systematically correlated with the changes in foaming reactivity, cell structure, physico‐mechanical properties, and morphology of viscoelastic (VE) foams. The data show that replacing the polyether polyols with the NOP slightly increased the rate of the foaming reactivity. Increasing the NOP content resulted in increased cell size and cells remained fully open. Increased NOP content contributed to higher load bearing properties of VE foam, which can be attributed to higher functionality of NOP compared to polyether polyols. Addition of the NOP slightly increased the resilience of the foams, however, the hysteresis which is the measure of energy absorption remained mostly unaffected. Age properties, characterized by dry and humid compression sets, were mostly unaffected by the replacement of the polyether polyol with the NOP. The addition of NOP did not impact the morphology of the VE foam polymer matrix, which appears to retain a low degree of hard and soft segment domain separation. Overall, the results demonstrate a feasibility that the NOP can be used to partially replace the polyether polyols in VE polyurethane foams without significant impact on the functional performance. 相似文献
50.
Urethane‐forming reaction kinetics and catalysis of model palm olein polyols: Quantified impact of primary and secondary hydroxyls
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Tuan Noor Maznee Tuan Ismail Kosheela Devi Poo Palam Zailan Bin Abu Bakar Hoong Seng Soi Yeong Shoot Kian Hazimah Abu Hassan Christi Schiffman Aisa Sendijarevic Vahid Sendijarevic Ibrahim Sendijarevic 《应用聚合物科学杂志》2016,133(5)
Model palm olein natural oil polyols (NOPs) with varying ratios of primary to secondary hydroxyls were synthesized, characterized, and evaluated in reaction kinetics study with isocyanate in formation of polyurethanes. Reaction rate constants and activation energies associated with primary and secondary hydroxyls of NOPs were quantified. The kinetic study in toluene shows that the NOP containing primary hydroxyls have three times higher reaction rate constants in noncatalyzed reaction with 4,4′‐diphenylmethane diisocyanate (4,4′‐MDI) compared to the model NOP containing only secondary hydroxyls, which is associated with higher activation energy of secondary hydroxyls. However, the difference in reaction rate constants of primary and secondary hydroxyls in NOPs diminished in the reactions catalyzed with dibutyltin dilaurate. Bulk polymerization reaction confirms the kinetics results in toluene, showing that the model NOP containing primary hydroxyls reached gel time at a faster rate. Evaluation of elastomers from bulk polymerization shows low degree of phase separation of hard and soft segments for elastomers based on the model NOPs. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42955. 相似文献