(R/S)‐BINOL‐α‐Phosphoryloxy Enecarbamate‐Mediated and (R/S)‐Titanium(IV) BINOLates‐Catalyzed Enantioselective Intramolecular Heck/Aza‐Diels–Alder Cycloaddition (IHADA): An Expedient Methodology

An (R/S)‐titanium(IV) BINOLate‐catalyzed highly enantioselective intramolecular Heck/aza‐Diels–Alder cycloaddition (IHADA) cascade was developed to prepare tetrahydropyridoindoles (tHPs) and octahydropyrazinopyridoindoles (oHPPs) from in situ generated (R/S)‐BINOL α‐phosphoryloxy carbamate ( αPPC2 ) in one pot. Chiral cooperativity between (R/S)‐αPPC2 and (R/S)‐titanium(IV) BINOLate was observed and successfully utilized for the construction of various tHPs (7 examples) and oHPPs (17 examples).

     

Crosstalk suppression in networked resistive sensor arrays using virtual ground technique

In 2D resistive sensor arrays, the interconnections are reduced considerably by sharing rows and columns among various sensor elements in such a way that one end of each sensor is connected to a row node and other end connected to a column node. This scheme results in total N?+?M interconnections for N?×?M array of sensors. Thus, it simplifies the interconnect complexity but suffers from the crosstalk problem among its elements. We experimentally demonstrate that this problem can be overcome by putting all the row nodes at virtually equal potential using virtual ground of high gain operational amplifiers in negative feedback. Although it requires large number of opamps, it solves the crosstalk problem to a large extent. Additionally, we get the response of all the sensors lying in a column simultaneously, resulting in a faster scanning capability. By performing lock-in-amplifier based measurements on a light dependent resistor at a randomly selected location in a 4?×?4 array of otherwise fixed valued resistors, we have shown that the technique can provide 86?dB crosstalk suppression even with a simple opamp. Finally, we demonstrate the circuit implementation of this technique for a 16?×?16 imaging array of light dependent resistors.     

Letter to the Editor: Reply to the Comments on “Water Solubility of Cloud-Active Aerosols”

Please click here to find the Letter to the Editor to which this Response refers: http://dx.doi.org/10.1080/02786828508959062     

PSO-based learning of sub-band adaptive thresholding function for image denoising

In this paper, a new computationally efficient approach has been proposed for denoising the images which are corrupted by Gaussian noise. In this approach, relatively recent category of stochastic global optimization technique i.e., particle swarm optimization (PSO) technique have been proposed for learning the parameters of adaptive thresholding function required for optimum performance. The proposed PSO-based denoising approach not only speeds up the optimization but also improves the performance in comparison with wavelet transform-based thresholding neural network (WT-TNN) approach. The results obtained shows better edge preservation performance with bior6.8 wavelet filter when compared to db8 wavelet filter. Further, problem of dependency of learning time on initial value of thresholding parameters and noise level in the image have been sorted out in the proposed approach.     

Biomass-based energy fuel through biochemical routes: A review

Energy demand is increasing continuously due to rapid growth in population and industrialization development. The development of energy sources is not keeping pace with spiraling consumption. Even developed countries are not able to compensate even after increasing the energy production multifold. The major energy demand is provided from the conventional energy sources such as coal, oil, natural gas, etc. Two major problems, which every country is facing with these conventional fuels, are depletion of fossil fuels and deterioration of environment.The present review article aims to highlight various biochemical processes for conversion of biomass into biological hydrogen gas and ethanol. The present discussion focuses on hydrogen production through various routes viz. fermentative, photosynthesis and biological water gas shift reaction. In addition, emphasis has been laid on ethanol as biomass-based energy fuel. The discussion has been focused on the technology for ethanol production from various biomass sources such as molasses, lignocellulosic feedstock and starch. Various biochemical processes and their major steps involved during the ethanol production from biomass have been discussed in detail.     

Experimental studies on rewetting of hot vertical annular channel

Studies on the rewetting behaviour of hot vertical annular channels are of interest in the context of emergency core cooling in nuclear reactors following LOCA. Experimental studies were carried out to study the rewetting behaviour of a hot vertical annular channel, with hot inner tube, for bottom flooding and top flow rewetting conditions. The length of the inner tube of the test section was 3030 mm for bottom flooding rewetting experiments and 2630 mm for top flow rewetting experiments. The tube was made of stainless steel. Experiments were conducted for water flow rates in the annulus upto 7 lpm (11.7×10⁻⁵ m³ s⁻¹). The initial surface temperature of the inner tube was varied from 200 to 500°C. The experimental studies show that for a given initial surface temperature of the tube, the rewetting velocity increases with an increase in flow rate of water and it decreases with an increase in the initial surface temperature for a given water flow rate. For a given water flow rate and initial surface temperature, the rewetting velocity is higher in the case of rewetting under bottom flooding conditions as compared to that in the case of rewetting under top flow conditions. These conclusions agree with the conclusions reported in the earlier literature. Using the experimental data of the present work, correlations for bottom flooding and top flow rewetting velocities are developed.     

The flexible PEI composites

The present study investigates the compatibilizing effect of polyphosphazene on the blends of poly(ether imide) (PEI) and thermotropic liquid crystalline polymer (Vectra‐B). FTIR study showed that there was a partial interaction or chemical reaction between the PEI and LCP in the presence of compatibilizer. Polyphosphazene is compatibilized with both PEI and LCP, which was evident from DMA results. From the X‐ray diffraction study, it has been observed that the crystalline structure of PEI–LCP blends was increased with the addition of compatibilizer. The thermal study of the composites has been studied by DTA/thermo gravimetric analyses (TGA). TGA thermograms showed an increase in decomposition temperature of PEI–LCP blends in the presence of compatibilizer. Measurement of the tensile properties showed an increase in the elongation as well as enhanced modulus and strength. From SEM micrographs of tensile fractured surfaces, the addition of compatibilizer to PEI–LCP blends was found to increase the adhesion between the matrix and the dispersed phase. POLYM. COMPOS., 27:533–538, 2006. © 2006 Society of Plastics Engineers     

A new version of AAKF (Reduced Tensor Matrix Elements) adapted to spectroscopic notation

Title of program: REDUCED TENSOR MATRIX ELEMENTS 2 Catalogue number: AAKP Program obtainable from: CPC Program Library, Queen's University of Belfast N. Ireland (see application form in this issue) Computer: Installation: IBM 360/75 University of Waterloo, Waterloo, Ont. Canada Operating system: OS/360 HASP II Programming languages used: FORTRAN IV High speed store required: 102 K bytes No. of bits per byte: 8 Overlay structure: None Other peripherals used: Card reader, line printer No. of cards in combined program and test deck: 1524 Card punching code: EBCDIC 029CPC Library subprograms used:

     

179.

Switching characteristics of an optically controlled GaAs-MESFET   总被引：1，自引：0，他引：1  

Chakrabarti  P. Shrestha  S.K. Srivastava  A. Saxena  D. 《Microwave Theory and Techniques》1994,42(3):365-375

The switching characteristics of an optically controlled Metal Semiconductor Field Effect Transistor (MESFET), popularly known as Optical Field Effect Transistor (OPFET), have been derived analytically. The limitations of the existing model have been overcome in the present model. Calculations are being carried out to examine the effect of illumination on the current-voltage characteristics, drain-to-source capacitance (C_dc), internal gate-to-source capacitance (C_gs), drain-to-source resistance (R_ds), the transconductance (g_m), the input RC time constant and the cutoff frequency (f_T) of a GaAs-MESFET. The variations of these parameters with gate length L_g and the doping concentration N_d have also been studied in dark and illuminated conditions. The results of numerical calculations show that there is an overall decrease in the input RC time constant of the device in the illuminated condition arising from the internal gate-to-source capacitance and the transconductance. The results obtained on the basis of the model show a close agreement with the reported experimental findings. The simple model presented here is fairly accurate and can be used as a basic tool for circuit simulation purposes     

180.

Effect of Halloysite Nanotubes as Novel Nanofiller on Peroxide- and Electron Beam Radiation-Initiated Polyphosphazene Elastomer     

Mrinal Kanti Kundu  Goutam Hatui  Vineeta Nigam  Arvind Kumar Saxena 《Polymer-Plastics Technology and Engineering》2015,54(7):691-702

A tubelike, naturally occurring halloysite clay mineral (HNTs) incorporated polyphosphazene (PPZ) elastomeric nanocomposites had been electron beam radiated and thermally treated for certain applications. To improve the dispersion of raw HNTs (H), an organosilane modifier had been exploited. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) technique were utilized for plausible interaction and intercalation. The efficiency of electron beam radiation over chemical initiation for intra and inter chain network formation within the resin was substantiated through oil and solvent resistance studies. Effective delay in mass transport as compared to the virgin elastomer was observed through thermal analysis.     

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Cat. numbers	Titles	Refs. in C.P.C.
ACQB	P SHELL CFP	1 (1969) 15
ACRN	A NEW D SHELL CFP	6 (1973) 88
AAGD	NJSYM	1 (1970) 241, 2 (1971) 173
AAGD0001	ADAPT NJSYM FOR WEIGHTS		2 (1971) 180
AAGD0002		ADAPT TO INTEGER ARITHMETIC	5 (1973) 161

Switching characteristics of an optically controlled GaAs-MESFET

The switching characteristics of an optically controlled Metal Semiconductor Field Effect Transistor (MESFET), popularly known as Optical Field Effect Transistor (OPFET), have been derived analytically. The limitations of the existing model have been overcome in the present model. Calculations are being carried out to examine the effect of illumination on the current-voltage characteristics, drain-to-source capacitance (C_dc), internal gate-to-source capacitance (C_gs), drain-to-source resistance (R_ds), the transconductance (g_m), the input RC time constant and the cutoff frequency (f_T) of a GaAs-MESFET. The variations of these parameters with gate length L_g and the doping concentration N_d have also been studied in dark and illuminated conditions. The results of numerical calculations show that there is an overall decrease in the input RC time constant of the device in the illuminated condition arising from the internal gate-to-source capacitance and the transconductance. The results obtained on the basis of the model show a close agreement with the reported experimental findings. The simple model presented here is fairly accurate and can be used as a basic tool for circuit simulation purposes     

Effect of Halloysite Nanotubes as Novel Nanofiller on Peroxide- and Electron Beam Radiation-Initiated Polyphosphazene Elastomer

A tubelike, naturally occurring halloysite clay mineral (HNTs) incorporated polyphosphazene (PPZ) elastomeric nanocomposites had been electron beam radiated and thermally treated for certain applications. To improve the dispersion of raw HNTs (H), an organosilane modifier had been exploited. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) technique were utilized for plausible interaction and intercalation. The efficiency of electron beam radiation over chemical initiation for intra and inter chain network formation within the resin was substantiated through oil and solvent resistance studies. Effective delay in mass transport as compared to the virgin elastomer was observed through thermal analysis.