Greenhouse gases mitigation by CO<Subscript>2</Subscript> reforming of methane to hydrogen-rich syngas using praseodymium oxide supported cobalt catalyst

This study focuses on the potential of hydrogen-rich syngas production by CO₂ reforming of methane over Co/Pr₂O₃ catalyst. The Co/Pr₂O₃ catalyst was synthesized via wet-impregnation method and characterized for physicochemical properties by TGA, XRD, BET, H₂-TPR, FESEM, EDX, and FTIR. The CO₂ reforming of methane over the as-synthesized catalyst was studied in a tubular stainless steel fixed-bed reactor at feed ratio ranged 0.1–1.0, temperature ranged 923–1023 K, and gas hourly space velocity (GHSV) of 30,000 h^?1 under atmospheric pressure condition. The catalyst activity studies showed that the increase in the reaction temperature from 923 to 1023 K and feed ratio from 0.1 to 1.0 resulted in a corresponding increase in the reactant’s conversion and the product’s yields. At 1023 K and feed ratio of 1.0, the activity of the Co/Pr₂O₃ catalyst climaxed with CH₄ and CO₂ conversions of 41.49 and 42.36 %. Moreover, the catalyst activity at 1023 K and feed ratio of 1.0 resulted in the production of H₂ and CO yields of 40.7 and 40.90 %, respectively. The syngas produced was estimated to have H₂:CO ratio of 0.995, making it suitable as chemical building blocks for the production of oxygenated fuel and other value-added chemicals. The used Co/Pr₂O₃ catalyst which was characterized by TPO, XRD, and SEM-EDX show some evidence of carbon formation and deposition on its surface.     

Tennessee's failed managed care program for mental health and substance abuse services

In July 1996, Tennessee initiated a managed mental health and substance abuse program called TennCare Partners. This publicly funded "carve-out" experiment started chaotically and soon deteriorated into a crisis. Many patients did not receive care or lost continuity of care, and the traditional "safety net" mental health system nearly disintegrated. This qualitative case study sought to ascertain the impact of the TennCare Partners program. It points out that the program's difficulties stemmed directly from a flawed design that spread funds previously earmarked for severely mentally ill patients across the entire Medicaid population. States contemplating similar reforms should strive to protect vulnerable patients by risk-adjusting capitation payments and by focusing resources on care for severely mentally ill persons. States should also minimize program complexity and ensure the accountability of managed care networks for their patients' behavioral health care needs.     

Protein kinase C modulates estrogen receptors in differentiated osteoblastic cells in vitro

Ventriculo-peritoneal shunts (VPS) are the most frequent operative procedures used to treat hydrocephalic children. Abdominal complications of VPS are now a rare event; however, their frequency varies from 5% to 47% according to reports. Anything that causes an obstruction or impediment of the VP derivation system will lead to intracranial hypertension, which requires immediate surgery. From 1985 to 1995 at the Division of Pediatric Surgery of the Federico II University of Naples, ten laparoscopies were performed in ten children with VPS complications. Cerebrospinal fluid pseudocysts were found in four infants. There was one case of abdominal wall perforation by the tip of the catheter at the umbilical level, two bowel obstructions, and one catheter was lost in the abdominal cavity. Finally, two children had malfunctioning of the peritoneal limb of the catheter. The laparoscopic technique was curative in all ten cases, thus avoiding a conventional laparotomy and the consequent risk of adhesions, which could cause further complications.     

Pseudo software: A mediating instrument for modeling software requirements

A new synthesis of software requirements models called pseudo software is proposed with the aim to cut requirements-related errors. Pseudo software achieves this aim by serving as a mediating instrument to empower stakeholders to participate in requirements elicitation and validation through model construction and manipulation, and to provide guidance to the development team to correctly interpret the requirements in the downstream development activities. Pseudo software obtains its traits as a mediating instrument through the choice of requirements information bits and the use of multimodal representations with tool support to integrate the requirements. Using historical data of fifty projects in the enterprise computing domain, pseudo software is shown to effectively cut the requirements-related errors committed by both the customer and the development team.     

Weight determination in the cross-efficiency evaluation

A neutral data envelopment analysis (DEA) model for cross-efficiency evaluation was recently proposed by Wang and Chin [Wang and Chin (2010b). A neutral DEA model for cross-efficiency evaluation and its extension. Expert Systems with Applications, 37(5), 3666–3675], which maximinimizes the relative efficiency of each output and effectively reduces the number of zero weights of outputs. Since a large number of zero weights may still exist among inputs, this paper proposes a simultaneously input- and output-oriented weight determination DEA model for the cross-efficiency evaluation. The new DEA model proves to reduce the number of zero weights for both inputs and outputs very significantly, as illustrated by numerical examples. The weights determined by the new DEA model are neutral, neither aggressive nor benevolent.     

An effective 3-in-1 keyword search method over heterogeneous data sources

Conventional keyword search engines are restricted to a given data model and cannot easily adapt to unstructured, semi-structured or structured data. In this paper, we propose an efficient and adaptive keyword search method, called EASE, for indexing and querying large collections of heterogeneous data. To achieve high efficiency in processing keyword queries, we first model unstructured, semi-structured and structured data as graphs, and then summarize the graphs and construct graph indices instead of using traditional inverted indices. We propose an extended inverted index to facilitate keyword-based search, and present a novel ranking mechanism for enhancing search effectiveness. We have conducted an extensive experimental study using real datasets, and the results show that EASE achieves both high search efficiency and high accuracy, and outperforms the existing approaches significantly.     

Technical importance ratings in fuzzy QFD by integrating fuzzy normalization and fuzzy weighted average

Fuzzy quality function deployment (QFD) has been extensively used for translating customer requirements (CRs) into product design requirements (DRs) in fuzzy environments. Existing approaches, however, for rating technical importance of DRs in fuzzy environments are found problematic, either incorrect or inappropriate. This paper investigates how the technical importance of DRs can be correctly rated in fuzzy environments. A pair of nonlinear programming models and two equivalent pairs of linear programming models are developed, respectively, to rate the technical importance of DRs. The developed models are examined and illustrated with two numerical examples.     

A 1-Local Asymptotic 13/9-Competitive Algorithm for Multicoloring Hexagonal Graphs

In the frequency allocation problem, we are given a mobile telephone network, whose geographical coverage area is divided into cells, wherein phone calls are serviced by assigning frequencies to them so that no two calls emanating from the same or neighboring cells are assigned the same frequency. The problem is to use the frequencies efficiently, i.e., minimize the span of frequencies used. The frequency allocation problem can be regarded as a multicoloring problem on a weighted hexagonal graph. In this paper, we give a 1-local asymptotic 4/3-competitive distributed algorithm for multicoloring a triangle-free hexagonal graph, which is a special case of hexagonal graph. Based on this result, we then propose a 1-local asymptotic13/9-competitive algorithm for multicoloring the (general-case) hexagonal graph, thereby improving the previous 1-local 3/2-competitive algorithm. A preliminary version of this paper appeared in the Proceedings of the 13th Annual International Computing and Combinatorics Conference (COCOON 2007), LNCS 4598, pp. 526–536. Y. Zhang research was supported by European Regional Development Fund (ERDF). F.Y.L. Chin research was supported by Hong Kong RGC Grant HKU-7113/07E. H. Zhu research was supported by National Natural Science Fund (grant #60496321).     

Failure mode and effects analysis using a group-based evidential reasoning approach

Failure mode and effects analysis (FMEA) is a methodology to evaluate a system, design, process or service for possible ways in which failures (problems, errors, risks and concerns) can occur. It is a group decision function and cannot be done on an individual basis. The FMEA team often demonstrates different opinions and knowledge from one team member to another and produces different types of assessment information such as complete and incomplete, precise and imprecise and known and unknown because of its cross-functional and multidisciplinary nature. These different types of information are very difficult to incorporate into the FMEA by the traditional risk priority number (RPN) model and fuzzy rule-based approximate reasoning methodologies. In this paper we present an FMEA using the evidential reasoning (ER) approach, a newly developed methodology for multiple attribute decision analysis. The proposed FMEA is then illustrated with an application to a fishing vessel. As is illustrated by the numerical example, the proposed FMEA can well capture FMEA team members’ diversity opinions and prioritize failure modes under different types of uncertainties.