Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

High temperature polymerization of propylene catalyzed by MgCl2‐supported Ziegler–Natta catalyst with various cocatalysts

Four cocatalysts, referred to as ethylaluminoxanes, were synthesized by the reaction between triethylaluminium (AIEt₃) and water under various molar ratios of H₂O/Al at ?78°C. Aluminoxanes were used as cocatalysts for a MgCl₂‐supported Ziegler–Natta catalyst for propylene polymerization at temperatures ranging from 70 to 100°C. When the polymerization was activated by AlEt₃, the activity as well as the molecular weight and isotacticity of the resulting polymer gradually dropped as the temperature varied from 70 to 100°C. When ethylaluminoxane was employed as the cocatalyst, good activity and high molecular weight and isotacticity were obtained at 100°C. Furthermore, when the cocatalyst varied from AlEt₃ to ethylaluminoxane, the atactic fraction and polymer fraction with moderate isotacticity decreased and the high isotactic fraction slightly increased, which indicated that the variation of the cocatalyst significantly affects the isospecificity of active sites. It was suggested that the reactivity of the Al‐Et group and the size of the cocatalyst were correlated to the performance of the Ziegler–Natta catalyst at different temperatures. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1978–1982, 2006     

基于数据密度的半监督自训练分类算法

在实际的分类任务中,无标记样本数量充足而有标记样本数量稀少的情况经常出现,目前处理这种情况的常用方法是半监督自训练分类算法。提出了一种基于数据密度的半监督自训练分类算法,该算法首先依据数据的密度对数据集进行划分,从而确定数据的空间结构;然后再按照数据的空间结构对分类器进行自训练的迭代,最终得到一个新的分类器。在UCI中6个数据集上的实验结果表明,与三种监督学习算法以及其分别对应的自训练版本相比,提出的算法分类效果更好。     

熔融石英陶瓷的性能及其应用

介绍了石英陶瓷的性能特点、制备过程及应用领域     

[Cu_2(Gly—GlyO)_2(OH)_2(4,4—bpy)]·9H_2O配合物合成、晶体结构研究

采用Gly—GlyOH,4,4＇—联吡啶与Cu(NO_3)_2·H_2O在二次水溶液中反应,合成出以4,4＇—bpy为中继基,Gly—Glyo为螯环新型双核铜配合物。经X射线单晶结构分析确定该配合物品体的化学结构式:[(H_2NCH_2CONHCH_2COO) Cu(OH) (C_(10)H_8N_2)Cu(OH) (H_2NCH_2CONHCH_2COO)]·9H_2O.晶体属于三斜晶系,P_空间群,晶胞参数a=1.1412nm,b=1.2298nm,C=1.4269nm,α=113.82°,β=101.91°,y=103.64°,V=1.6747nm~3,Z=2。衍射数据是在Nicolet XRD R3型四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,最终一致性因子R值为0.068,RW值为0.057。     

新型聚丙烯接枝物的制备及应用

为制备强韧的共混材料,利用熔融接枝法研制了含有两种接技单体的新型聚丙烯接枝物,讨论了第二单体在接枝过程中的作用,并将其应用于尼龙6/聚丙烯(PA6/PP)共混体系,获得了使分散相粒径更细小、界面更模糊的增容效果。     

Stochastic modeling of segregation in a motionless mixer

The mixing of particles with different characteristics is generally accompanied by segregation which prevents the particles from attaining the randomly mixed state. A discrete steady-state Markov chain model was employed to model the axial segregation of solid particles in a motionless mixer. Three systems containing particles of different sizes and/or densities were studied. One step transition probabilities of the model were experimentally determined. The model can predict the concentration profiles, the degrees of mixedness, and the equilibrium states of these particle systems blended by passing the particles through a motionless mixer. Experimental results are in good agreement with those predicted from the model.     

Multivariate statistical analysis of solids mixing

The applicability of multivariate statistics to the analysis of mixing processes and mixtures of multicomponent solid particles in a drum mixer has been successfully demonstrated. The applications include (1) test of sampling techniques, (2) test of the completely random state, (3) test of the completely segregated state, and (4) definition of a mixing index for a multicomponent mixture.