Structure/property relationships in sintered and thermally sprayed WC-Co

Thermally sprayed WC-Co is widely used as a wear-resistant coating for a variety of applications. Although it is well established that thermal spray processes significantly affect chemistry, microstructure, and the phase distribution of WC-Co coatings, little is known about how these changes influence wear resistance. In this study, the microstructure and wear behavior of sintered and thermally sprayed WC-Co materials are examined. Powders of WC-12 wt% Co and WC-17 wt% Co were pressed and sintered, as well as thermally sprayed by high-velocity oxy-fuel (HVOF), air plasma spray (APS), and vacuum plasma spray (VPS) techniques. Results indicated considerable differences in the resulting microstructures, mechanical properties, and wear resistance. The thermally sprayed coatings showed anisotropic fracture toughness, whereas the sintered materials did not. It was also shown that a combined mechanical property/microstructure parameter, based on considerations of indentation fracture mechanisms, can be used in most cases to describe abrasive and erosive wear resistance of thermally sprayed WC-Co materials as follows: Wear resistance a whereK _ic is the indentation fracture toughness,H is hardness, andV ^Co _f is the volume fraction of cobalt. This relationship provides a means for assessing wear resistance of WC-Co coatings intended for industrial applications requiring abrasion and/or erosion resistance.     

Protecting Business Secrets in an EDI/CALS Environment

ABSTRACT

Communicating with confidential data requires special attention in a mobile agents environment, especially when the other hosts must be prevented from eavesdropping on the communication. We propose a communication model for secured communication between the agents belonging to publishers and consumers data. Confidentiality is ensured using our on-the-fly encryption-decryption sequence using ElGamal system to directly convert the message or plaintext into one that is encrypted directly with the public key of consumer. The scheme ensures that the data possessed by the agents is secured at all times when it is executing at any untrusted host. Our minimal implementation of the model with Aglets agent platform gives the first faithful picture of the happenings in the model. Finally, we also explain how the homomorphic property of ElGamal scheme can be integrated with our model for a Web-based application such as voting involving multiple agents.     

Application of the Soil and Water Assessment Tool for six watersheds of Lake Erie: Model parameterization and calibration

The Soil and Water Assessment Tool (SWAT), a physically-based watershed-scale model, holds promise as a means to predict tributary sediment and nutrient loads to the Laurentian Great Lakes. In the present study, model performance is compared across six watersheds draining into Lake Erie to determine the applicability of SWAT to watersheds of differing characteristics. After initial model parameterization, the Huron, Raisin, Maumee, Sandusky, Cuyahoga, and Grand SWAT models were calibrated (1998-2001) and confirmed, or validated (2002-2005), individually for stream water discharge, sediment loads, and nutrient loads (total P, soluble reactive P, total N, and nitrate) based on available datasets. SWAT effectively predicted hydrology and sediments across a range of watershed characteristics. SWAT estimation of nutrient loads was weaker although still satisfactory at least two-thirds of the time across all nutrient parameters and watersheds. SWAT model performance was most satisfactory in agricultural and forested watersheds, and was less so in urbanized settings. Model performance was influenced by the availability of observational data with high sampling frequency and long duration for calibration and confirmation evaluation. In some instances, it appeared that parameter adjustments that improved calibration of hydrology negatively affected subsequent sediment and nutrient calibration, suggesting trade-offs in calibrating for hydrologic vs. water quality model performance. Despite these considerations, SWAT accurately predicted average stream discharge, sediment loads, and nutrient loads for the Raisin, Maumee, Sandusky, and Grand watersheds such that future use of these SWAT models for various scenario testing is reasonable and warranted.     

Avoiding semantic and temporal gaps in developing software intensive systems

Development of software intensive systems (systems) in practice involves a series of self-contained phases for the lifecycle of a system. Semantic and temporal gaps, which occur among phases and among developer disciplines within and across phases, hinder the ongoing development of a system because of the interdependencies among phases and among disciplines. Such gaps are magnified among systems that are developed at different times by different development teams, which may limit reuse of artifacts of systems development and interoperability among the systems. This article discusses such gaps and a systems development process for avoiding them.     

Frame-level temporal calibration of video sequences from unsynchronized cameras

This paper describes a method for temporally calibrating video sequences from unsynchronized cameras by image processing operations, and presents two search algorithms to match and align trajectories across different camera views. Existing multi-camera systems assume that input video sequences are synchronized either by genlock or by time stamp information and a centralized server. Yet, hardware-based synchronization increases installation cost. Hence, using image information is necessary to align frames from the cameras whose clocks are not synchronized. The system built for temporal calibration is composed of three modules: object tracking module, calibration data extraction module, and the search module. A robust and efficient search algorithm is introduced that recovers the frame offset by matching the trajectories in different views, and finding the most reliable match. Thanks to information obtained from multiple trajectories, this algorithm is robust to possible errors in background subtraction and location extraction. Moreover, the algorithm can handle very large frame offsets. A RANdom SAmple Consensus (RANSAC) based version of this search algorithm is also introduced. Results obtained with different video sequences are presented, which show the robustness of the algorithms in recovering various range of frame offsets for video sequences with varying levels of object activity.     

Methane coupling at low temperatures on Ru(0001) and Ru(11¯20) catalysts

The conversion of methane to higher hydrocarbons on single crystal Ru catalysts has been investigated using combined elevated-pressure kinetic measurements/surface science studies. The reaction consists of activation of methane on Ru(0001) and Ru(11¯20) surfaces to produce carbonaceous intermediates at temperatures between 350 and 700 K and rehydrogenation of these species to ethane and propane at 370 K. It is found that under the reaction conditions employed, the maximum yield in ethane/propane production occurs at 500 K on both surfaces. Influence of the hydrogenation temperature on the production of ethane and propane is also examined. On Ru(0001), the yields of ethane and propane maximize at = 400 K, whereas no maximum yield was observed on Ru(11 0) in the 300–500 K temperature range. Under optimum reaction conditions, hydrocarbon products consist of 16% ethane and 2% propane. High-resolution electron energy-loss spectroscopy (HREELS) has been used to identify various forms of hydrocarbonaceous intermediates following methane decomposition. An effort is made to relate the hydrocarbon intermediates identified by HREELS to the gas phase products observed in the elevated pressure experiments.     

Photophysical models of aromatic polyesters: excited state interactions in bis(phenalkyl)terephthalate

Summary The nature of the excited state interactions in poly(ethylene terephthalate) is still subject to debate. We study a new series of model compounds composed of a central terephthaloyl group condensed with -hydroxy--phenyl-n-alkanes. Although the molecular architecture prevents these molecules from achieving symmetric ring-ring overlap, the steady-state fluorescence spectra are remarkably similar to those of other models studied earlier, where such overlap was expected. The solvent polarity dependence suggests that the excited state complex is an exciplex and not an excimer.     

Noninvasive pacing: what you should know

Noninvasive pacing is a valuable therapy in emergency cardiac care. The more experience clinicians have with the noninvasive pacing procedure, the greater their confidence and the easier the job becomes. Effective troubleshooting during pacing becomes less problematic with increased experience with the therapy. Noninvasive pacing allows rapid initiation of emergency pacing and "buys time" to stabilize the patient and plan further care.     

Mid-IR real-time monitoring of the carbocationic polymerization of isobutylene and styrene

The in-situ monitoring of the living carbocationic polymerization of isobutylene (IB) and styrene (St) with a fiber optic Attenuated Total Reflection (ATR) probe in the mid-IR "fingerprint" range is reported here for the first time. Monomer consumption was followed by the disappearance of the C=C stretching for both IB and St, and the C−H bending of the CH₃-group in IB. The formation of polyisobutylene (PIB) was also monitored by tracing the asymmetrical doublet characteristic of C−H bending of the t-butyl groups of the PIB. Conversion measurements by conventional off-line gravimetry correlated well with the new technique. Received: 27 August 1997/Revised version: 2 November 1997/Accepted: 20 November 1997